Solar XUV limb brightening observations

Limb brightening of XUV lines of the ions Ciii Niii, Niv, Oiii, Oiv, Ov and Siiv is compared with that predicted by a modified version of a coronal model developed by Dupree and Goldberg. Systematic differences between the predicted and observed limb brightening are found. These differences can be eliminated by introducing into the model the effects of spicules that extend up into the chromospheric-coronal transition region. The spicules are assumed to be opaque to radiation between 500 and 900 Å because of absorption in the hydrogen Lyman continuum.     

Moonquakes and lunar tectonism

With the succesful installation of a geophysical station at Hadley Rille, on July 31, 1971, on the Apollo 15 mission, and the continued operation of stations 12 and 14 approximately 1100 km SW, the Apollo program for the first time achieved a network of seismic stations on the lunar surface. A network of at least three stations is essential for the location of natural events on the Moon. Thus, the establishment of this network was one of the most important milestones in the geophysical exploration of the Moon. The major discoveries that have resulted to date from the analysis of seismic data from this network can be summarized as follows:

1. Lunar seismic signals differ greatly from typical terrestrial seismic signals. It now appears that this can be explained almost entirely by the presence of a thin dry, heterogeneous layer which blankets the Moon to a probable depth of few km with a maximum possible depth of about 20 km. Seismic waves are highly scattered in this zone. Seismic wave propagation within the lunar interior, below the scattering zone, is highly efficient. As a result, it is probable that meteoroid impact signals are being received from the entire lunar surface.
2. The Moon possesses a crust and a mantle, at least in the region of the Apollo 12 and 14 stations. The thickness of the crust is between 55 and 70 km and may consist of two layers. The contrast in elastic properties of the rocks which comprise these major structural units is at least as great as that which exists between the crust and mantle of the earth. (See Toks?zet al., p. 490, for further discussion of seismic evidence of a lunar crust.)
3. Natural lunar events detected by the Apollo seismic network are moonquakes and meteoroid impacts. The average rate of release of seismic energy from moonquakes is far below that of the Earth. Although present data do not permit a completely unambiguous interpretation, the best solution obtainable places the most active moonquake focus at a depth of 800 km; slightly deeper than any known earthquake. These moonquakes occur in monthly cycles; triggered by lunar tides. There are at least 10 zones within which the repeating moonquakes originate.
4. In addition to the repeating moonquakes, moonquake ‘swarms’ have been discovered. During periods of swarm activity, events may occur as frequently as one event every two hours over intervals lasting several days. The source of these swarms is unknown at present. The occurrence of moonquake swarms also appears to be related to lunar tides; although, it is too soon to be certain of this point.

These findings have been discussed in eight previous papers (Lathamet al., 1969, 1970, 1971) The instrument has been described by Lathamet al. (1969) and Sutton and Latham (1964). The locations of the seismic stations are shown in Figure 1.     

An investigation of numerical grid effects in parameter estimation

Modern ground water characterization and remediation projects routinely require calibration and inverse analysis of large three-dimensional numerical models of complex hydrogeological systems. Hydrogeologic complexity can be prompted by various aquifer characteristics including complicated spatial hydrostratigraphy and aquifer recharge from infiltration through an unsaturated zone. To keep the numerical models computationally efficient, compromises are frequently made in the model development, particularly, about resolution of the computational grid and numerical representation of the governing flow equation. The compromise is required so that the model can be used in calibration, parameter estimation, performance assessment, and analysis of sensitivity and uncertainty in model predictions. However, grid properties and resolution as well as applied computational schemes can have large effects on forward-model predictions and on inverse parameter estimates. We investigate these effects for a series of one- and two-dimensional synthetic cases representing saturated and variably saturated flow problems. We show that "conformable" grids, despite neglecting terms in the numerical formulation, can lead to accurate solutions of problems with complex hydrostratigraphy. Our analysis also demonstrates that, despite slower computer run times and higher memory requirements for a given problem size, the control volume finite-element method showed an advantage over finite-difference techniques in accuracy of parameter estimation for a given grid resolution for most of the test problems.     

Experiments on the kinetics of partial melting of a leucogranite at 200 MPa H<Subscript>2</Subscript>O and 690–800°C: compositional variability of melts during the onset of H<Subscript>2</Subscript>O-saturated crustal anatexis

We have experimentally investigated the kinetics of melting of an aplitic leucogranite (quartz+sodic plagioclase of ≈Ab₉₀+K-feldspar+traces of biotite) at 690, 740, and 800°C, all at 200 MPa H₂O. Leucogranite cylinders, 3.5 mm in diameter and 7 mm in length, were run in the presence of excess H₂O using cold-seal pressure vessels for 11–2,925 h. At 690 and 740°C and any experimental time, and 800°C and short run times, silicate glass (melt at run conditions) occurs as interconnected films along most of the mineral boundaries and in fractures, with the predominant volume occurring along quartz/feldspars boundaries and quartz/plagioclase/K-feldspar triple junctions. Glass film thickness is roughly constant throughout a given experimental charge and increases with experimental temperature and run duration. The results indicate that H₂O-saturated partial melting of a quartzo-feldspathic protolith will produce an interconnected melt phase even at very low degrees (<5 vol%) of partial melting. Crystal grain boundaries are therefore completely occluded with melt films even at the lowest degrees of partial melting, resulting in a change in the mechanism of mass transport through the rock from advection of aqueous vapor to diffusion through silicate melt. At 690 and 740°C the compositions of glasses are homogeneous and (at both temperatures) close to, but not on, the H₂O-saturated 200 MPa haplogranite eutectic; glass compositions do not change with run duration. At 800°C glasses are heterogeneous and plot away from the minimum, although their molar ratios ASI (=mol Al₂O₃/CaO+Na₂O+K₂O) and Al/Na are constant throughout the entire charge at any experimental time. Glass compositions within individual 800°C experiments form linear trends in (wt%) normative quartz–albite–orthoclase space. The linear trends are oriented perpendicular to the 200 MPa H₂O haplogranite cotectic line, reflecting nearly constant albite/orthoclase ratio versus variable quartz/feldspar ratio, and have endpoints between the 800°C isotherms on the quartz and feldspar liquidus surfaces. With increasing experimental duration the trends migrate from the potassic side of the minimum toward the bulk rock composition located on the sodic side, due to more rapid (and complete) dissolution of K-feldspar relative to plagioclase. The results indicate that partial melting at or slightly above the solidus (690–740°C) is interface reaction-controlled, and produces disequilibrium melts of near-minimum composition that persist metastably for up to at least 3 months. Relict feldspars show no change in composition or texture, and equilibration between melt and feldspars might take from a few to tens of millions of years. Partial melting at temperatures well above the solidus (800°C) produces heterogeneous, disequilibrium liquids whose compositions are determined by the diffusive transport properties of the melt and local equilibrium with neighboring mineral phases. Feldspars recrystallize and change composition rapidly. Partial melting and equilibration between liquids and feldspars might take from a few to tens of years (H₂O-saturated conditions) at these temperatures well above the solidus.     

Large-scale galactic turbulence: can self-gravity drive the observed H i velocity dispersions?

Observations of turbulent velocity dispersions in the H  i component of galactic discs show a characteristic floor in galaxies with low star formation rates and within individual galaxies the dispersion profiles decline with radius. We carry out several high-resolution adaptive mesh simulations of gaseous discs embedded within dark matter haloes to explore the roles of cooling, star formation, feedback, shearing motions and baryon fraction in driving turbulent motions. In all simulations the disc slowly cools until gravitational and thermal instabilities give rise to a multiphase medium in which a large population of dense self-gravitating cold clouds are embedded within a warm gaseous phase that forms through shock heating. The diffuse gas is highly turbulent and is an outcome of large-scale driving of global non-axisymmetric modes as well as cloud–cloud tidal interactions and merging. At low star formation rates these processes alone can explain the observed H  i velocity dispersion profiles and the characteristic value of  ∼10 km s⁻¹  observed within a wide range of disc galaxies. Supernovae feedback creates a significant hot gaseous phase and is an important driver of turbulence in galaxies with a star formation rate per unit area  ≳10⁻³ M_⊙ yr⁻¹ kpc⁻²  .     

The depletion of carbon by extra mixing in metal-poor giants

There is an apparent dichotomy between the metal-poor  ([Fe/H]≤−2)  yet carbon-normal giants and their carbon-rich counterparts. The former undergo significant depletion of carbon on the red giant branch after they have undergone first dredge-up, whereas the latter do not appear to experience significant depletion. We investigate this in the context that the extra mixing occurs via the thermohaline instability that arises due to the burning of  ³He  . We present the evolution of [C/Fe], [N/Fe] and  ¹²C/¹³C  for three models: a carbon-normal metal-poor star, and two stars that have accreted material from a  1.5 M_⊙  AGB companion, one having received  0.01 M_⊙  of material and the other having received  0.1 M_⊙  . We find the behaviour of the carbon-normal metal-poor stars is well reproduced by this mechanism. In addition, our models also show that the efficiency of carbon-depletion is significantly reduced in carbon-rich stars. This extra-mixing mechanism is able to reproduce the observed properties of both carbon-normal and carbon-rich stars.     

Role of electrochemical reactions in pressure solution

Using a Surface Forces Apparatus we have measured changes in the electrical potential difference between quartz and mica surfaces that correlate with the changing quartz dissolution rate when surfaces are pressed together at relatively low pressures (2-3 atm) in aqueous electrolyte solutions of 30 mM CaCl₂ at 25 °C. No detectable dissolution or voltage potential difference is measured in symmetrical systems (e.g. mica-mica or quartz-quartz) or between dry surfaces subjected to similar pressures, indicating that the dissolution can not be attributed to a simple pressure effect, slow aging (creep), or plastic deformation of the quartz surface. In quartz-mica systems brought together under pressure or to close proximity in electrolyte solution, the onset of quartz dissolution is marked by a sudden, rapid decrease in the quartz thickness at initial rates in the range from 1 to 4 nm/min, which after several hours settles into a constant rate of approximately 0.01 nm/min (∼5 μm/yr). Concomitantly, the potential drops to a constant value once the dissolution rate has stabilized. The decrease in the decay rate is interpreted as being due to saturation of the confined aqueous film and/or to the buildup of a Stern layer on the quartz surface, and the constant rate as being due to the steady-state chemical dissolution and diffusion of the dissolving silica into the surrounding reservoir. The dissolution is ‘non-uniform’: the surfaces become rough as dissolution proceeds, with the appearance of pits in a manner analogous to corrosion. On occasions, the process of rapid dissolution followed by a gradual transition to steady dissolution repeats itself, suggesting that the pit structure and Stern layer are fragile and subject to collapse and/or expulsion from the gap. Preliminary experiments on the dissolution of multi-faceted milled quartz particles (∼1.0 μm diameter) compressed between two muscovite surfaces suggest an asymmetry in the dissolution rates at different crystallographic planes. The origin of the electrical potential is interpreted as arising from the overlapping of the electric double-layers of two dissimilar surfaces when they are forced into close proximity. This electrical potential difference, for as yet unknown reasons, appears to be the driving force for the dissolution, rather than pressure.     

Rapid incorporation of lipids into macromolecules during experimental decay of invertebrates: Initiation of geopolymer formation

Diagenetic alteration is critical for the preservation of fossil cuticles of plant and animal origin and to the formation of kerogen. The process takes place over millions of years, but the stage at which it is initiated is not known. Laboratory decay experiments were carried out on shrimps, scorpions and cockroaches to monitor changes in the chitin–protein of the arthropod cuticle and associated lipids. The cockroach and scorpion exoskeleton remained largely unaltered morphologically, but the shrimp experienced rapid decomposition within a month, which progressed through the 44 week duration of the experiment as revealed using electron microscopy. Mass spectrometry and ¹³C NMR (nuclear magnetic resonance) spectroscopy revealed the association of an n-alkyl component with labile lipids, such as fatty acids with up to 24 carbon atoms, which were incorporated into the decaying macromolecule. The scorpion and cockroach cuticle did not reveal the incorporation of additional lipids, indicating that decay is important in initiating in situ lipid association. This experiment provides evidence that lipids can become associated with carbohydrate and proteinaceous macromolecules during the very early stages of decay, representing the first stage in the transformation process that contributes to the aliphatic rich composition ubiquitous in organic fossils and kerogen.     

Characterization of permineralized kerogen from an Eocene fossil fern

The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state ¹³C nuclear magnetic resonance spectroscopy (¹³C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, ¹³C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants.