The depletion of carbon by extra mixing in metal-poor giants

There is an apparent dichotomy between the metal-poor  ([Fe/H]≤−2)  yet carbon-normal giants and their carbon-rich counterparts. The former undergo significant depletion of carbon on the red giant branch after they have undergone first dredge-up, whereas the latter do not appear to experience significant depletion. We investigate this in the context that the extra mixing occurs via the thermohaline instability that arises due to the burning of  ³He  . We present the evolution of [C/Fe], [N/Fe] and  ¹²C/¹³C  for three models: a carbon-normal metal-poor star, and two stars that have accreted material from a  1.5 M_⊙  AGB companion, one having received  0.01 M_⊙  of material and the other having received  0.1 M_⊙  . We find the behaviour of the carbon-normal metal-poor stars is well reproduced by this mechanism. In addition, our models also show that the efficiency of carbon-depletion is significantly reduced in carbon-rich stars. This extra-mixing mechanism is able to reproduce the observed properties of both carbon-normal and carbon-rich stars.     

Role of electrochemical reactions in pressure solution

Using a Surface Forces Apparatus we have measured changes in the electrical potential difference between quartz and mica surfaces that correlate with the changing quartz dissolution rate when surfaces are pressed together at relatively low pressures (2-3 atm) in aqueous electrolyte solutions of 30 mM CaCl₂ at 25 °C. No detectable dissolution or voltage potential difference is measured in symmetrical systems (e.g. mica-mica or quartz-quartz) or between dry surfaces subjected to similar pressures, indicating that the dissolution can not be attributed to a simple pressure effect, slow aging (creep), or plastic deformation of the quartz surface. In quartz-mica systems brought together under pressure or to close proximity in electrolyte solution, the onset of quartz dissolution is marked by a sudden, rapid decrease in the quartz thickness at initial rates in the range from 1 to 4 nm/min, which after several hours settles into a constant rate of approximately 0.01 nm/min (∼5 μm/yr). Concomitantly, the potential drops to a constant value once the dissolution rate has stabilized. The decrease in the decay rate is interpreted as being due to saturation of the confined aqueous film and/or to the buildup of a Stern layer on the quartz surface, and the constant rate as being due to the steady-state chemical dissolution and diffusion of the dissolving silica into the surrounding reservoir. The dissolution is ‘non-uniform’: the surfaces become rough as dissolution proceeds, with the appearance of pits in a manner analogous to corrosion. On occasions, the process of rapid dissolution followed by a gradual transition to steady dissolution repeats itself, suggesting that the pit structure and Stern layer are fragile and subject to collapse and/or expulsion from the gap. Preliminary experiments on the dissolution of multi-faceted milled quartz particles (∼1.0 μm diameter) compressed between two muscovite surfaces suggest an asymmetry in the dissolution rates at different crystallographic planes. The origin of the electrical potential is interpreted as arising from the overlapping of the electric double-layers of two dissimilar surfaces when they are forced into close proximity. This electrical potential difference, for as yet unknown reasons, appears to be the driving force for the dissolution, rather than pressure.     

Rapid incorporation of lipids into macromolecules during experimental decay of invertebrates: Initiation of geopolymer formation

Diagenetic alteration is critical for the preservation of fossil cuticles of plant and animal origin and to the formation of kerogen. The process takes place over millions of years, but the stage at which it is initiated is not known. Laboratory decay experiments were carried out on shrimps, scorpions and cockroaches to monitor changes in the chitin–protein of the arthropod cuticle and associated lipids. The cockroach and scorpion exoskeleton remained largely unaltered morphologically, but the shrimp experienced rapid decomposition within a month, which progressed through the 44 week duration of the experiment as revealed using electron microscopy. Mass spectrometry and ¹³C NMR (nuclear magnetic resonance) spectroscopy revealed the association of an n-alkyl component with labile lipids, such as fatty acids with up to 24 carbon atoms, which were incorporated into the decaying macromolecule. The scorpion and cockroach cuticle did not reveal the incorporation of additional lipids, indicating that decay is important in initiating in situ lipid association. This experiment provides evidence that lipids can become associated with carbohydrate and proteinaceous macromolecules during the very early stages of decay, representing the first stage in the transformation process that contributes to the aliphatic rich composition ubiquitous in organic fossils and kerogen.     

Characterization of permineralized kerogen from an Eocene fossil fern

The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state ¹³C nuclear magnetic resonance spectroscopy (¹³C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, ¹³C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants.     

Palaeoleptus burmanicus n. gen., n. sp., an Early Cretaceous shore bug (Hemiptera: Palaeoleptidae n. fam.) in Burmese amber

Palaeoleptus burmanicus gen. et sp. nov. (Hemiptera: Leptopodomorpha: Palaeoleptidae fam. nov.) is described from Early Cretaceous Burmese amber. The fossil is characterized by nearly completely coreaceous wings with only a small membranous area at the distal tip, and a unique wing venation consisting of eight closed cells, including four obliquely orientated toward the embolar wing margin and two large vertically-positioned cells extending nearly to the apical wing margin. Additional characters are large, compound eyes, three pairs of cephalic trichobothria, four antennal segments all similar in texture, spines on the profemur, ocelli positioned on a tubercle and a rostrum extending to the mesocoxae, with the second segment bearing four pairs of spines. The female fossil contains an asymmetrical subgenital plate orientated toward the left side of the body, indicating a side-by-side mating behavior as occurs in extant Leptopodomorpha.     

The early-type galaxies NGC 1407 and NGC 1400 – I. Spatially resolved radial kinematics and surface photometry

This is the first paper of a series focused on investigating the star formation and evolutionary history of the two early-type galaxies NGC 1407 and NGC 1400. They are the two brightest galaxies of the NGC 1407 (or Eridanus-A) group, one of the 60 groups studied as part of the Group Evolution Multi-wavelength Study.
Here, we present new high signal-to-noise ratio long-slit spectroscopic data obtained at the ESO 3.6-m telescope and high-resolution multiband imaging data from the Hubble Space Telescope /Advanced Camera for Surveys and wide-field imaging from Subaru Suprime-Cam. We spatially resolved integrated spectra out to ∼0.6 (NGC 1407) and ∼1.3 (NGC 1400) effective radii. The radial profiles of the kinematic parameters v _rot, σ, h ₃ and h ₄ are measured. The surface brightness profiles are fitted to different galaxy light models and the colour distributions analysed. The multiband images are modelled to derive isophotal shape parameters and residual galaxy images. The parameters from the surface brightness profile fitting are used to estimate the mass of the possible central supermassive black hole in NGC 1407. The galaxies are found to be rotationally supported and to have a flat core in the surface brightness profiles. Elliptical isophotes are observed at all radii and no fine structures are detected in the residual galaxy images. From our results, we can also discard a possible interaction between NGC 1400, NGC 1407 and the group intergalactic medium. We estimate a mass of  ∼1.03 × 10⁹ M_⊙  for the supermassive black hole in NGC 1407 galaxy.     

Landscape transform and spatial metrics for mapping spatiotemporal land cover dynamics using Earth Observation data-sets

Analysis of Earth observation (EO) data, often combined with geographical information systems (GIS), allows monitoring of land cover dynamics over different ecosystems, including protected or conservation sites. The aim of this study is to use contemporary technologies such as EO and GIS in synergy with fragmentation analysis, to quantify the changes in the landscape of the Rajaji National Park (RNP) during the period of 19 years (1990–2009). Several statistics such as principal component analysis (PCA) and spatial metrics are used to understand the results. PCA analysis has produced two principal components (PC) and explained 84.1% of the total variance, first component (PC1) accounted for the 57.8% of the total variance while the second component (PC2) has accounted for the 26.3% of the total variance calculated from the core area metrics, distance metrics and shape metrics. Our results suggested that notable changes happened in the RNP landscape, evidencing the requirement of taking appropriate measures to conserve this natural ecosystem.     

Morphology of lunar craters: A test of lunar erosional models

This paper is a test of published theoretical and experimental studies of crater erosion by micrometeorite bombardment which predict systematic variations in the morphology of lunar craters as a function of crater diameter and crater age. Numerical, ranking-type degradation classifications indicate that the craters on Mare Imbrium and Mare Tranquillitatus confirm these predictions by showing a systematic increase in degradation with decreasing diameter for craters smaller than a few kilometers in diameter but larger than the equilibrium diameter, and by showing fixed proportions of fresh, moderately degraded and very degraded craters under equilibrium conditions. Furthermore, the relative ages of the two mare surfaces may be determined using a diameter/mean-degradation-number curve. These determinations of relative age and process of crater erosion are both essentially independent of the traditionally studied crater diameter/frequency relationships. Morphologies of terra craters near Mare Humorum suggest a young, non-equilibrium crater population superposed on a perimordial population with about equilibrium proportions of fresh, moderately degraded and very degraded craters. The primordial population has been modified by pre-Imbrian or early Imbrian deposition of blanketing deposits. A comparative study of several crater degradation classifications indicates that all are essentially interchangeable.