Groundwater age dating and recharge mechanism of Arusha aquifer,northern Tanzania: application of radioisotope and stable isotope techniques

The continuous abstraction of groundwater from Arusha aquifers in northern Tanzania has resulted in a decline in water levels and subsequent yield reduction in most production wells. The situation is threatening sustainability of the aquifers and concise knowledge on the existing groundwater challenge is of utmost importance. To gain such knowledge, stable isotopes of hydrogen and oxygen, and radiocarbon dating on dissolved inorganic carbon (DIC), were employed to establish groundwater mean residence time and recharge mechanism.¹⁴C activity of DIC was measured in groundwater samples and corrected using a δ¹³C mixing method prior to groundwater age dating. The results indicated that groundwater ranging from 1,400 years BP to modern is being abstracted from deeper aquifers that are under intensive development. This implies that the groundwater system is continuously depleted due to over-pumping, as most of the sampled wells and springs revealed recently recharged groundwater. High ¹⁴C activities observed in spring water (98.1?±?7.9 pMC) correspond with modern groundwater in the study area. The presence of modern groundwater suggests that shallow aquifers are actively recharged and respond positively to seasonal variations.     

Functional and Compositional Responses of Periphyton Mats to Simulated Saltwater Intrusion in the Southern Everglades

Periphyton plays key ecological roles in karstic, freshwater wetlands and is extremely sensitive to environmental change making it a powerful tool to detect saltwater intrusion into these vulnerable and valuable ecosystems. We conducted field mesocosm experiments in the Florida Everglades, USA to test the effects of saltwater intrusion on periphyton metabolism, nutrient content, and diatom species composition, and how these responses differ between mats from a freshwater versus a brackish marsh. Pulsed saltwater intrusion was simulated by dosing treatment chambers monthly with a brine solution for 15 months; control chambers were simultaneously dosed with site water. Periphyton from the freshwater marsh responded to a 1-ppt increase in surface water salinity with reduced productivity and decreased concentrations of total carbon, nitrogen, and phosphorus. These functional responses were accompanied by significant shifts in periphytic diatom assemblages. Periphyton mats at the brackish marsh were more functionally resilient to the saltwater treatment (~?2 ppt above ambient), but nonetheless experienced significant shifts in diatom composition. These findings suggest that freshwater periphyton is negatively affected by small, short-term increases in salinity and that periphytic diatom assemblages, particularly at the brackish marsh, are a better metric of salinity increases compared with periphyton functional metrics due to functional redundancy. This research provides new and valuable information regarding periphyton dynamics in response to changing water sources in the southern Everglades that will allow us to extend the use of periphyton, and their diatom assemblages, as tools for environmental assessments related to saltwater intrusion.     

Plug shaped burrows <Emphasis Type="Italic">Conichnus - Conostichus</Emphasis> from the Late Cretaceous of Bagh Group,Gujarat, western India

Plug-shaped ichnofossils Conichnus conicus, Conostichus broadheadi and C. stouti are found in the intercalated micritic sandstone and sandy allochemic limestone shale sequence of Bagh Group, Narmada district, Gujarat. These ichnospecies occur at two stratigraphic levels and shows distinct morphological features interpreted as resting/dwelling structures of sea anemone. The occurrence of these ichnospecies along with oyster fossils genera like Bosostrea and Indostrea indicate shallow marine environment.     

Adaptation policy and adaptation realities: local social organization and cross-scale networks for climate adaptation on Mount Kilimanjaro

Least developed countries have prepared national adaptation programs of action (NAPAs) to coordinate international adaptation funding to reduce social vulnerability to climate change. The adaptation programs have been written for consistency with existing sectoral policies and development agendas—policies which have thus far led to inequitable and incomplete decentralization of responsibility to organize and manage adaptation at the local level. The capacity of local social organization and of cross-scale networks and flows of knowledge and resources from higher levels of government is insufficient to facilitate socially equitable and sustainable adaptation to climate change. Tanzania’s NAPA, poverty reduction strategy paper, and sectoral policies for forest, water, and agriculture/livestock illustrate the coordination of adaptation plans with existing policies. National and regional statistics and a survey of households on Mount Kilimanjaro—a regional priority for climate adaptation in Tanzania—demonstrate significant gaps in local social organization and cross-scale networks for adaptation. Challenging existing structural causes of vulnerability will be difficult under adaptation plans written for complementarity with the very policies that have produced social inequality. Outside of a few development projects of limited geographic extent, there is limited evidence for socially equitable and sustainable adaptation outcomes. Sustainable adaptation will require substantial new commitments to developing local capacity and cross-scale networks.     

基于生物酶的固土技术在香港的应用研究

传统加固土体的方法主要是通过在土中加入一定量的高性能掺合剂使之成为一种强度较高的复合土体,但这种方法需要较长的养护时间,且不经济。利用一种新型实用的生物酶固化技术,针对香港地区3种常见的海洋黏土、完全风化花岗岩和完全风化凝灰岩,开展了土体加固试验研究。试验结果表明,生物酶对海洋土的加固效果最好,强度增加最高可达20%,而生物酶对完全风化花岗岩的加固效果则不太理想,抗剪强度指标只有少许改变。此外,海洋土和完全风化凝灰岩的压缩性因为生物酶的作用反而有所增强。最后,从微观上分析了生物酶固土作用的本质,指出固土效果主要缘自于生物酶分子与土中的黏土矿物分子发生相互作用产生的胶结作用。     

Identifying characteristics of charge transfer transitions in minerals

Criteria used to identify Fe²⁺-Fe³⁺ and Fe²⁺-Ti⁴⁺ intervalence charge transfer absorption bands in electronic spectra are reviewed and compared to the characteristics of unperturbed Fe²⁺ crystal field bands and those that are intensified by interaction with Fe³⁺. Band energy is the least definitive diagnostic criterion. Changes in band intensity with temperature are also of limited value. Large widths are the most reliable characteristic of charge transfer bands. New optical absorption spectra are presented for euclase, as well as 80 K spectra of rockbridgeite, babingtonite and lazulite. Comparison of optical spectra to magnetic susceptibility measurements for rockbridgeite and babingtonite provides support for recent theories regarding the effect of magnetic coupling on the variation of charge transfer intensity with temperature.     

Spatial variability estimation and risk assessment of the aquifer level at sparsely gauged basins using geostatistical methodologies

The spatial variability evaluation of the water table level of an aquifer provides useful information in water resources management plans. Three different approaches are applied to estimate the spatial variability of the water table in the study basin. All of them are based on the Kriging methodology. The first is the classical Ordinary Kriging approach, while the second involves information from a secondary variable (surface elevation) and the application of Residual Kriging. The third calculates the probability to lie below a certain groundwater level limit that could cause significant problems in groundwater resources availability. The latter is achieved by means of Indicator Kriging. A recently developed non-linear normalization method is used to transform both data and residuals closer to normal distribution for improved prediction results. In addition, the recently developed Spartan variogram model is applied to determine the spatial dependence of the measurements. The latter proves to be the optimal model, compared to a series of models tested, which provides in combination with the Kriging methodologies the most accurate cross validation estimations. The variogram form is explained with respect to the radius of influence of the pumping wells representing the spatial impact of the pumping activity. Groundwater level and probability maps are developed providing the ability to assess the spatial variability of the groundwater level in the basin and the risk that certain locations have in terms of a safe groundwater level limit that has been set for the sustainability of the groundwater resources of the basin.     

Hydrothermal origin of metals in some East African Rift Lakes

The chemical composition of all Western Rift valley lakes is controlled by emanations of saline and metalliferous hydrothermal solutions. Center of present day activity is Lake Kivu. Sediments of the last 15,000 years carry the distinct chemical fingerprint of hydrothermal springs in the form of stratiform ore deposits. The geological record reveals periods of volcanic and hydrothermal activity and quiescence which coincide with the African climatic sequence of pluvials and interpluvials. It is concluded that the hydrothermal solutions are meteoric waters which on passage through the volcanic wall rock have derived their metal and salt load. Presence of volcanic CO₂ has enforced the leaching process.

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Zusammenfassung Die chemische Zusammensetzung der großen Seen im Bereich des Western Rift ist maßgeblich durch Einschüttungen salziger und metallhaltiger hydrothermaler Lösungen bestimmt. Zentrum heutiger hydrothermaler Tätigkeit ist der Kivusee. Sedimente der letzten 15 000 Jahre weisen einen deutlichen hydrothermalen Fingerabdruck in der Form schichtgebundener Erzlagen auf. Die Sedimentabfolge zeigt einen mehrfachen Wechsel von Perioden vulkanisch-hydrothermaler Tätigkeit und Stille. Diese stimmen zeitlich überein mit Pluvial- bzw. Interpluvialzeiten. Wir vermuten, daß die hydrothermalen Lösungen ehemalige Regenwässer sind, die beim Durchfluß durch das vulkanische Nebengestein Salze und Metalle aufgenommen haben. Die Anwesenheit von vulkanischem CO₂ hat die Auslaugungsprozesse verstärkt.

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Résumé La composition chimique des lacs de la vallée du «Western Rift» est contrôlée par des émanations de solutions hydrothermales salines et métallifères. Le centre de l'activité actuelle est le lac Kivu. Dans les sédiments des derniers 15000 ans ces émanations hydrothermales ont formé des enrichissements minéralisés stratiformes. Les annales géologiques indiquent des périodes d'activité et de quiétude volcaniques et hydrothermales qui coïncident avec la séquence climatique africaine d'époques pluviales et interpluviales. On conclût que les solutions hydrothermales sont des eaux météoriques qui ont dérivé leur charge de métal et de sel en traversant les roches volcaniques encaissantes. La présence du CO₂ volcanique a facilité cet enrichissement.

     

Isotopic evolution of common lead

The isotopic composition of lead from galenas and feldspars of granitic rocks covering a time span of 3600 m.y. is reviewed. Hew data are combined with data from the literature, all ratios being normalized to a fixed value for the isotopic composition of lead in an inter-laboratory reference sample. Comparison of feldspar and galena results show that the isotopic composition of initial lead in granitic rocks may be identical to, or more radiogenic than, that in coeval stratiform (or ‘single stage’) ore deposits. The isotopic evolution of terrestrial lead over the past 3600 m.y. deduced from the stratiform ore data does not fit the closed system source. The data are best fitted to evolution models in which the value of μ (U²³⁸/Pb²⁰⁴ normalized to the present day) in the source has increased either over approximately the past 3.6 billion years or since the time of formation of the Earth. A limited number of high precision data for strontium likewise indicate open system isotopic evolution. In this system the Rb/Sr ratio appears to have decreased as a function of time. Physical models that explain the data are presented. Either mantle differentiation or crustal contamination processes could account for the change in μ in the source for the lead. The strontium data and some detailed studies of the isotopic composition of lead in oceanic volcanic rocks support mantle differentiation rather than crustal contamination. The exact nature of the mantle differentiation process cannot be specified, although empirical data favoring the existence of such a process are given. The best estimate of the age of the Earth, calculated with the data from 2750 and 3290 m.y.-old lead ores, is 4660 m.y.     

Geochemistry of surface sediments and heavy metal contamination assessment: Messolonghi lagoon complex,Greece

The Messolonghi lagoon complex in Western Greece receives agricultural and domestic effluents both from point and diffused sources. Surface sediments were analyzed for grain size, organic carbon, total nitrogen, total sulfur, major and minor elements, aiming at the identification of geochemical relationships between all variables. Enrichment factors and the modified degree of contamination methods were applied to assess potential heavy metal enrichment related to human activities. Sediment texture was highly variable, with muddy sediments prevailing. In the central sector of the Messolonghi lagoon, organic carbon contents were high. Principal factor analysis revealed the following main groups of variables with common geochemical behavior: (1) terrigenous aluminosilicates (2) organic matter, (3) biogenic carbonates, (4) mineral quartz-aluminosilicates, and (5) Mn-oxides. Enrichment factors estimated for V, Cr, Mn, Co, Ni, Cu, Zn, and Pb using local pre-industrial sediment showed that all metals exhibit almost natural background levels, except for Pb, which was found to be slightly elevated (legacy of leaded fuel). Estimation of contamination factors concluded in similar results, whereas the overall modified degree of contamination was at the lowest level, therefore suggesting that this transitional water body has not been affected by anthropogenic activities. The data set may be considered as a baseline for future monitoring projects according to EU policy.