Environmental problems associated with the development and operation of a lined and unlined landfill site: a case study demonstrating two landfill sites in Patra,Greece

The present work demonstrates the environmental problems associated with the development and operation of a lined and unlined landfill site, both used for municipal solid waste landfilling, that are situated next to the city of Patra, Greece. Findings from a detailed site investigation as well calculations on hydrologic evaluation of landfill’s performance and measurements on leachate composition proved that the lined landfill site is more secure and environmental friendly compared with the unlined landfill site. Even though, until today, there is no evidence from near boreholes for severe contamination problems generated by any of the two landfills, in the forthcoming future several environmental problems are expected to occur from the unlined site. In addition the prevailing hydrogeotechnical conditions indicated that the unlined site is a potential source of contamination; hence extra remedial measures should be received by the local authorities to prevent severe contamination in soil and groundwater.     

FT-IR Spectroscopic Investigation of Hydrous Components in Sillimanite from Eastern Ghat Granulite Belt, India

FT-IR spectra of sillimanite samples from high grade regionally metamorphosed rocks belonging to the granulite terrain (amphibolite to pyroxene granulite facies) deciphers prominent OH features. Heating experiments indicate growth of prominent band at 3161cm⁻¹. Heating above 1000°C all OH features disappear in intensity into broad features with slight shift of bands towards lower energies. Complete dehydration requires temperatures above 1000°C. Coexistence of boron and OH features are also observed in all sillimanite samples. The high temperature behaviour of sillimanite from the granulite terrain discerns that the hydrous species in sillimanite were incorporated much below 700°C, however, secondary hydration due to pegmatite activity, retrograde metamorphism and migmatisation is not ruled out. Thus a near anhydrous condition were probably not achieved during the granulite facies metamorphism in Eastern ghat granulite terrain.     

Palaeoleptus burmanicus n. gen., n. sp., an Early Cretaceous shore bug (Hemiptera: Palaeoleptidae n. fam.) in Burmese amber

Palaeoleptus burmanicus gen. et sp. nov. (Hemiptera: Leptopodomorpha: Palaeoleptidae fam. nov.) is described from Early Cretaceous Burmese amber. The fossil is characterized by nearly completely coreaceous wings with only a small membranous area at the distal tip, and a unique wing venation consisting of eight closed cells, including four obliquely orientated toward the embolar wing margin and two large vertically-positioned cells extending nearly to the apical wing margin. Additional characters are large, compound eyes, three pairs of cephalic trichobothria, four antennal segments all similar in texture, spines on the profemur, ocelli positioned on a tubercle and a rostrum extending to the mesocoxae, with the second segment bearing four pairs of spines. The female fossil contains an asymmetrical subgenital plate orientated toward the left side of the body, indicating a side-by-side mating behavior as occurs in extant Leptopodomorpha.     

Solution mechanisms of H2O in depolymerized peralkaline melts

Solubility mechanisms of water in depolymerized silicate melts quenched from high temperature (1000°-1300°C) at high pressure (0.8-2.0 GPa) have been examined in peralkaline melts in the system Na₂O-SiO₂-H₂O with Raman and NMR spectroscopy. The Na/Si ratio of the melts ranged from 0.25 to 1. Water contents were varied from ∼3 mol% and ∼40 mol% (based on O = 1). Solution of water results in melt depolymerization where the rate of depolymerization with water content, ∂(NBO/Si)/∂X_H2O, decreases with increasing total water content. At low water contents, the influence of H₂O on the melt structure resembles that of adding alkali oxide. In water-rich melts, alkali oxides are more efficient melt depolymerizers than water. In highly polymerized melts, Si-OH bonds are formed by water reacting with bridging oxygen in Q⁴-species to form Q³ and Q² species. In less polymerized melts, Si-OH bonds are formed when bridging oxygen in Q³-species react with water to form Q²-species. In addition, the presence of Na-OH complexes is inferred. Their importance appears to increase with Na/Si. This apparent increase in importance of Na-OH complexes with increasing Na/Si (which causes increasing degree of depolymerization of the anhydrous silicate melt) suggests that water is a less efficient depolymerizer of silicate melts, the more depolymerized the melt. This conclusion is consistent with recently published ¹H and ²⁹Si MAS NMR and ¹H-²⁹Si cross polarization NMR data.     

Environmental magnetic indicators of the sedimentary context of archaeological sites in the Shangqiu area of China

Environmental magnetic techniques provide significant potential for characterizing sediments and soils and inferring their sources. This article discusses the application of environmental magnetic techniques in the study of an evolving landscape in the Shangqiu area, China, an archaeologically important region for investigating the origin of Shang civilization. Two magnetic parameters—anhysteretic remanent magnetization (ARM) and low-field magnetic susceptibility (χ)—are employed to discriminate the pre-Neolithic paleosol from the historic alluvium. In order to quantitatively interpret magnetic measurements, ARM versus χ plots are utilized with rigorous statistical analyses including group comparison and discriminant classification. With the ARM/χ classification model defined by the pre-Neolithic paleosol and historic alluvium, the sediment sources of three anthropogenic deposits (A-1, A-2, and A-3 from oldest to youngest) are addressed. Magnetic data clearly show that A-1 and A-3 are closely associated with the pre-Neolithic paleosol and historic alluvium, respectively. Cultural mixing processes might be partially responsible for the formation of A-2. © 1998 John Wiley & Sons, Inc.     

Construction of detrital mineral populations: insights from mixing of U–Pb zircon ages in Himalayan rivers

Fission‐track, U–Pb and Pb–Pb analyses of detrital heavy mineral populations in depositional basins and modern river sediments are widely used to infer the exhumational history of mountain belts. However, relatively few studies address the underlying assumption that detrital mineral populations provide an accurate representation of their entire source region. Implicit in this assumption is the idea that all units have equal potential to contribute heavy minerals in proportion to their exposure area in the source region. In reality, the detrital mineral population may be biased by variable concentrations of minerals in bedrock and differential erosion rates within the source region. This study evaluates the relative importance of these two variables by using mixing of U–Pb zircon ages to trace zircon populations from source units, through the fluvial system, and into the foreland. The first part of the study focuses on the Marsyandi drainage in central Nepal, using tributaries that drain single formations to define the U–Pb age distributions of individual units and using trunk river samples to evaluate the relative contributions from each lithology. Observed mixing proportions are compared with proportions predicted by a simple model incorporating lithologic exposure area and zircon concentration. The relative erosion rates that account for the discrepancy between the observed and predicted mixing proportions are then modelled and compared with independent erosional proxies. The study also compares U–Pb age distributions from four adjacent drainages spanning ～250 km along the Himalayan front using the Kolmogorov–Smirnov statistic and statistical estimates of the proportion of zircon derived from each upstream lithology. Results show that, along this broad swath of rugged mountains, the U–Pb age distributions are remarkably similar, thereby allowing data from more localized sources to be extrapolated along strike.     

Towards multiple hazard resilient bridges: a methodology for modeling frequent and infrequent time-varying loads Part I, Comprehensive reliability and partial failure probabilities

The current AASHTO load and resistance factor design (LRFD) guidelines are formulated based on bridge reliability,which interprets traditional design safety factors into more rigorously deduced factors based on the theory of probability.This is a major advancement in bridge design specifications.However,LRFD is only calibrated for dead and live loads.In cases when extreme loads are significant,they need to be individually assessed.Combining regular loads with extreme loads has been a major challenge,mainly because the extreme loads are time variables and cannot be directly combined with time invariant loads to formulate the probability of structural failure.To overcome these difficulties,this paper suggests a methodology of comprehensive reliability,by introducing the concept of partial failure probability to separate the loads so that each individual load combination under a certain condition can be approximated as time invariant.Based on these conditions,the extreme loads (also referred to as multiple hazard or MH loads) can be broken down into single effects.In Part Ⅱ of this paper,a further breakdown of these conditional occurrence probabilities into pure conditions is discussed by using a live truck and earthquake loads on a bridge as an example.There are three major steps in establishing load factors from MH load distributions:(1) formulate the failure probabilities;(2) normalize various load distributions;and (3) establish design limit state equations.This paper describes the formulation of the failure probabilities of single and combined loads.     

Eddy covariance imaging of diffuse volcanic CO<Subscript>2</Subscript> emissions at Mammoth Mountain,CA, USA

Use of eddy covariance (EC) techniques to map the spatial distribution of diffuse volcanic CO₂ fluxes and quantify CO₂ emission rate was tested at the Horseshoe Lake tree-kill area on Mammoth Mountain, California, USA. EC measurements of CO₂ flux were made during September–October 2010 and ranged from 85 to 1,766 g m⁻² day⁻¹. Comparative maps of soil CO₂ flux were simulated and CO₂ emission rates estimated from three accumulation chamber (AC) CO₂ flux surveys. Least-squares inversion of measured eddy covariance CO₂ fluxes and corresponding modeled source weight functions recovered 58–77% of the CO₂ emission rates estimated based on simulated AC soil CO₂ fluxes. Spatial distributions of modeled surface CO₂ fluxes based on EC and AC observations showed moderate to good correspondence (R ² = 0.36 to 0.70). Results provide a framework for automated monitoring of volcanic CO₂ emissions over relatively large areas.     

Travel time controls the magnitude of nitrate discharge in groundwater bypassing the riparian zone to a stream on Virginia's coastal plain

Groundwater that bypasses the riparian zone by travelling along deep flow paths may deliver high concentrations of fertilizer‐derived NO₃^? to streams, or it may be impacted by the NO₃^? removal process of denitrification in streambed sediments. In a study of a small agricultural catchment on the Atlantic coastal plain of Virginia's eastern shore, we used seepage meters deployed in the streambed to measure specific discharge of groundwater and its solute concentrations for various locations and dates. We used values of Cl^? concentration to discriminate between bypass water recharged distal to the stream and that contained high NO₃^? but low Cl^? concentrations and riparian‐influenced water recharged proximal to the stream that contained low NO₃^? and high Cl^? concentrations. The travel time required for bypass water to transit the 30‐cm‐thick, microbially active denitrifying zone in the streambed determined the extent of NO₃^? removal, and hydraulic conductivity determined travel time through the streambed sediments. At all travel times greater than 2 days, NO₃^? removal was virtually complete. Comparison of the timescales for reaction and transport through the streambed sediments in this system confirmed that the predominant control on nitrate flux was travel time rather than denitrification rate coefficients. We conclude that extensive denitrification can occur in groundwater that bypasses the riparian zone, but a residence time in biologically active streambed sediments sufficient to remove a large fraction of the NO₃^? is only achieved in relatively low‐conductivity porous media. Instead of viewing them as separate, the streambed and riparian zone should be considered an integrated NO₃^? removal unit. Copyright © 2011 John Wiley & Sons, Ltd.