Characterization of permineralized kerogen from an Eocene fossil fern

The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state ¹³C nuclear magnetic resonance spectroscopy (¹³C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, ¹³C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants.     

A knowledge-based software for the preliminary design of seismically isolated bridges

Seismic design of isolated bridges involves conceptual, preliminary and detailed structural design. However, despite the variety of commercial software currently available for the analysis and design of such systems, conceptual and preliminary design can prove to be a non-straightforward procedure because of the sensitivity of bridge response on the initial decisions made by the designer of the location, number and characteristics of the bearings placed, as well as on a series of broader criteria such as serviceability, target performance level and cost-effectiveness of the various design alternatives. Given the lack of detailed design guidelines to ensure, at this preliminary stage, compliance with the above requirements, a “trial and error” procedure is typically followed in the design office to decide on the most appropriate design scheme in the number and location of the bearing systems; the latter typically based on engineering judgment to balance performance with cost. To this end, the particular research effort aims to develop a decision-making system for the optimal preliminary design of seismically isolated bridges, assumed to respond as single degree of freedom (SDOF) systems. The proposed decision-making process is based on the current design provisions of Eurocode 8, but is complemented by additional criteria set according to expert judgment, laboratory testing and recent research findings, while using a combined cost/performance criterion to select from a database of bearings available on the international market. Software is also developed for the implementation of the system. The paper concludes with the application, and essentially the validation of the methodology and software developed through more rigorous MDOF numerical analysis for the case of a real bridge.     

The Total Irradiance Monitor (TIM): Instrument Design

The Total Irradiance Monitor (TIM) instrument is designed to measure total solar irradiance with an absolute accuracy of 100 parts per million. Four electrical substitution radiometers behind precision apertures measure input radiant power while providing redundancy. Duty cycling the use of the radiometers tracks degradation of the nickel-phosphorous absorptive black radiometer interiors caused by solar exposure. Phase sensitive detection at the shutter frequency reduces noise and simplifies the estimate of the radiometer's equivalence ratio. An as-designed uncertainty budget estimates the instrument's accuracy goal. The TIM measurement equation defines the conversion from measured signal to solar irradiance.     

Clinoform architecture and along‐strike facies variability through an exhumed erosional to accretionary basin margin transition

Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km² area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.     

POST-FIRE DEVELOPMENT OF CANOPY STRUCTURE IN A MEDITERRANEAN SHRUB,QUERCUS COCCIFERAL.

The canopy structure, including density, the apportionment of biomass in basal stem and branch diameter classes and foliage, and leaf characteristics, was examined for a dense Quercus coccifera garrigue in southern France at 3,9, and 33 years since the last fire. Indications of changing canopy structure were considered in relation to succession, regeneration strategies, water relations, and flammability. Other shrub species and herbs are most abundant at 3 and 33 years following fire, but at 9 years Q. coccifera is especially dominant. At 9 years the density of stems in the middle range of diameter classes is greatest, overall biomass reaches its peak, and leaf area index is highest. The canopy closes quickly, but by 33 years evidence for self-thinning, slowed but continuing basal sprouting, and declining leaf area and biomass is found; senescence may be beginning, but it is not an important factor in the first 33 years of canopy development. The continuity of the below-ground biomass in this and similar vegetation probably plays an important role in determining the optimum tactics for ramets through cyclic successions. Renewed competition in later years in a more open canopy of Q. coccifera, as indicated by the data, probably would be limited by recurrent fire. [Key words: biomass, canopy, density, mediterranean, physiognomy.]     

COMPUTATIONAL GEOMETRY AND GEOGRAPHY *

New developments in computational geometry are applicable to geographic data processing. Computationally efficient procedures incorporating logarithmic searches over appropriate data structures, and other shortcuts, can yield important savings in computation time and data storage space. There are “fast”methods for two-dimensional problems such as point inclusion, nearest-neighbor and two-nearest-neighbors determination, and grid overlay. Worst-case analysis of algorithms provides useful performance bounds for the developers of geographic production software.     

Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay

A combination of CTD casts, discrete bottle sampling and in situ voltammetric microelectrode profiling was used to examine changing redox conditions in the water column at a single station south of the Bay Bridge in the upper Chesapeake Bay in late July/early August, 2002–2005. Short-term (2–4 h) fluctuations in the oxic/suboxic/anoxic interface were documented using in situ voltammetric solid-state electrodes. Profiles of dissolved oxygen and sulfide revealed tidally-driven vertical fluctuations of several meters in the depth and thickness of the suboxic zone. Bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ also varied over the tidal cycle by approximately an order of magnitude. These data indicate that redox species concentrations at this site varied more due to physical processes than biogeochemical processes. Based on analysis of ADCP data, tidal currents at this station were strongly polarized, with the principal axis of tidal currents aligned with the mainstem channel. Together with the chemical data, the ADCP analysis suggests tidal flushing of anoxic bottom waters with suboxic water from north of the site. The present study is thus unique because while most previous studies have focused on processes across relatively stable redox interfaces, our data clearly demonstrate the influence of rapidly changing physical mixing processes on water column redox chemistry.Also noted during the study were interannual differences in maximum bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺. In 2003, for example, heavy spring rains resulted in severe hypoxia/anoxia in June and early July. While reported storm-induced mixing in late July/early August 2003 partially alleviated the low-oxygen conditions, bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ were still much higher than in the previous year. The latter implies that the response time of the microbial community inhabiting the suboxic/anoxic bottom waters to changing redox conditions is slow compared to the time scale of episodic mixing events. Bottom water concentrations of the redox-sensitive chemical species should thus be useful as a tracer to infer prior hypoxic/anoxic conditions not apparent from ambient oxygen levels at the time of sampling.