Structural relaxation in the MnCO3–CaCO3 solid solution: a Mn K-edge EXAFS study

Mn K-edge EXAFS spectroscopy of solid-solution samples encompassing the complete MnCO₃–CaCO₃ series shows that first-shell Mn–O distances deviate little from the 2.19-Å distance observed in pure MnCO₃. Very slight lengthening is observed only in the limiting case of dilute Mn(II) calcite solid solutions, where the Mn–O distance is 2.21 Å. The observed nearly complete structural relaxation and the composition independence of the Mn–O distance are consistent with the Pauling model behavior of solid solutions, and agree with previous studies showing a high degree of relaxation around hetero-sized substituents in the calcite structure. Strain occurs through bond bending, which is facilitated by the exclusively corner-sharing topology of calcite. Observed distances from Mn to more distant neighbors show significant variation across the solid-solution series that resembles Vegard's law-type behavior but reflects averaging. The high degree of relaxation suggests modest enthalpies of mixing in the solution, consistent with calorimetric studies.     

A decade of change in the Skidaway River estuary I. Hydrography and nutrients

The Skidaway River estuary is a tidally-dominated subtropical estuary in the southeastern USA surrounded by extensiveSpartina salt marshes. Weekly smapling at high and low tide began in 1986 for hydrography, nutrients, chlorophylla, particulate matter, and microbial and plankton biomass and composition; hydrographic and nutrient data during 1986–1996 are reported here. Salinity varied inversely with river discharge and exhibited variability at all time scales but with no long-term trend. Water temperature typically ranged over 25°C and was without apparent long-term frend. Seasonal cycles in concentrations of NO₃, NH₄, PO₄, Si(OH)₄, and DON were observed, with annual maxima generally occurring in late summer. Superimposed on seasonal cycles, all five nutrients exhibited steady increases in minimum, mean, and maximum concentrations; mean concentrations increased c. 50–150% during the decade. Nutrient concentrations were highly correlated with water temperature over the ten-year period, but weakly related to salinity and discharge. Nutrients were strongly correlated with one another, and the relative ratios among inorganic nutrients showed little long-term trend. Correlations among temperature and nutrient concentrations exhibited considerable inter-annual variability. Major spikes in organic and inorganic nutrient concentrations coincided with significant rainfall events; concentrations increased hyperbolically with rainfall. Although pristine compared to more heavily impacted waterways primarily outside the region, residential development and population density have been increasing rapidly during the past 15–20 years. Land use is apparently altering nutrient loading over the long-term (months-years), and superimposed on this are stochastic meteorological events that accelerate these changes over the short term (days-weeks).     

Persistence of tidally-oriented vertical migration by zooplankton in a temperate estuary

Tidal vertical migration by zooplankton is a common phenomenon in estuaries, usually associated with landward movement of meroplankton or position maintenance of holoplankton. Little is known about the persistence of this behavior, its spatial variability, or its response to changing environmental conditions. We extended a previous study of tidal movements of zooplankton in the low-salinity zone (LSZ) of the San Francisco estuary in 1994 to include data from two additional years with very different hydrology. Freshwater flow during sampling in 1995 was about 7-fold greater than in 1994; the LSZ was about 28 km further seaward, and gravitational circulation in the LSZ was strong. In 1996 freshwater flow and LSZ position were intermediate but, because the LSZ was in shallower water in 1996 than in 1995, gravitational circulation was uncommon. Behavior of copepods in both years was similar to that reported in 1994 with some tidal migration observed during most cruises. An exception was the introduced carnivorous copepodTortanus dextrilobatus, which did not migrate and maintained a position deep in the water column (1995 only). In 1996, mysids mainly stayed near the bottom with evidence for vertical migration from only 1 of 6 data sets, whereas amphipods migrated slightly on a diel schedule; these behaviors contrasted with the tidal migration observed in 1994. The bay shrimpCrangon franciscorum did not appear to migrate, but was more abundant in the water column during both ebb and flood, suggesting passive vertical dispersal. Zooplankton did not appear to maintain position by interactions with lateral circulation cells. The results for copepods suggest rigidity in behavior with little or no relaxation of the vertical movement in 1995 when strong gravitational circulation would have made upstream movement relatively easy. Mysids and amphipods altered their behavior depending on local conditions related to freshwater flow.     

Multiple stressors in an estuarine system: Effects of nutrients, trace elements, and trophic complexity on benthic photosynthesis and respiration

The effects of nutrients, trace elements, and trophic complexity on benthic photosynthesis and respriation were studied in the Paxtuxent River estuary near St. Leonard, Maryland. Experiments were conducted over three years (1995–1997) in mesocosms containing riverine sediment and water. The experimental design was 2×2×3 factorial with two levels of nutrients (ambient and + nutrients), two of trace elements (ambient and + trace elements) and three of trophic complexity (plankton, plankton + fish, and plankton + fish + benthos). Trace elements included arsenic (As), copper (Cu), and cadmium (Cd). The experiment was conducted three times in 1995 and 1997 and four times in 1996. In 1995 and 1996, sediments were muddy, while in the final year sediments were sandy. In mesocoms with sandy sediments, nutrient additions increased benthic photosynthesis overall, while trace element additions increased benthic photosynthesis in two of three experimental runs. Benthic photosynthesis in these mesocosms appeared to be related to nitrogen loading. Benthic respiration increased in nutrient and trace element amended mesocosms with sandy sediments, apparently in response to higher benthic photosynthesis. Increasing trophic complexity, particularly the presence of benthic organisms, also increased benthic respiration in mesocosms with sandy sediments. There were no effects of nutrient or trace element additions on benthic photosynthesis and respiration when the sediments were muddy. The lack of consistent responses to nutrient additions was surprising given that benthic respiration rates (and presumably nutrient regeneration) were similar in all three years, regardless of sediment type. Muddy, sediments did not mask, the effects of nutrient addition by supplying more nutrients to benthic microalgae than sandy sediments. In 1996, the presence of filter feeding bivalves increased the relative heterotrophy of sediments, measured as production: respiration. Consistent with increased heterotrophy, effluxes of ammonium and soluble reactive phosphorus from sediments were greater in mesocosms containing benthic organisms. Anthropogenically-induced changes in estuaries, such as loading of nutrients and trace elements or reduced trophic complexity, can have important effects on benthic processes and potentially pelagic processes through feedback mechanisms.     

An estuarine benthic index of biotic integrity for the Mid-Atlantic region of the United States. II. Index development

A benthic index of biotic integrity was developed for use in estuaries of the mid-Atlantic region of the United States (Delaware Bay estuary through Albemarle-Pamlico Sound). The index was developed for the Mid-Atlantic Integrated Assessment Program (MAIA) of the U.S. Environmental Protection Agency using procedures similar to those applied previously in Chesapeake Bay and southeastern estuaries, and was based on sampling in July through early October. Data from seven federal and state sampling programs were used to categorize sites as degraded or non-degraded based on dissolved oxygen, sediment contaminant, and sediment toxicity criteria. Various metrics of benthic community structure and function that distinguished between degraded and reference (non-degraded) sites were selected for each of five major habitat types defined by classification analysis of assemblages. Each metric was scored according to thresholds established on the distribution of values at reference sites, so that sites with low scoring metrics would be expected to show signs of degradation. For each habitat, metrics that correctly classified at least 50% of the degraded sites in the calibration data set were selected whenever possible to derive the index. The final index integrated the average score of the combination of metrics that performed best according to several criteria. Selected metrics included measures of productivity (abundance), diversity (number of taxa, Shannon-Wiener diversity, percent dominance), species composition and life history (percent abundance of pollution-indicative taxa, percent abundance of pollution-sensitive taxa, percent abundance of Bivalvia, Tanypodinae-Chironomidae abundance ratio), and trophic composition (percent abundance of deep-deposit feeders). The index correctly classified 82% of all sites in an independent data set. Classification efficiencies of sites were higher in the mesohaline and polyhaline habitats (81–92%) than in the oligohaline (71%) and the tidal freshwater (61%). Although application of the index to low salinity habitats should be done with caution, the MAIA index appeared to be quite reliable with a high likelihood of correctly identifying both degraded and non-degraded conditions. The index is expected to be of great utility in regional assessments as a tool for evaluating the integrity of benthic assemblages and tracking their condition over time.     

湖泊沉积物中胶黄铁矿的鉴出及其磁学意义

对青藏高原东部若尔盖盆地钻孔获取的湖泊沉积物进行了详细的岩石磁学调查及矿物学鉴定, 发现大量胶黄铁矿存在, 并认定其为主要的磁载体. 该矿物颗粒细小, 粒度均匀, 可能为生物化学成因. 与大量文献报道的相反, 在长期暴露于空气后, 样品中的胶黄铁矿仍未被氧化. 这可能与钻孔内该矿物被硅质胶结物包裹有关. 研究结果初步揭示了湖泊沉积物磁学研究的复杂性, 同时也为环境磁学机理的研究提供了新的线索.     

Principal axes of m-DOF structures PartⅠ:Static loading

This paper is the first in a two-part series that discusses the principal axes of M-DOF structures subjected to static and dynamic loads. The primary purpose of this series is to understand the magnitude of the dynamic response of structures to enable better design of structures and control modification devices/systems. Under idealized design conditions, the structural responses are obtained by using single direction input ground motions in the direction of the intended control devices/systems,and by assuming that the responses of the structure is decoupleable in three mutually perpendicular directions. This standard practice has been applied to both new and retrofitted structures using various seismic protective systems. Very limited information is available on the effects of neglecting the impact of directional couplings (cross effects - of which torsion is a component) of the dynamic response of structures. In order to quantify such effects, it is necessary to examine the principal axes of structures under both static and dynamic loading.This first paper deals with quantitative definitions of principal axes and "cross effects" of three-dimensional structures under static load by using linear algebra. It shows theoretically that, for three-dimensional structures, such principal axes rarely exist. Under static loading conditions, the cross effect is typically small and negligible from the viewpoint of engineering applications. However, it provides the theoretical base for subsequent quantification of the response couplings under dynamic loads, which is reported in part Ⅱ of this series.     

The El Salvador earthquakes of January and February 2001: context, characteristics and implications for seismic risk

The small Central American republic of El Salvador has experienced, on average, one destructive earthquake per decade during the last hundred years. The latest events occurred on 13 January and 13 February 2001, with magnitudes M_w 7.7 and 6.6, respectively. The two events, which were of different tectonic origin, follow the patterns of the seismicity of the region although neither event has a known precedent in the earthquake catalogue in terms of size and location. The earthquakes caused damage to thousands of traditionally built houses and triggered hundreds of landslides, which were the main causes of fatalities. The earthquakes have clearly demonstrated trends of increasing seismic risk in El Salvador due to rapid population expansion in areas of high shaking and landslide hazard, exacerbated by deforestation and uncontrolled urbanisation. The institutional mechanisms required for the control of land use and building practice are very weak and present a major obstacle to risk mitigation.