Ultrasonic Velocities, Acoustic Emission Characteristics and Crack Damage of Basalt and Granite

Acoustic emissions (AE), compressional (P), shear (S) wave velocities, and volumetric strain of Etna basalt and Aue granite were measured simultaneously during triaxial compression tests. Deformation-induced AE activity and velocity changes were monitored using twelve P-wave sensors and eight orthogonally polarized S-wave piezoelectric sensors; volumetric strain was measured using two pairs of orthogonal strain gages glued directly to the rock surface. P-wave velocity in basalt is about 3 km/s at atmospheric pressure, but increases by > 50% when the hydrostatic pressure is increased to 120 MPa. In granite samples initial P-wave velocity is 5 km/s and increases with pressure by < 20%. The pressure-induced changes of elastic wave speed indicate dominantly compliant low-aspect ratio pores in both materials, in addition Etna basalt also contains high-aspect ratio voids. In triaxial loading, stress-induced anisotropy of P-wave velocities was significantly higher for basalt than for granite, with vertical velocity components being faster than horizontal velocities. However, with increasing axial load, horizontal velocities show a small increase for basalt but a significant decrease for granite. Using first motion polarity we determined AE source types generated during triaxial loading of the samples. With increasing differential stress AE activity in granite and basalt increased with a significant contribution of tensile events. Close to failure the relative contribution of tensile events and horizontal wave velocities decreased significantly. A concomitant increase of double-couple events indicating shear, suggests shear cracks linking previously formed tensile cracks.     

Crustal age domains and metamorphic reworking of the deep crust in Northern-Central Tanzania: a U/Pb zircon and monazite age study

Geochronological data are presented from Northern Tanzania, where deep-crustal terranes of different age are exposed. Stacking of these terranes was diachronous with one peak around 640 Ma, defined as East African Orogeny, and final consolidation at 550–580 Ma, that is defined as Kuunga Orogeny. This later event is predominant in the Western Granulite Belt of northern Tanzania and related to thrusting onto the Tanzanian Craton. The Tanzania Craton itself experienced a polycyclic history; age domains around 2.64 Ga prevail in the studied samples. There is no evidence of the Paleoproterozoic Usagaran Belt in northern Tanzania. Here the gneisses contain relicts of reworked Archean basement and are therefore considered part of the Western Granulites. Inliers of the Western Granulites are also found in the cores of marble antiforms that are part of the upper, sedimentary sequence of the Eastern Granulites. Those inliers formed during the Kuungan orogenic phase when the Eastern Granulites have taken their final position and were folded together with the Western Granulites.     

Fluvial and permafrost history of the lower Lena River,north-eastern Siberia,over late Quaternary time

Arctic warming and permafrost thaw visibly expose changes in the landscape of the Lena River delta, the largest Arctic delta. Determining the past and modern river regime of thick deltaic deposits shaping the Lena River mouth in north-eastern Siberia is critical for understanding the history of delta formation and carbon sequestration. Using a 65 m long sediment core from the delta apex a set of sedimentological techniques is applied to aid in reconstructing the Lena River history. The analysis includes: (i) grain-size measurements and the determination of the bedload composition; (ii) X-ray fluorescence, X-ray diffractometry, and magnetic susceptibility measurements and heavy mineral analysis for tracking mineral change; (iii) pH, electrical conductivity, ionic concentrations, and the δ¹⁸O and δD stable isotope composition from ground ice for reconstructing permafrost formation. In addition; (iv) total and dissolved organic carbon is assessed. Chronology is based on; (vi) radiocarbon dating of organic material (accelerator mass spectrometry and conventional) and is complemented by two infrared – optically stimulated luminescence dates. The record stretches back approximately to Marine Isotope Stage 7. It holds periods from traction, over saltation, to suspension load sedimentation. Minerogenic signals do not indicate provenance change over time. They rather reflect the change from high energy to a lower energy regime after Last Glacial Maximum time parallel to the fining-up grain-size trend. A prominent minimum in the ground ice stable isotope record at early Holocene highlights that a river arm migration and an associated refreeze of the underlying river talik has altered the isotopic composition at that time. Fluvial re-routing might be explained by internal dynamics in the Lena River lowland or due to a tectonic movement, since the study area is placed in a zone of seismic activity. At the southern Laptev Sea margin, onshore continental compressional patterns are bordering offshore extensional normal faults.     

115 years of sediment deposition in a reservoir in Central Europe: Topographic change detection

Reservoirs have become an important component in the worldwide river sediment flux. Reservoirs prevent downstream sediment transport and have become a major sediment sink. In this study, sediment deposition during the last 115 years in the Urft Reservoir in western Germany is reconstructed. The Urft Reservoir is the oldest reservoir in the Eifel Mountains and was almost completely drained in 2020. This enabled a detailed mapping of the lake bottom using an unmanned aerial system and the computation of a high-resolution digital surface model. Topographic maps with a nominal resolution of 1:1000 from the time prior to the construction of the dam (around 1900) were used to construct a pre-reservoir elevation model. A digital elevation model of difference (DoD) was calculated from these two datasets for the reservoir floor (0.72 km²). Based on the DoD, a net sediment accumulation of 1.16 × 10⁶ m³ was calculated alongside a propagated volume error of 6.91 × 10⁵ m³, resulting in a mean accumulation of 1.54 m. Conservative vertical error propagation results in an average level of detection (LoD) of 1.8 m. In contrast, the comparison of the DoD with 47 cores in the upper part of the reservoir showed a mean difference of −0.11 m, indicating a high, independently assessed accuracy of the DoD. Three depositional hotspots were identified in the reservoir. One is close to the Urft dam where very fine sediments are draped across the pre-reservoir topography. Two areas are related to reservoir management. Sediment deposition in the Urft Reservoir has been comparably low in comparison to other regions globally, resulting in a 3.25% ± 1.93% loss of reservoir volume between 1905 and 2020. To analyse the effect of strong flooding events, a subset of the reservoir was analysed after an extreme event in July 2021, but accumulation did almost entirely not exceed the LoD.     

Volcanic arcs as archives of plate tectonic change

Processing of the oceanic lithosphere in subduction zones gives rise to arc magmatism, and strong compositional links exist between trench input and arc output. Here we address the question whether these compositional links are sufficiently strong to allow for ‘tracing’ the composition of the sedimentary and igneous oceanic crust through the chemistry of arcs. The tracing approach hinges critically on whether key characteristics of the subducted slab are transmitted to arcs. Results from forward and inverse modeling, verified by observations from modern arc settings, demonstrate that elements Sr, Pb, Nd and Hf that are associated with radiogenic isotopes may preserve chemical characteristics of the subducted slab in arc magmas. The data indicate that the much thicker igneous subducted crust dominates the recycled flux to arcs. The flux from the highly enriched, but thin sediment layer is buffered, and may be even concealed, by the concomitant contributions from igneous crust, and/or subarc mantle, despite the much better visibility of sediment components in trace element and isotope space. Arc Pb and Pb isotopes are the most promising tracers that may capture the isotopic diversity of subducted MORB-type and OIB-type crust with sufficient temporal and spatial resolution. While arc Sr is also strongly controlled by the flux from the subducted crust, arc data may allow for distinguishing among radiogenic Sr recycled from altered oceanic crust or from subducted sediment in moderately radiogenic arcs (⁸⁷Sr/⁸⁶Sr < ~ 0.7045). Co-mingling of Nd and Hf from igneous subducted crust with mantle contributions mostly hinders the isotopic identification of subducted crust through arc chemistry. However, Nd and Hf may provide complementary information about the efficiency of recycling, and recycling via subduction erosion.The tracing approach appears feasible in Cenozoic arcs where much of the original subduction context is preserved. First results from the Izu Bonin and Central American arcs show that plate tectonic events like oceanic plate formation and destruction, subduction of hotspot tracks and the closure of oceanic gateways are recorded in the chemistry of arcs. A comparative evaluation of Cenozoic global arcs may hence significantly complement the information from the modern oceanic basins, help to obtain a more complete image of the oceanic crustal composition and implicate the geochemical processes by which it formed. Possibly, the tracing approach may also be useful in ancient, inactive arcs to obtain information on the composition of oceanic crust subducted in the geological past.     

Development of a conceptual hydrogeological model for the evaluation of residence times of water in soil and groundwater: the state of Hesse case study, Germany

A regional conceptual hydrogeological model has been developed for evaluating residence times of both, percolate water in the unsaturated zone and groundwater in upper aquifers. The model is based on digitally geo-data bases available at the regional level and has been applied for the entire Federal State of Hesse (Germany) with a spatial resolution of 60?×?60?m. Residence times determined for unconsolidated rock areas typically ranged between 10 and 25?years, whereas residence times of <5?years were assessed for consolidated rock areas. With regard to the implementation of the EU Water Framework Directive, the determined residence times may help to assess the time periods between the introduction of well-targeted groundwater protection measures and their impact on groundwater and surface water quality, respectively.     

On some measurements of the condensation of different vapors upon Aitken condensation nuclei

No final theory on the activity of Aitken nuclei has been established yet. In particular the supersaturation is not known for the Aitken nuclei to grow into droplets, f.e. according toF. Volz only nuclei of radius >0.1 can cause condensation under atmospheric conditions. On the other hand according toH. G. Müller condensation over the continents has to occur at the Aitken nuclei since precipitation washes out the other nuclei.This uncertainty becomes obvious in the interpretation of the experimental results.Chr. Junge found that the necessary activation supersaturation of a continental Aitken aerosol and of artificial aerosols of the same size of nuclei lies between 2 and 20%, 10% being sufficient for the main fraction of nuclei to grow.In contrastW. Wieland was able to activate in a mixing cloud chamber a big portion, if not all, of the nuclei of a continental aerosol at supersaturations below 1.5%. Some of our own results, obtained with the same technic, agree with this. At supersaturations below 0.8% at least half of the Aitken nuclei present are activated. To obtain the same result with benzene and acetone we found, that benzene required a slightly smaller, and acetone a somewhat bigger supersaturation.However later experiments revealed a considerable effect of the geometry of the mixing cloud chamber upon the results. Since the physics of the chamber has not been fully explored the method was abandoned. Instead the principle of cooling by adiabatic expansion was used. An expansion apparatus based on the principle of a fotoelectric nucleus counter was developed allowing us to measure with two cathode ray oscillographs the pressure and simultaneously the change of intensity of a lightbeam due to the scattering on the forming cloud as a function of time. The length of the lightbeam could be chosen between 60 and 200 cm. The overpressure before the expansion was always 180 mm of mercury. The ratio of expansion rates was 12.53060 at the beginning of the expansion. The slowest rate was about 6 seconds, corresponding to a rate of ascent of 210 m/s at the beginning of the expansion. Smaller rates could not be obtained because of heat transfer at the chamber walls.The present work has been performed for the Eidgenössische Kommission zum Studium der Hagelbildung und der Hagelabwehr (Switzerland) at the research station Osservatorio Ticinese Locarno-Monti della Centrale Meteorologica Svizzera     

A procedure to identify natural arsenic sources,applied in an affected area in North Rhine-Westphalia,Germany

The aim of the study was to identify the geogenic source for elevated arsenic (As) concentrations recently discovered in soils of the Heubach plain, North Rhine-Westphalia, Germany. Therefore, a catalogue of conditions that an As source has to fulfil in order to be considered as geogenic was formulated, including the source’s linkage to the sink, its mineralogy, As total content, As mobilization potential, groundwater redox conditions and As output. Accordingly, mineralogical, geo- and hydrochemical investigations were carried out, including X-ray diffractometry, microscopy, ICP-OES and AAS analysis and a sequential extraction procedure. Paleo bog iron ores (PBIOs) of Tertiary age, occurring within unconsolidated sands (Haltern-layers, Santonian–Lower Campanian), and glauconitic marlstones (Dülmen-layers, Lower Campanian) were examined. Results indicate that output from the PBIOs is responsible for the elevated As levels. Accounting their diverse mineralogy, five types of PBIOs were defined. Type-dependent, they at least partly fulfil all of the formulated requirements. The relations and behaviour of As sources and sinks in space and time could be clarified for the area of interest. The approach presented in this paper may offer a tool for identifying natural As sources worldwide.     

Coupled anion substitution in natural carbon-bearing apatites

Reliable wet chemical methods of minor element analysis (F, Cl, OH) and X-ray diffraction studies reveal that a coupled substitution of fluorine and carbonate is required in natural carbon-bearing apatites. Thus, CO ₃ ^2– · F^–replaces PO ₄ ^3– with tetravalent carbon substituting for pentavalent phosphorus and a halogen in excess replacing one O^2– to give: Ca₁₀ [(PO₄)_6–x(CO₃·F)_x](F, OH, Cl)₂ The coupled substitution not only maintains the electrical neutrality of the structure, but also retains the tetrahedral coordination for the cations involved. The resulting variation in the unit cell parameter a_o corresponds well with the proposed geometrical model: partial replacement of P⁵⁺ (ionic radius 0.35Å) by the smaller C⁴⁺ (0.16 Å) ion reduces the lateral distance between the Ca-O trigonal prism columns, thus shortening the length of the a_o cell edge. The replacement of P by C does not have a significant effect on the cell dimension c_o which is mainly determined by the distance of the Ca- and O-triangles and is not influenced directly by minor substitutions of C for P. Our investigations suggest a carbonate apatite (francolite) with a stoichiometric chemical formula. The nature of the anion configuration is emphasized in this paper.