Hydraulic zonation of the lagoons of Marano and Grado,Italy. A modelling approach

The hydraulic regime-based zonation scheme of the Lagoons of Marano and Grado (Italy) has been derived by means of numerical models. A finite element modelling system has been used to describe the water circulation taking in account different forces such as tide, wind and rivers. The model has been validated by comparing the simulation results against measured water levels, salinity and water temperature data collected in several stations inside the lagoons. The analysis of water circulation, salinity and spatial distribution of passive tracers released at the inlets, led to a physically-based division of the lagoons system into six subbasins. The derived classification scheme is of crucial value for understanding the renewal capacity and pollutants distribution patterns in the lagoon.     

Multiple drivers of Holocene lake level changes at a lowland lake in northeastern Germany

Many German lakes experienced significant water level declines in recent decades that are not fully understood due to the short observation period. At a typical northeastern German groundwater‐fed lake with a complex basin morphology, an acoustic sub‐bottom profile was analysed together with a transect of five sediment cores, which were correlated using multiple proxies (sediment facies, μ‐XRF, macrofossils, subfossil Cladocera). Shifts in the boundary between sand and mud deposition were controlled by lake level changes, and hence, allowed the quantification of an absolute lake level amplitude of ~8 m for the Holocene. This clearly exceeded observed modern fluctuations of 1.3 m (AD 1973–2010). Past lake level changes were traced continuously using the calcium‐record. During high lake levels, massive organic muds were deposited in the deepest lake basin, whereas lower lake levels isolated the sub‐basins and allowed carbonate deposition. During the beginning of the Holocene (>9700 cal. a BP), lake levels were high, probably due to final melting of permafrost and dead‐ice remains. The establishment of water‐use intensive Pinus forests caused generally low (3–4 m below modern) but fluctuating lake levels (9700–6400 cal. a BP). Afterwards, the lake showed an increasing trend and reached a short‐term highstand at c. 5000 cal. a BP (4 m above modern). At the transition towards a cooler and wetter late Holocene, forests dominated by Quercus and Fagus and initial human impact probably contributed more positively to groundwater recharge. Lake levels remained high between 3800 and 800 cal. a BP, but the lake system was not sensitive enough to record short‐term fluctuations during this period. Lake level changes were recorded again when humans profoundly affected the drainage system, land cover and lake trophy. Hence, local Holocene water level changes reflect feedbacks between catchment and vegetation characteristics and human impact superimposed by climate change at multiple temporal scales.     

Sample return of interstellar matter (SARIM)

The scientific community has expressed strong interest to re-fly Stardust-like missions with improved instrumentation. We propose a new mission concept, SARIM, that collects interstellar and interplanetary dust particles and returns them to Earth. SARIM is optimised for the collection and discrimination of interstellar dust grains. Improved active dust collectors on-board allow us to perform in-situ determination of individual dust impacts and their impact location. This will provide important constraints for subsequent laboratory analysis. The SARIM spacecraft will be placed at the L2 libration point of the Sun–Earth system, outside the Earth’s debris belts and inside the solar-wind charging environment. SARIM is three-axes stabilised and collects interstellar grains between July and October when the relative encounter speeds with interstellar dust grains are lowest (4 to 20 km/s). During a 3-year dust collection period several hundred interstellar and several thousand interplanetary grains will be collected by a total sensitive area of 1 m². At the end of the collection phase seven collector modules are stored and sealed in a MIRKA-type sample return capsule. SARIM will return the capsule containing the stardust to Earth to allow for an extraction and investigation of interstellar samples by latest laboratory technologies.     

DuneXpress

The DuneXpress observatory will characterize interstellar and interplanetary dust in-situ, in order to provide crucial information not achievable with remote sensing astronomical methods. Galactic interstellar dust constitutes the solid phase of matter from which stars and planetary systems form. Interplanetary dust, from comets and asteroids, represents remnant material from bodies at different stages of early solar system evolution. Thus, studies of interstellar and interplanetary dust with DuneXpress in Earth orbit will provide a comparison between the composition of the interstellar medium and primitive planetary objects. Hence DuneXpress will provide insights into the physical conditions during planetary system formation. This comparison of interstellar and interplanetary dust addresses directly themes of highest priority in astrophysics and solar system science, which are described in ESA’s Cosmic Vision. The discoveries of interstellar dust in the outer and inner solar system during the last decade suggest an innovative approach to the characterization of cosmic dust. DuneXpress establishes the next logical step beyond NASA’s Stardust mission, with four major advancements in cosmic dust research: (1) analysis of the elemental and isotopic composition of individual interstellar grains passing through the solar system, (2) determination of the size distribution of interstellar dust at 1 AU from 10^− 14 to 10^− 9 g, (3) characterization of the interstellar dust flow through the planetary system, (4) establish the interrelation of interplanetary dust with comets and asteroids. Additionally, in supporting the dust science objectives, DuneXpress will characterize dust charging in the solar wind and in the Earth’s magnetotail. The science payload consists of two dust telescopes of a total of 0.1 m² sensitive area, three dust cameras totaling 0.4 m² sensitive area, and a nano-dust detector. The dust telescopes measure high-resolution mass spectra of both positive and negative ions released upon impact of dust particles. The dust cameras employ different detection methods and are optimized for (1) large area impact detection and trajectory analysis of submicron sized and larger dust grains, (2) the determination of physical properties, such as flux, mass, speed, and electrical charge. A nano-dust detector searches for nanometer-sized dust particles in interplanetary space. A plasma monitor supports the dust charge measurements, thereby, providing additional information on the dust particles. About 1,000 grains are expected to be recorded by this payload every year, with 20% of these grains providing elemental composition. During the mission submicron to micron-sized interstellar grains are expected to be recorded in statistically significant numbers. DuneXpress will open a new window to dusty universe that will provide unprecedented information on cosmic dust and on the objects from which it is derived.     

Hydrogeology of the Kabul Basin (Afghanistan), part II: groundwater geochemistry

Shallow groundwater is the main source for drinking water in Kabul, Afghanistan. It comes from a multitude of shallow hand-pumped wells spread over the whole city area. The groundwater is characterised by slightly oxic redox conditions. Interactions with aquifer carbonates lead to near-neutral pH and high degrees of hardness. The mostly negative water budget of the Kabul Basin is the result of strong evaporation which leads to an increase in salt and also of some undesirable constituents, e.g. borate. Several years of drought have aggravated this problem. The shallow groundwater in the city has received tremendous amounts of pollution due to a lack of proper waste disposal and sewage treatment. Common indicators are elevated concentrations of nutrients such as nitrate and faecal bacteria. The high infant mortality can at least partially be attributed to the insufficient water hygiene. Acid generated during the mineralisation of the wastewater is hidden due to the strong pH buffering capacity of the groundwater system. Redox and pH conditions preclude significant mobilisation of trace metals and metalloids.     

Source potential and palynofacies of Late Jurassic “Lemeš facies”, Croatia

Laminated limestone and calcareous shale outcrop samples from the Late Jurassic “Leme?” facies (Croatia) were investigated to characterize their organic facies and palynofacies and their hydrocarbon generative potential. The results indicate that the organic rich sediments of “Leme?” facies were deposited within a relatively shallow marine environment at low redox potential, characterized as an oxygen depleted depositional setting with stratified bottom waters of the carbonate platform (Adriatic Carbonate Platform). The organic rich samples contain a high portion of lipid rich amorphous kerogen of algal/phytoplankton origin, enriched by bacterial biomass. Most of the analyzed samples have total organic carbon contents (TOC) greater than 3%, Rock-Eval S2 >20 mg HC/g rock, yielding Hydrogen Index (HI) values ranging from 509–602 mg HC/g TOC. According to these results, the analyzed samples have very good to excellent oil generative potential. Relatively high sulfur content suggests that the kerogen is best described as Type II-S. Biomarker maturity parameters, as well as the fluorescence of the isolated kerogen, show that the organic matter is at early to peak oil thermal maturity. The observed level of thermal maturity indicates that these samples were once buried to depths of ～5.5–5.8 km before being uplifted in the late Tertiary. The surface outcrops of the “Leme?” facies suggest that these strata have significant source potential and are the likely source of oil in the Croatian External Dinarides.     

Mineralogical impact on organic nitrogen across a long-term soil chronosequence (0.3-4100 kyr)

Large portions of organic N (ON) in soil exist tightly associated with minerals. Mineral effects on the type of interactions, chemical composition, and stability of ON, however, are poorly understood. We investigated mineral-associated ON along a Hawaiian soil chronosequence (0.3-4100 kyr) formed in basaltic tephra under comparable climatic, topographic, and vegetation conditions. Mineral-organic associations were separated according to density (ρ > 1.6 g/cm³), characterized by X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge fine structure (NEXAFS) and analyzed for amino acid enantiomers and amino sugars. The ¹⁴C activity of mineral-bound OC was estimated by accelerator mass spectrometry. The close OC-ON relationship (r = 0.96) and XPS results suggest that ON exists incorporated in bulk mineral-bound OM and likely becomes associated with minerals as part of sorbing OM. The youngest site (0.3 kyr), with soils mainly composed of primary minerals (olivine, pyroxene, feldspar) and with little ON, contained the largest proportion of hydrolyzable amino sugars and amino acids but with a small share of acidic amino acids (aspartic acid, glutamic acid). In soils of the intermediate weathering stage (20-400 kyr), where poorly crystalline minerals and metal(hydroxide)-organic precipitates prevail, more mineral-associated ON was present, containing a smaller proportion of hydrolyzable amino sugars and amino acids due to the preferential accumulation of other OM components such as lignin-derived phenols. Acidic amino acids were more abundant, reflecting the strong association of acidic organic components with metal(hydroxide)-organic precipitates and variable-charge minerals. In the final weathering stage (1400-4100 kyr) with well-crystalline secondary Fe and Al (hydr)oxides and kaolin minerals, mineral-organic associations held less ON and were, relative to lignin phenols, depleted in hydrolyzable amino sugars and amino acids, particularly in acidic amino acids. XPS and NEXAFS analyses showed that the majority (59-78%) of the mineral-associated ON is peptide N while 18-34% was aromatic N. Amino sugar ratios and d-alanine suggest that mineral-associated ON comprises a significant portion of bacterial residues, particularly in the subsoil. With increasing ¹⁴C age, a larger portion of peptide N was non-hydrolyzable, suggesting the accumulation of refractory compounds with time. The constant d/l ratios of lysine in topsoils indicate fresh proteinous material, likely due to continuous sorption of or exchange with fresh N-containing compounds. The ¹⁴C and the d/l signature revealed a longer turnover of proteinous components strongly bound to minerals (not NaOH-NaF-extractable). This study provides evidence that interactions with minerals are important in the transformation and stabilization of soil ON. Mineral-associated ON in topsoils seems actively involved in the N cycling of the study ecosystems, accentuating N limitation at the 0.3-kyr site but increasing N availability at older sites.     

The 410,000 year terrestrial age of eucrite Río Cuarto 001

Abstract— We have measured a surprisingly long terrestrial age of 410,000 ±_45,00^20,000 yr (410 ±₂₀⁴⁵ka) for basaltic eucrite Río Cuarto 001 using accelerator mass spectrometry of ²⁶Al, ³⁶Cl, and ⁴¹Ca. Though many meteorites are known to have survived for tens or hundreds of ka in Antarctica or hot deserts, the mean annual precipitation of 815 mm in Río Cuarto, Cordoba Province, Argentina, makes the long survival of this meteorite remarkable. We propose two explanations for the exceptional preservation of Río Cuarto 001. First, the meteorite contains only trace amounts of metal, so the weathering and oxidation of metallic Fe, which commonly destroys chondrites, is ineffective in this case. Second, the meteorite was found in a relatively young deflation basin, and may have been exhumed only recently from beneath a protective layer of soil. Insofar as the survival on Earth of Río Cuarto 001 is due to environmental factors, there may be other meteorites with comparably long terrestrial ages still to be discovered in the vicinity.     

Neoendemic ground beetles and private tree haplotypes: two independent proxies attest a moderate last glacial maximum summer temperature depression of 3–4 °C for the southern Tibetan Plateau

Previous findings regarding the Last Glacial Maximum LGM summer temperature depression (maxΔT in July) on the Tibetan Plateau varied over a large range (between 0 and 9 °C). Geologic proxies usually provided higher values than palynological data. Because of this wide temperature range, it was hitherto impossible to reconstruct the glacial environment of the Tibetan Plateau. Here, we present for the first time data indicating that local neoendemics of modern species groups are promising proxies for assessing the LGM temperature depression in Tibet. We used biogeographical and phylogenetic data from small, wingless edaphous ground beetles of the genus Trechus, and from private juniper tree haplotypes. The derived values of the maxΔT in July ranged between 3 and 4 °C. Our data support previous findings that were based on palynological data. At the same time, our data are spatially more specific as they are not bound to specific archives. Our study shows that the use of modern endemics enables a detailed mapping of local LGM conditions in High Asia. A prerequisite for this is an extensive biogeographical and phylogenetic exploration of the area and the inclusion of additional endemic taxa and evolutionary lines.     

Global,regional and local scale factors determining glaciation extent in Eastern Siberia over the last 140,000 years

The aim of this work is to evaluate the effect of variations of greenhouse gas concentrations, orbital parameters, sea-surface conditions, vegetation and dust deposition on the extent of East Siberian mountain glaciations during the late Quaternary. An atmosphere-only general circulation model is used in a series of 16 sensitivity tests at high spatial resolution over the region of interest to systematically evaluate the relative importance of these different forcing parameters. No attempt was made to reproduce in detail the history of late Quaternary mountain glaciations in East Siberia, because, given (a) the temporal and spatial scarcity of available evidence of mountain glaciations in this region and (b) the large uncertainties concerning the boundary conditions to be prescribed in this model, such an exercise must necessarily remain incomplete and partially inconclusive. The results of this study suggest that moisture delivery from the Atlantic is an important factor determining mountain glacier mass balance in Eastern Siberia and is very sensitive to the geometry of the West Eurasian ice sheet. This means that variable moisture blocking by the West Eurasian ice sheet during the Weichselian is the most important single factor explaining the opposite history of glacier and ice sheet extent in West and East Eurasia during the Weichselian. This work confirms earlier results showing that the large 140 kyr BP West Eurasian ice sheet caused regional-scale cooling extending towards Eastern Eurasia. Nevertheless, the simulated response of the regional summer temperature (and thus glacier extent because of the strong dependency of glacier mass balance of summer melt rates) is to a very large extent directly determined by insolation. For the Early Weichselian, this leads to a clear maximum of local glacier extent at 70 kyr BP, which is in line with the variations of top-of-the-atmosphere insolation on orbital time scales, but to some degree at odds with geological evidence which suggests larger glacier extent at 115 and 90 kyr BP than at 70 kyr BP. Through snow feedbacks, the effects of changes in the prescribed vegetation distribution and dust deposition rate are also substantial. In summary, it appears that the broad features of late Quaternary glaciation history in Eastern Eurasia can be understood in terms of known forcings.