时间剖面上小断层的计算机自动检测

煤田地震勘探一直探寻着对小断层的自动检测方法，因受各种因素的影响，至今尚无良策。本文介绍了多元地震参数的模式识别方法，并通过模型及实测资料成功地检测到１０ｍ以下小断层。     

华南西部晚二叠世碳同位素地层学研究

对黔桂地区７条晚二叠世碳酸盐岩型煤系剖面进行了碳酸盐岩碳氧同位素测定，发现晚二叠世吴家坪阶与长兴阶碳酸盐岩的δ１３Ｃ值有明显差异，前者δ１３Ｃ多大于３．０‰，后者多小于３．０‰，进一步对晚二叠世δ１３Ｃ的变化原因的分析表明，δ１３Ｃ的变化可能与晚古生代末期聚煤作用的减弱密切相关，后者造成自然界碳库中的１２Ｃ的富集，从而使得海水以及在其中沉淀出的碳酸盐岩中的δ１３Ｃ值降低。此外，植物光合作用从大气中吸收ＣＯ２的量也随陆地植被减少而减少，结果造成大气中的ＣＯ２的大量富集，从而进一步产生温室效应，制约生物界的发展。联系到这一阶段生物界的衰亡灭绝，可以认为温室效应是晚二叠世生物逐渐衰亡及晚二叠世末群体灭绝的主要原因之一。     

冀西北麻粒岩区早前寒武纪主要地质事件的年代格架

本文通过年代学资料和其它地质依据建立了冀西北及邻区麻粒岩地体早前寒武纪主要地质事件的年代格架。早期的基性火山喷发事件发生在2868—2932Ma期间,形成本区的早期地壳。在2761Ma左右发生了大规模的TTG岩浆侵位事件,在2650Ma时发生了基性岩浆侵位,使地壳加厚。在2561—2503Ma期间,花岗闪长质岩浆在本区广泛侵入,使地壳进一步加厚。2477—2461Ma期间,紫苏花岗岩以岩株形式侵入,同时发生区域麻粒岩相变质,早期地壳受到改造。大约在2300Ma时发生第二阶段的麻粒岩相变质。此后,在2144—2087Ma期间红色花岗岩侵位,形成花岗岩带。     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

新疆喀纳斯国家地质公园旅游资源及评价

新疆喀纳斯国家地质公园是以第四纪冰川遗迹为主要特色的综合性国家地质公园。本文对公园内的旅游资源进行了概要介绍，并对其作了定性评价，认为园区内旅游资源类型多样，功能齐全，极具科考、旅游观光和科普教育价值。     

Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.     

The influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes in pyrolysates of selected terrestrial kerogens

Expulsion of petroleum from source rock is a complex part of the entire migration process. There exist fractional effects on chemical compositions in hydrocarbon expulsion. Does the carbon isotopic fractionation occur during expulsion and to what extent? Here the influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes from pyrolysates of selected terrestrial kerogens from Tuha basin and Fushun, Liaoning Province of China has been experimentally studied. The pyrogeneration-expulsion experiments were carried out under semi-closed system. The carbon isotopic compositions of individual n-alkanes were measured by GC-IRMS. The main conclusions are as follows. First, there is carbon isotopic fractionation associated with hydrocarbon expulsion from Type III kerogens in Tuha Basin. There exist differences of carbon isotopic compositions between the unexpelled n-alkanes and expelled n-alkanes from Tuha desmocollinite and Tuha mudstone. Second, there is almost no carbon isotopic fractionation associated with hydrocarbon expulsion from Type II kerogens in Fushun and Liaohe Basin. Third, carbon isotopic fractionation in hydrocarbon expulsion should be considered in making oil-source correlation of Type III kerogens at least in the Tuha Basin. Further studies need to be carried out to determine whether this is true in other basins. Fourth, oil and source at different maturity levels cannot be correlated directly for Type III kerogens since the carbon isotopic compositions of expelled hydrocarbons at different temperatures are different. The expelled hydrocarbons are usually lighter (depleted in ¹³C) than the hydrocarbons remaining in the source rock at the same maturity.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

黄土区人类活动影响下的 产汇流模拟研究

日益频繁的人类活动改变了流域下垫面条件,对流域产汇流产生很大的影响。本文以黄河中游典型支流岔巴沟为研究区域,提出利用基于DEM的分布式水文模拟技术,探讨流域人类活动过程中的产汇流模拟,避免了经验公式的概化和由此引起的局限。模拟的结果证实了该方法的可行性。采用网格滞蓄的方法可以在子网格上体现人类活动引起的下垫面的变化及其对产汇流的影响,反映各个时期的产汇流条件,对降雨做出合理响应。     

Impact of the Pacific–Japan Teleconnection Pattern on July Sea Fog over the Northwestern Pacific: Interannual Variations and Global Warming Effect

The northwestern Pacific(NWP) is a fog-prone area, especially the ocean east of the Kuril Islands. The present study analyzes how the Pacific–Japan(PJ) teleconnection pattern influences July sea fog in the fog-prone area using independent datasets. The covariation between the PJ index and sea fog frequency(SFF) index in July indicates a close correlation, with a coefficient of 0.62 exceeding the 99% confidence level. Composite analysis based on the PJ index, a case study, and model analysis based on GFDL-ESM2 M, show that in high PJ index years the convection over the east of the Philippines strengthens and then triggers a Rossby wave, which propagates northward to maintain an anticyclonic anomaly in the midlatitudes,indicating a northeastward shift of the NWP subtropical high. The anticyclonic anomaly facilitates the formation of relatively stable atmospheric stratification or even an inversion layer in the lower level of the troposphere, and strengthens the horizontal southerly moisture transportation from the tropical–subtropical oceans to the fog-prone area. On the other hand, a greater meridional SST gradient over the cold flank of the Kuroshio Extension, due to ocean downwelling, is produced by the anticyclonic wind stress anomaly. Both of these two aspects are favorable for the warm and humid air to cool, condense, and form fog droplets, when air masses cross the SST front. The opposite circumstances occur in low PJ index years, which are not conducive to the formation of sea fog. Finally, a multi-model ensemble mean projection reveals a prominent downward trend of the PJ index after the 2030 s, implying a possible decline of the SFF in this period.