Novel C15 sesquiterpanes in Niger Delta oils: Structural identification and potential application as new markers of angiosperm input in light oils

Two new C₁₅ sesquiterpanes have been isolated from a Niger Delta oil. Based on nuclear magnetic resonance (NMR) data, their structures are similar to the ring D and E part of oleanane. The mass spectra show an m/z 193 base peak typical of rearranged drimanes. They have been found only in oleanane-containing oils with a Cretaceous or Tertiary source. Data are presented for 34 such oils from Angola, Canada, Greece, India, Indonesia, Iran, New Zealand, Nigeria, Thailand and Vietnam. The ratio between the new sesquiterpanes and rearranged drimanes roughly follows the oleanane index. They are absent from marine oils whose source rock age (Jurassic or older) predates the evolution and proliferation of angiosperms. They are probably formed via degradation of functionalized oleanoids or by cleavage of seco-oleananes. These sesquiterpanes may be useful as markers of angiosperm input in light oils (jet fuel, diesel or condensates) usually devoid of higher molecular weight markers for higher plant input.     

A geochemical study of island-arc and back-arc tholeiites from the Scotia Sea

⁸⁷Sr/⁸⁶Sr and¹⁴³Nd/¹⁴⁴Nd ratios, REE and selected minor and trace elements are presented and compared for present-day volcanic rocks in the Scotia Sea.Tholeiitic basalts from the South Sandwich Islands show widely ranging contents of some lithophile elements, e.g. K₂O (0.09–0.55%) and Rb (1.55–14.2 ppm), but fairly constant Na₂O and Sr. Total REE contents range from about 4–20 times chondritic abundances with significant light-REE depletion and both positive and negative Eu anomalies. The variations in minor and trace element abundances are consistent with low-pressure fractional crystallization of plagioclase and clinopyroxene but only minor amounts of olivine. The⁸⁷Sr/⁸⁶Sr and¹⁴³Nd/¹⁴⁴Nd ratios of the parental magmas are thought be 0.7038–0.7039 and 0.51301–0.51314 respectively, and indicate derivation of at least some⁸⁷Sr from subducted ocean crust.The back-arc tholeiites in the Scotia Sea have lower⁸⁷Sr/⁸⁶Sr ratios (0.7028–0.7033), similar¹⁴³Nd/¹⁴⁴Nd ratios (0.51305) and are variably light-REE-enriched(Ce_N/Yb_N= 1.0–1.6). Total REE contents are comparable to those of the South Sandwich Islands tholeiites.     

Brood patch temperature during provocation of common eiders in Ny-Ålesund, Svalbard

In this short note we describe the behaviour and body changes of three incubating female common eiders ( Somateria mollissima ) during provocation made by humans approaching the nest. The study site was near the settlement of Ny-Ålesund, Svalbard. Temperture transmitters were implanted subcutaneously at the brood patch and data recorded using a VHF receiver. We found that the female experiment exhibited a passive defence response ("freezing"), accompanied by a significant drop in brood patch temperature (0.6 °C) during provocation; this temperature drop lasted for 5 minutes. These accord with other studies of the physiological changes which the passive defence response in birds and other animals.     

Contemporary rates of chemical denudation and atmospheric CO2 sequestration in glacier basins: an Arctic perspective

This paper presents new estimates of solute fluxes from five high Arctic glacier basins in Svalbard. These estimates are combined with data from two other glacier basins to assess the effectiveness of chemical denudation on Svalbard and to estimate rates of temporary (or transient) CO₂ drawdown. We use a solute provenance model to partition solutes into marine, aerosol, atmospheric and crustal components and to estimate their annual fluxes. Crustally derived solute fluxes are equivalent to a mean chemical denudation rate of 350 Σmeq⁺ m⁻² a⁻¹ for Svalbard (range: 160–560 Σmeq⁺ m⁻² a⁻¹), which lies within the global range of 94–4200 Σmeq⁺ m⁻² a⁻¹ for 21 glacier basins in the northern hemisphere, and is close to the continental average of 390 Σmeq⁺ m⁻² a⁻¹. Specific annual discharge is the most significant control upon chemical denudation in the glacierized basins, and basin lithology is an important secondary control, with carbonate‐rich and basaltic lithologies currently showing the greatest chemical denudation rates. Estimates of transient CO₂ drawdown are also directly associated with specific annual discharge and rock type. On Svalbard transient CO₂ drawdown lies in the range 110–3000 kg C km⁻² a⁻¹, whilst the range is 110–13000 kg C km⁻² a⁻¹ for the northern hemisphere glacial data set. Transient CO₂ drawdown is therefore usually low in the Svalbard basins unless carbonate or basalt rocks are abundant. The analysis shows that a large area of uncertainty in the transient CO₂ drawdown estimates exists due to the non‐stoichiometric release of solute during silicate hydrolysis. Silicate hydrolysis is particularly non‐stoichiometric in basins where the extent of glacierization is high, which is most probably an artefact of high flushing rates through ice‐marginal and subglacial environments where K‐feldspars are undergoing mechanical comminution. Copyright © 2000 John Wiley & Sons, Ltd.     

Comparing the adaptive Gaussian mixture filter with the ensemble Kalman filter on synthetic reservoir models

Over the last years, the ensemble Kalman filter (EnKF) has become a very popular tool for history matching petroleum reservoirs. EnKF is an alternative to more traditional history matching techniques as it is computationally fast and easy to implement. Instead of seeking one best model estimate, EnKF is a Monte Carlo method that represents the solution with an ensemble of state vectors. Lately, several ensemble-based methods have been proposed to improve upon the solution produced by EnKF. In this paper, we compare EnKF with one of the most recently proposed methods, the adaptive Gaussian mixture filter (AGM), on a 2D synthetic reservoir and the Punq-S3 test case. AGM was introduced to loosen up the requirement of a Gaussian prior distribution as implicitly formulated in EnKF. By combining ideas from particle filters with EnKF, AGM extends the low-rank kernel particle Kalman filter. The simulation study shows that while both methods match the historical data well, AGM is better at preserving the geostatistics of the prior distribution. Further, AGM also produces estimated fields that have a higher empirical correlation with the reference field than the corresponding fields obtained with EnKF.     

The Norwegian plan for integrated ecosystem-based management of the marine environment in the Norwegian Sea

A White Paper on a new integrated management plan for the Norwegian Sea was launched by the Norwegian government in May 2009. Following international guidelines for ecosystem-based management, the plan provides an overall framework for managing all human activities (mainly oil and gas industry, fishing, and shipping) in the area to ensure the continued production and function of the ecosystem. The plan is based on an assessment of the present and projected future impact of human activities and of the interactions between them, taking into account deficits in current knowledge of ecosystem state and dynamics. Areas of particular value in terms of biodiversity or biological production were identified. In each of these valuable areas, any access for substantial human activity is to be carefully managed. To monitor the overall development of the Norwegian Sea, a set of indicators with associated environmental quality objectives have been selected. The approach used builds upon experience gained from the first integrated Norwegian management plan for a marine area, the Barents Sea–Lofoten region, developed in 2002–2006. Work towards a Norwegian management plan for the North Sea, including Skagerrak, was initiated in 2009.     

Geological modeling and simulation of CO2 injection in the Johansen formation

The Johansen formation is a candidate site for large-scale CO₂ storage offshore of the south-western coast of Norway. An overview of the geology for the Johansen formation and neighboring geological formations is given, together with a discussion of issues for geological and geophysical modelling and integrated fluid flow modelling. We further describe corresponding simulation models. Major issues to consider are capacity estimation and processes that could potentially cause CO₂ to leak out of the Johansen formation and into the formations above. Currently, these issues can only be investigated through numerical simulation. We consider the effect of different boundary conditions, sensitivity with respect to vertical grid refinement and permeability/transmisibility data, and the effect of residual gas saturations, since these strongly affect the CO₂-plume distribution. The geological study of the Johansen formation is performed based on available seismic and well data. Fluid simulations are performed using a commercial simulator capable of modelling CO₂ flow and transport by simple manipulation of input files and data. We provide details for the data and the model, with a particular focus on geology and geometry for the Johansen formation. The data set is made available for download online.     

Potential impact of climate change on ecosystems of the Barents Sea Region

The EU project BALANCE (Global Change Vulnerabilities in the Barents region: Linking Arctic Natural Resources, Climate Change and Economies) aims to assess vulnerability to climate change in the Barents Sea Region. As a prerequisite the potential impact of climate change on selected ecosystems of the study area has to be quantified, which is the subject of the present paper. A set of ecosystem models was run to generate baseline and future scenarios for 1990, 2020, 2050 and 2080. The models are based on data from the Regional Climate Model (REMO), driven by a GCM which in turn is forced by the IPCC-B2 scenario. The climate change is documented by means of the Köppen climate classification. Since the multitude of models requires the effect of climate change on individual terrestrial and marine systems to be integrated, the paper concentrates on a standardised visualisation of potential impacts by use of a Geographical Information System for the timeslices 2050 and 2080. The resulting maps show that both terrestrial and marine ecosystems of the Barents region will undergo significant changes until both 2050 and 2080.