Osmium isotope and highly siderophile element systematics of the lunar crust

Coupled ¹⁸⁷Os/¹⁸⁸Os and highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, and Re) abundance data are reported for pristine lunar crustal rocks 60025, 62255, 65315 (ferroan anorthosites, FAN) and 76535, 78235, 77215 and a norite clast in 15455 (magnesian-suite rocks, MGS). Osmium isotopes permit more refined discrimination than previously possible of samples that have been contaminated by meteoritic additions and the new results show that some rocks, previously identified as pristine, contain meteorite-derived HSE. Low HSE abundances in FAN and MGS rocks are consistent with derivation from a strongly HSE-depleted lunar mantle. At the time of formation, the lunar floatation crust, represented by FAN, had 1.4 ± 0.3 pg g^? 1 Os, 1.5 ± 0.6 pg g^? 1 Ir, 6.8 ± 2.7 pg g^? 1 Ru, 16 ± 15 pg g^? 1 Pt, 33 ± 30 pg g^? 1 Pd and 0.29 ± 0.10 pg g^? 1 Re (～ 0.00002 × CI) and Re/Os ratios that were modestly elevated (¹⁸⁷Re/¹⁸⁸Os = 0.6 to 1.7) relative to CI chondrites. MGS samples are, on average, characterised by more elevated HSE abundances (～ 0.00007 × CI) compared with FAN. This either reflects contrasting mantle-source HSE characteristics of FAN and MGS rocks, or different mantle–crust HSE fractionation behaviour during production of these lithologies. Previous studies of lunar impact-melt rocks have identified possible elevated Ru and Pd in lunar crustal target rocks. The new results provide no supporting evidence for such enrichments.If maximum estimates for HSE in the lunar mantle are compared with FAN and MGS averages, crust–mantle concentration ratios (D-values) must be ≤ 0.3. Such D-values are broadly similar to those estimated for partitioning between the terrestrial crust and upper mantle, with the notable exception of Re. Given the presumably completely different mode of origin for the primary lunar floatation crust and tertiary terrestrial continental crust, the potential similarities in crust–mantle HSE partitioning for the Earth and Moon are somewhat surprising. Low HSE abundances in the lunar crust, coupled with estimates of HSE concentrations in the lunar mantle implies there may be a ‘missing component’ of late-accreted materials (as much as 95%) to the Moon if the Earth/Moon mass-flux estimates are correct and terrestrial mantle HSE abundances were established by late accretion.     

Detecting changing river temperatures in England and Wales

Changes in water temperature can have important consequences for aquatic ecosystems, with some species being sensitive even to small shifts in temperature during some or all of their life cycle. While many studies report increasing regional and global air temperatures, evidence of changes in river water temperature has, thus far, been site specific and often from sites heavily influenced by human activities that themselves could lead to warming. Here we present a tiered assessment of changing river water temperature covering England and Wales with data from 2773 locations. We use novel statistical approaches to detect trends in irregularly sampled spot measurements taken between 1990 and 2006. During this 17‐year period, on average, mean water temperature increased by 0.03 °C per year (±0.002 °C), and positive changes in water temperature were observed at 2385 (86%) sites. Examination of catchments where there has been limited human influence on hydrological response shows that changes in river flow have had little influence on these water temperature trends. In the absence of other systematic influences on water temperature, it is inferred that anthropogenically driven climate change is driving some of this trend in water temperature. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Review of Quantitative Surveys of the Length and Stability of MTBE,TBA, and Benzene Plumes in Groundwater at UST Sites

Quantitative information regarding the length and stability condition of groundwater plumes of benzene, methyl tert‐butyl ether (MTBE), and tert‐butyl alcohol (TBA) has been compiled from thousands of underground storage tank (UST) sites in the United States where gasoline fuel releases have occurred. This paper presents a review and summary of 13 published scientific surveys, of which 10 address benzene and/or MTBE plumes only, and 3 address benzene, MTBE, and TBA plumes. These data show the observed lengths of benzene and MTBE plumes to be relatively consistent among various regions and hydrogeologic settings, with median lengths at a delineation limit of 10 µg/L falling into relatively narrow ranges from 101 to 185 feet for benzene and 110 to 178 feet for MTBE. The observed statistical distributions of MTBE and benzene plumes show the two plume types to be of comparable lengths, with 90th percentile MTBE plume lengths moderately exceeding benzene plume lengths by 16% at a 10‐µg/L delineation limit (400 feet vs. 345 feet) and 25% at a 5‐µg/L delineation limit (530 feet vs. 425 feet). Stability analyses for benzene and MTBE plumes found 94 and 93% of these plumes, respectively, to be in a nonexpanding condition, and over 91% of individual monitoring wells to exhibit nonincreasing concentration trends. Three published studies addressing TBA found TBA plumes to be of comparable length to MTBE and benzene plumes, with 86% of wells in one study showing nonincreasing concentration trends.     

Intraplate deformation adjacent to the Macquarie Ridge south of New Zealand—The tectonic evolution of a complex plate boundary

The distribution of relocated seismicity and the evolving shape of fracture zones through time in the oceanic crust of the Australian Plate adjacent to the Australia:Pacific plate boundary south of New Zealand are used to constrain the deformation of this region of the Australian Plate, here called the Puysegur Block. Relocated seismicity reveals a broad distribution of earthquakes in the Puysegur Block on both inter- and intraplate structures, including two great (M8+) earthquakes in the region over the past twenty years, one of which occurred over 130 km from the plate boundary. Plate reconstructions from the Late Oligocene through Early–Mid Miocene allow us to determine the undeformed shape of fracture zones in the Puysegur Block, formed during the Paleogene when the plate boundary was dominantly a divergent mid-ocean ridge system. Comparing these reconstructions to the present-day shape of the fracture zones allows us to map the deformation that has occurred within the Puysegur Block since the fracture zones formed. These two sets of independent observations delineate a broad zone of deformation extending ~ 150 km into the plate interior from the Macquarie Ridge Complex, the modern plate boundary structure through the region. The persistence of this deformation through time indicates a link with the evolution of the plate boundary over the past ~ 25 Ma from divergence to translation and subduction of the Australian Plate further north at the Puysegur Trench. We infer that this deformation may be a result of stresses in the Puysegur Block resulting from the impingement of the subducting plate on the thickened lithosphere of southern New Zealand. Such a collision may resist subduction, and if resistance remains substantial, further deformation internal to the Puysegur Block may lead to a southward migration of the Australia:Pacific subduction interface and the capturing of this section of lithosphere onto the Pacific Plate.     

The effects of surface moisture on aeolian sediment transport threshold and mass flux on a beach

This paper presents results from a study designed to explore the effects of beach surface moisture and fetch effects on the threshold of movement, intensity of sand transport by wind and mass flux. The experiment was carried out over a period of five weeks at Greenwich Dunes, Prince Edward Island, Canada in May and June 2002. Moisture content was measured with a Delta‐T moisture probe over a 50 m by 25 m grid established on the beach. Measurements of wind speed and direction were made with arrays of cup anemometers and a two‐dimensional sonic anemometer. Transport intensity was measured at a height of 2–4 cm above the bed using omnidirectional saltation probes which count the impact of saltating grains on a piezoelectric crystal. Anemometers and saltation probes were sampled at 1 Hz. Sand transport was measured with vertical integrating sand traps over periods of 10–20 minutes. Results show that where there is a considerable supply of dry sand the saltation system responds very rapidly (1–2 s) to fluctuations in wind speed, i.e. to wind gusts. Where sand supply from the surface is limited by moisture, mean transport rates are much lower and this reflects in both a reduction in the instantaneous transport rate and in a transport system that becomes increasingly intermittent. Threshold wind speed is significantly correlated with an increase in surface moisture content near the upwind end of the beach fetch, but the relationship is not significant at the downwind end where sediment transport is initiated primarily by saltation impact from upwind. Mass flux increases with increasing fetch length and the relationship is described best by a power function. Further work is necessary to develop a theoretical function to predict the increase in transport with fetch distance as well as the critical fetch distance. Copyright © 2007 John Wiley & Sons, Ltd.     

Population biology of coral trout species in eastern Torres Strait: Implications for fishery management

Coral trout (Plectropomus spp.) are the main target species for commercial fishers in the eastern Torres Strait Reef Line Fishery (ETS RLF). The four species of coral trout known to occur in Torres Strait: Plectropomus leopardus, Plectropomus maculatus, Plectropomus areolatus and Plectropomus laevis are currently managed as a single species in Torres Strait, as there is no species-specific biological information available for the region which could be used to assess whether species differ in their response to fishing pressure. The aim of our study was to determine whether it is appropriate (biologically) to manage coral trout in the ETS RLF as a single species group or whether different management arrangements are required for some species. We used catch data and biological data from samples collected by commercial fishers to examine the distribution within Torres Strait and estimate a range of biological parameters for P. leopardus, P. maculatus and P. areolatus. Insufficient P. laevis samples were collected to reliably examine this species. Results indicated that the population biology, particularly the reproductive biology, of P. areolatus was substantially different to both P. leopardus and P. maculatus. Although it is difficult to predict the response to fishing, P. areolatus may be more vulnerable to fishing than P. leopardus and P. maculatus, due to the larger size at sex change observed for this species and the very low proportion of males protected by the current minimum size limit. Therefore, while the common management arrangements for P. leopardus and P. maculatus appear to be adequate for these species, separate management arrangements are needed for the sustainable harvest of P. areolatus populations in the ETS. Specifically, we recommend the introduction of a maximum size limit for P. areolatus, in addition to the current minimum size limit, which may allow a proportion of males some protection from fishing.     

Depositional history and evolution of the Paso del Indio site,Vega Baja,Puerto Rico

Potshards discovered during excavation of bridge pilasters for a major expressway over the Rio Indio floodplain, a stream incised within the karsts of north‐central Puerto Rico, required large‐scale archaeological excavation. Five‐meter‐deep bridge pilaster excavations in the alluvial valley provide a 4500‐year history of deposition. Stratigraphic analysis of the exposed pilaster walls in combination with textural and organic carbon analyses of sediment cores obtained over a much broader area suggest a fluvial system dominated by overbank deposition. Six sequences of alternating light and dark layers of sediment were identified. The darker layers are largely composed of silts and clays, whereas the lighter layers are rich in sand‐sized sediment. Archaeological evidence indicates the organic‐rich dark layers, believed to be buried A horizons, coincide with pre‐historic occupation by Cedrosan Saladoid, Elenan Ostionoid, and Chican Ostionoid, extending from A.D. 450 to A.D. 1500. Lighter layers below the dark soil horizons are interpreted as overbank deposits from large magnitude flood events. The floodplain aggraded discontinuously with rapid deposition of sand followed by gradual accumulation of silt, clay, and organic material. An approximately 1‐m‐thick layer of coarse sand and gravel halfway up the stratigraphic column represents an episode of more frequent and severe floods. Based on radiocarbon ages, this layer aggraded between A.D. 1000 and A.D. 1100, which is well within the Elenan Ostionoid era (A.D. 900–1200). Rates of sedimentation during this period were approximately 8 mm per year, ten times greater than the estimates of sedimentation rates before and after this flood sequence. The cause for the change in deposition is unknown. Nonetheless the Elenan Ostionoid would have had to endure frequent loss of habitation structures and crops during these events. © 2003 Wiley Periodicals, Inc.     

Seasonal controls on sediment transport and deposition in Lake Ohau,South Island,New Zealand: Implications for a high‐resolution Holocene palaeoclimate reconstruction

Laminated sediments in Lake Ohau, Mackenzie Basin, New Zealand, offer a potential high‐resolution climate record for the past 17 kyr. Such records are particularly important due to the relative paucity of detailed palaeoclimate data from the Southern Hemisphere mid‐latitudes. This paper presents outcomes of a study of the sedimentation processes of this temperate lake setting. Hydrometeorological, limnological and sedimentological data were collected over a 14 month period between 2011 and 2013. These data indicate that seasonality in the hydrometeorological system in combination with internal lake dynamics drives a distinct seasonal pattern of sediment dispersal and deposition on a basin‐wide scale. Sedimentary layers that accumulate proximal to the lake inflow at the northern end of the lake form in response to discrete inflow events throughout the year and display an event stratigraphy. In contrast, seasonal change in the lake system controls accumulation of light (winter) and dark (summer) laminations at the distal end of the lake, resulting in the preservation of varves. This study documents the key processes influencing sediment deposition throughout Lake Ohau and provides fundamental data for generating a high‐resolution palaeoclimate record from this temperate lake.