Unbiased station grid for study of the kinetic energy balance of the atmosphere

Summary For the past several years observational studies of the northern hemisphere kinetic energy balance and related subjects have been performed by the Planetary Circulation Project of the Massachusetts Institute of Technology. Numerous integrals required were recently evaluated directly from a five-year period of observations using a network of nearly 800 stations. The stations, however, are concentrated primarily over temperate latitude continents, and the data from maritime and tropical areas were comparatively sparse. The question then arises whether the results are representative. The problem discussed in this paper is to select a subset of more uniformly spaced stations and to recompute the zonal kinetic energy balance. This is accomplished and the results are presented herewith.The research reported in this paper was sponsored by the U.S. National Science Foundation under Grant No. GA-1310X.     

Photochemistry of methane in the Earth's early atmosphere

A detailed model is presented of methane photochemistry in the primitive terrestrial atmosphere along with speculation about its interpretation. Steady-state CH₄ mixing ratios of 10⁻⁶–10⁻⁴ could have been maintained by a methane source of about 10¹¹ cm⁻² s⁻¹, which is comparable to the modern biogenic methane production rate. In the absence of a source, methane would have disappeared in <10⁴ years, being either oxidized, or polymerized into more complex hydrocarbons. The source strength needed to maintain a steady CH₄ mixing ratio and the degree to which methane could have polymerized to form higher hydrocarbons depend upon the amount of CO₂ present in the early atmosphere. The dependence on H₂ is much weaker. Infrared absorption by methane, and especially by other hydrocarbon species, may have supplemented the greenhouse warming due to carbon dioxide. A radiative model is needed to establish this effect quantitatively. The destruction of the methane greenhouse early in the Proterozoic may have triggered the Huronian glaciation.These calculations also suggest that atmospheres rich in both CO₂ and CH₄ may be photochemically unstable with respect to conversion to CO.     

Boninite primary magmas: Evidence from the Cape Vogel Peninsula,PNG

Boninites from Cape Vogel, PNG, are dominantly pyroxene-glass rocks, but many contain olivine, sometimes as refractory as Fo₉₄. We derive a parental magma for this suite (in equilibrium with Fo₉₄) which contains 20 wt.% MgO and is quartz-normative. This liquid is hydrous, and from petrographie evidence and whole rock H₂O⁺ values, we estimate it to contain 2–3 wt.% H₂O. These data suggest olivine fractionation and primary magmatic water are important in boninite genesis, but both are often obscured by later alteration. The derived parental magma has probably formed at 1,250–1,300° C and low pressures (< ?10kB) and is similar to those which gave rise to olivine-clinoenstatite phyric boninites from New Caledonia and from Howqua, Australia, and possibly to a proposed parental magma for the Bushveld Complex.     

Distribution and significance of chlorophyll derivatives and oxidation products during the spring phytoplankton bloom in the Celtic Sea April 2002

The abundances and distributions of chlorophyll a and its common transformation products have been profiled by high performance liquid chromatography during the disruption, re-establishment, growth and senescence of a phytoplankton bloom in the Celtic Sea during April 2002. Transformation products of chlorophyll a indicative of herbivory of the phytoplankton bloom have been identified using atmospheric pressure chemical ionisation liquid chromatography-multistage mass spectrometry and chlorophyll oxidation products, formed by autoxidation, are present in increasing abundance in samples collected during the later stages of bloom development. The formation of oxidation products during the earliest stages in the chlorophyll transformation pathway identifies water column processes as sources of these early intermediates in the formation of geologic aetioporphyrins and/or cycloalkanoporphyrins.     

Temporal variation in discharge chemistry and portal flow from the 8-Level adit, Lynx Mine, Myra Falls Operations, Vancouver Island, British Columbia

The Lynx mine, currently inactive, has produced copper and zinc concentrates from massive sulfide deposits on a lease within the rainy, mountainous interior of Vancouver Island. Tailings, used to back-fill a mined-out stope, are being leached by percolating groundwater and the resulting acidic, metal-laden drainage is discharging from the portal of the 8-Level adit. Temporal variations in the flow rate, specific conductance and temperature of the discharge were monitored continuously over a 2-year period while effluent chemistry was sampled weekly. Conductivity was relatively constant throughout most of the year but peaked with the first autumn storm events as accumulated soluble sulfide oxidation products were flushed from the workings. Concentrations of sulfate and most metals were closely correlated with conductivity as were low pH values as stored acidity was released along with dissolved species. Variations in pH controlled the speciation and partitioning of metals between dissolved and particulate phases.