Temporal variations in the chemistry of circum-neutral drainage from the 10-Level portal,Myra Mine,Vancouver Island,British Columbia

The Myra mine, now inactive, produced Zn and Cu concentrates from a Zn-rich, Kuroko-type, volcanogenic massive sulfide deposit located in the mountainous interior of Vancouver Island. The climate at the site is classified as “Marine West Coast”, with annual precipitation exceeding 2200 mm. Water from a losing stream on the mountainside above the mine follows preferential, fracture-controlled pathways to the upper workings before draining through the 10-Level portal. With a view toward mine decommissioning, portal discharge rate was monitored continuously over a 17-month period during which 46 water samples were collected. Effluent chemistry, dominated by Ca, HCO₃ and SO₄, shows moderate to high total base metal concentrations and near-neutral pH. Carbonatization, mainly of mafic rocks in the hangingwall, provides significant acid neutralizing potential. Metal concentrations vary seasonally, with smaller spikes associated with summer storm events, and a main peak associated with flushing of the workings during the first heavy autumn rains. Aqueous speciation modeling suggests that Fe and Al concentrations are controlled by the solubilities of hydrous ferric oxides and microcrystalline gibbsite, respectively. Concentrations of Zn, Cu and Cd appear controlled by sorption rather than by the solubilities of mineral phases. A comparison of precipitate concentrations observed in portal effluent with predictions from mass balance (inverse) modeling results suggests that less than 5% of the precipitated Fe and Al hydroxides are transported from the mine. However, amounts of sorbed Cu, Zn and Cd measured in the effluent are only slightly lower than modeled values. This suggests that the small fraction of (probably finer) Fe precipitates in portal effluent sorbs most of the Zn, Cu and Cd predicted by modeling. Based on mass balance calculations, metal loadings are explained by the oxidation of 3830 kg of pyrite, 600 kg of sphalerite and 190 kg of chalcopyrite, annually. Circum-neutral drainage conditions are maintained by the reaction of almost 19,800 kg of calcite, annually.     

The chemistry of suspended particulate material in a highly contaminated embayment of Port Jackson (Australia) under quiescent,high-wind and heavy-rainfall conditions

This study investigated physico-chemical characteristics of the water column and chemistry of suspended particulate material (SPM) under quiescent, high-wind and high-wind/heavy-rainfall conditions in Homebush Bay, a highly contaminated embayment of Port Jackson (Australia) to distinguish source and possible adverse effects to benthic and pelagic animals. Mean concentrations in surficial sediment were <1, 14, 181, 141, 37, 290 and 685 μg g⁻¹ for Cd, Co, Cr, Cu, Ni, Pb and Zn, respectively. Sediment chemistry indicated these metals had multiple sources, i.e. the estuary, stormwater and industry. Mean total suspended solids (TSS) were 7, 17 and 20 mg L⁻¹ during quiescent, high-rainfall and heavy rainfall/high wind conditions, respectively, whereas SPM Cd, Co, Cr, Cu, Ni, Pb and Zn concentrations varied between 13–25, 166–259, 127–198, 38–82, 236–305 and 605–865 μg g⁻¹, respectively under these conditions. TSS and total water metal concentrations were lowest during quiescent conditions. High TSS and metal loads in surface water characterised high-rainfall events. Wind-induced resuspension contributed the greatest mass of SPM and metals to the water column. Benthic animals may be adversely affected by Pb and Zn in sediment. Total water Cu and Zn concentrations may pose a risk to filter-feeding animals in the water column due to resuspension of contaminated sediment.     

Adaptive Management of the Global Climate Problem: Bridging the Gap Between Climate Research and Climate Policy

To date the Intergovernmental Panel on Climate Change (IPCC) has concerned itself with gathering a state of the art review of the science of climate change. While significant progress has been made in enhancing our integrated understanding of the climate system and the dynamics of the social systems that produce an array of potential greenhouse gases, it is also clear from the panel's reports how far the science community is from being able to present a dynamic and synoptic view of the climate system as a whole. Clear evidence of these complexities and uncertainties inherent in the climate system is evident in efforts aimed at designing robust policy interventions. In this paper, we argue that the adaptive management framework in ecosystem management may be a useful model for guiding how the IPCC can continue to be relevant both as a scientific establishment and as a policy-relevant scientific endeavor.     

Geographies of knowledge, practices of globalization: learning from the oil exploration and production industry

In this paper we initiate a dialogue between work on the geographies of globalization and knowledge economies, areas of inquiry that have tended to develop in isolation. We argue for a critical harnessing of these two bodies of work to (1) understand how and where different types of knowledge are acquired, produced and mobilized by firms as they seek to 'go global', (2) map the multi-scalar geographies of knowledge that enable practices of globalization and (3) examine the ways in which networks of knowledge structure emerging geographies of production. We demonstrate the potential of this move using oil exploration and production as an example.     

Age constraints on Pleistocene megafauna at Tight Entrance Cave in southwestern Australia

A well-stratified succession of fossiliferous sediments occurs in Tight Entrance Cave, southwestern Australia. These infill deposits contain the remains of megafauna and have accumulated intermittently since the Middle Pleistocene: >137, 137–119 and 50–29 ka, according to the results of ¹⁴C, U–Th, ESR and OSL dating techniques. Megafaunal species richness was highest in the latest part of the penultimate glacial maximum and during the subsequent last interglacial (137–119 ka), but remains are less abundant following an apparent 70 ka depositional hiatus in the sequence. Most megafaunal specimens from the upper (<44 ka) units are fragmentary, and reworking from older strata cannot yet be ruled out. However, one specimen of Simosthenurus occidentalis (a large extinct kangaroo), a pair of articulated dentaries showing no signs of secondary transportation, was found within a sedimentary layer deposited between 48 and 50 ka. This represents one of the youngest demonstrably in situ occurrences of an Australian megafaunal taxon.     

Application of sedimentary and chronological analyses to refine the depositional context of a Late Pleistocene vertebrate deposit,Naracoorte, South Australia

Cave deposits of infill sediments and associated vertebrate fossils provide a valuable source of information on terrestrial palaeoenvironments, climatic conditions and palaeocommunities. In the deposits of the Naracoorte Caves World Heritage Area, such records span the last 500 ka and are renowned for their rich, diverse vertebrate assemblages. Previous research into the Grant Hall deposit of Victoria Fossil Cave suggested that it may preserve the only peak last interglacial (ca. 125 ka) faunal community within the World Heritage Area. The current work tested this existing model for the age of faunal remains from Grant Hall using multiple techniques. Physical and geochemical properties of the visually homogeneous sediments were analysed at regular intervals through the sequence to establish meaningful stratigraphic divisions and sediment provenance. Optically stimulated luminescence dating of individual quartz grains indicates that sediments accumulated in Grant Hall from 93 ± 8 to 70 ± 5 ka. Minimum ages provided by U/Th dating of fossil teeth (72.3 ± 2.2 to 38.2 ± 0.8 ka) are consistent with the luminescence chronology, and show that the deposit represents a more recent faunal accumulation than previously modelled for the site. U/Th ages on calcite straws within the deposit are significantly older than the sediments and fossil teeth (>500 to 186.4 ± 1 ka). As such they provide no further constraint on the chronology of the deposit but do indicate that speleothem deposition was active over much of the Middle Pleistocene. Sedimentary analyses resulted in the identification of five depositional units, contrasting with previous divisions which were based only on visual observation of the sedimentary sequence. Sediments within each unit are broadly classified as sandy silts with soil structures and may be indirectly derived from the lunettes of nearby Bool Lagoon, although their ultimate provenance is unknown. As a result of this work, palaeoenvironmental reconstruction based on fossil remains in the deposit may be more accurately related to prevailing climatic and environmental conditions at the time of accumulation. It also contributes to an understanding of the temporal occurrence of regional vertebrate faunas through the Late Pleistocene, reinforcing the value of developing stratigraphically constrained chronologies for cave deposits based on multiple techniques.     

Truly isotropic biaxial hysteresis with arbitrary knee sharpness

The inelastic responses of framed structures and seismic isolation systems undergoing biaxial (horizontal) shaking are coupled. In existing models for biaxial coupling of hysteretic behavior, the smoothness (or ‘knee') of the transition from elastic to yielding behavior cannot be modified without affecting the shape of the yield surface. This paper presents a model for coupled biaxial hysteretic behavior in which the knee from pre‐yield to post‐yield can be adjusted while maintaining an isotropic yield surface. Copyright © 2014 John Wiley & Sons, Ltd.     

Hydroxyl and Peroxy Radical Chemistry in a Rural Area of Central Pennsylvania: Observations and Model Comparisons

Atmospheric hydroxyl (OH), hydroperoxy (HO₂), total peroxy (HO₂ and organic peroxy radicals, RO₂) mixing ratios and OH reactivity (first order OH loss rate) were measured at a rural site in central Pennsylvania during May and June 2002. OH and HO₂ mixing ratios were measured with laser induced fluorescence (LIF); HO₂ + RO₂ mixing ratios were measured with chemical ionization mass spectrometry (CIMS). The daytime maximum mixing ratios were up to 0.6 parts per trillion by volume (pptv) for OH, 30 pptv for HO₂, and 45 pptv for HO₂ + RO₂. A parameterized RACM (Regional Atmospheric Chemistry Mechanism) box model was used to predict steady state OH, HO₂ and HO₂ + RO₂ concentrations by constraining the model to the measured OH reactivity and previously measured volatile organic compound (VOC) distributions. The averaged model calculations are generally in good agreement with the observations. For OH, the model matched the observations for day and night, with an average observed-to-modeled ratio of 0.80. In previous studies such as PROPHET98, nighttime NO was near 0 pptv and observed nighttime OH was significantly larger than modeled OH. In this study, nighttime observed and modeled OH agree to within measurement and model uncertainties because the main source of the nighttime OH was the reaction HO₂ + NO → OH + NO₂, with the NO being continually emitted from the surrounding fertilized corn field. The observed-to-modeled ratio for HO₂ is 1.0 on average, although daytime HO₂ is underpredicted by a factor of 1.2 and nighttime HO₂ is over-predicted by a factor of ∼2. The average measured and modeled HO₂ + RO₂ agree well during daytime, but the modeled value is about twice the measured value during nighttime. While measured HO₂ + RO₂ values agree with modeled values for NO mixing ratios less than a few parts per billion by volume (ppbv), it increases substantially above the expected value for NO greater than a few ppbv. This observation of the higher-than-expected HO₂ + RO₂ with the CIMS technique confirms the observed increase of HO₂ above expected values at higher NO mixing ratios in HO₂ measurements with the LIF technique. The maximum instantaneous O₃ production rate calculated from HO₂ and RO₂ reactions with NO was as high as 10–15 ppb h⁻¹ at midday; the total daily O₃ production varied from 13 to 113 ppbv d⁻¹ and was 48 ppbv d⁻¹ on average during this campaign.