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101.
102.
Aeolian sand and dust in polar regions are transported offshore over sea ice and released to the ocean during summer melt. This process has long been considered an important contributor to polar sea floor sedimentation and as a source of bioavailable iron that triggers vast phytoplankton blooms. Reported here are aeolian sediment dispersal patterns and accumulation rates varying between 0·2 g m?2 yr?1 and 55 g m?2 yr?1 over 3000 km2 of sea ice in McMurdo Sound, south‐west Ross Sea, adjacent to the largest ice free area in Antarctica. Sediment distribution and the abundance of southern McMurdo Volcanic Group‐derived glass, show that most sediment originates from the McMurdo Ice Shelf and nearby coastal outcrops. Almost no sediment is derived from the extensive ice free areas of the McMurdo Dry Valleys due to winnowed surficial layers shielding sand‐sized and silt‐sized material from wind erosion and because of the imposing topographic barrier of the north‐south aligned piedmont glaciers. Southerly winds of intermediate strength (ca 20 m sec?1) are primarily responsible for transporting sediment northwards and offshore. The results presented here indicate that sand‐sized sediment does not travel more than ca 5 km offshore, but very‐fine sand and silt grains can travel >100 km from source. For sites >10 km from the coast, the mass accumulation rate is relatively uniform (1·14 ± 0·57 g m?2 yr?1), three orders of magnitude above estimated global atmospheric dust values for the region. This uniformity represents a sea floor sedimentation rate of only 0·2 cm kyr?1, well below the rates of >9 cm kyr?1 reported for biogenic‐dominated sedimentation measured over much of the Ross Sea. These results show that, even for this region of high‐windblown sediment flux, aeolian processes are only a minor contributor to sea floor sedimentation, excepting areas proximal to coastal sources.  相似文献   
103.
Concentrations of dissolved metals (Cd, Cu, Ni, Mn and Zn) were determined for summer and winter, under low-flow conditions in Port Jackson, a microtidal, well-mixed estuary in south-east Australia. Mean concentrations of Cd (0.04+/-0.02 microg/l), Ni (0.86+/-0.40 microg/l), Mn (20.0+/-25 microg/l) and Zn (6.47+/-2.0 microg/l) were below water quality guidelines. Concentrations of Cu (1.68+/-0.37 microg/l), however, slightly exceeded recommended values. Dissolved Ni and Mn behaved mostly conservatively, whereas Cd, Cu and Zn showed mid-estuarine maxima. Peaks in Cd, Cu and Zn concentrations were located in the upper estuary, independent of the salinity and suspended particulate matter loading, and were consistent with anthropogenic inputs of metals in the estuary. Concentrations of dissolved Cu were highest in summer, whereas concentrations of Cd, Ni and Mn were significantly lower in summer than winter (P< or =0.05). The increase in temperature and biological activity during summer explained the seasonal variation. The sequence of log K(d) values (20-30 salinity) was Mn>Zn>Cu>Ni. These results give unique information concerning the contemporaneous distribution of dissolved trace metals in the Port Jackson estuary and they provide a data set against which the long-term contamination may be assessed.  相似文献   
104.
Inversions for local helioseismology are an important and necessary step for obtaining three-dimensional maps of various physical quantities in the solar interior. Frequently, the full inverse problems that one would like to solve prove intractable because of computational constraints. Due to the enormous seismic data sets that already exist and those forthcoming, this is a problem that needs to be addressed. To this end, we present a very efficient linear inversion algorithm for local helioseismology. It is based on a subtractive optimally localized averaging (SOLA) scheme in the Fourier domain, utilizing the horizontal-translation invariance of the sensitivity kernels. In Fourier space the problem decouples into many small problems, one for each horizontal wave vector. This multichannel SOLA method is demonstrated for an example problem in time–distance helioseismology that is small enough to be solved both in real and Fourier space. We find that both approaches are successful in solving the inverse problem. However, the multichannel SOLA algorithm is much faster and can easily be parallelized.  相似文献   
105.
The Helioseismic and Magnetic Imager onboard the Solar Dynamics Observatory (SDO/HMI) provides continuous full-disk observations of solar oscillations. We develop a data-analysis pipeline based on the time–distance helioseismology method to measure acoustic travel times using HMI Doppler-shift observations, and infer solar interior properties by inverting these measurements. The pipeline is used for routine production of near-real-time full-disk maps of subsurface wave-speed perturbations and horizontal flow velocities for depths ranging from 0 to 20?Mm, every eight hours. In addition, Carrington synoptic maps for the subsurface properties are made from these full-disk maps. The pipeline can also be used for selected target areas and time periods. We explain details of the pipeline organization and procedures, including processing of the HMI Doppler observations, measurements of the travel times, inversions, and constructions of the full-disk and synoptic maps. Some initial results from the pipeline, including full-disk flow maps, sunspot subsurface flow fields, and the interior rotation and meridional flow speeds, are presented.  相似文献   
106.
The 167 sample lake-water pH-diatom calibration data-set created as part of the Palaeolimnology Programme within the Surface Water Acidification Project (SWAP) is re-analysed numerically using nine different numerical methods, six based on simple two-way weighted-averaging (WA), and the other three involving Gaussian logit regression (GLR) and maximum-likelihood (ML) calibration, the modern analogue technique, or weighted-averaging partial least-squares regression and calibration. Root mean squared error of prediction and maximum bias were estimated for all nine methods based on 10,000 internal and 10,000 external cross-validations involving a training-set, an optimisation-set, and a test-set. The results show that WA with a monotonic deshrinking spline equals or slightly outperforms WA with linear inverse deshrinking, especially in external cross-validation. Methods that employ tolerance downweighting generally have an inferior performance except when combined with monotonic deshrinking. It appears that simple two-way WA extensively used in SWAP cannot be significantly bettered. Thanks to increased computing power, better software, and more rigorous cross-validations, GLR shows good performance, especially in external cross-validation.  相似文献   
107.
The spatial and temporal variations of Fe, K, Co, V, Cr, Cu, Ni, Zn, and Pb were determined in the sediments of Taihu Lake, the third largest freshwater lake in China and categorized into natural origin (Fe, K, Co, and V) and human contamination (Cr, Cu, Ni, Zn, and Pb) groups by principal component analysis. Most of the metals were positively correlated with the clay content (<4???m) and negatively correlated with the >16???m fraction, indicating the dominant role of grain size in regulating metals concentrations. Geochemical normalization and enrichment factors (EFs) were introduced to reduce the confounding of variable grain size and to quantify anthropogenic contributions. Higher EF values for Cr, Cu, Ni, and Zn occurred in the north Zhushan, Meiliang, and Gonghu Bays, indicating a high level of human contamination from the northern cities, such as Wuxi and Changzhou. Higher EF values of Pb were also present in the southwest and east lake areas, denoting the existence of additional anthropogenic sources. Chrome, Cu, Ni, Zn, and Pb showed increasing EF values in the top layers of sediment cores, indicating enhancing contamination since 1970s with rapid economy development in the catchment. These results indicate that geochemical normalization is a necessary and effective method in quantifying heavy metals contamination, and that historic sediment should be used as background values in calculating EFs. Potential risks of the heavy metals were assessed linking the consensus-based sediment quality guidelines and human contamination. Concentrations of Ni and Cr are greater than the threshold effect concentration (TEC) values, even in the sediments before 1970s, due to higher background concentrations in terrestrial parent materials. Concentrations of Ni and Cr are generally lower than the probable effect concentration (PEC) values, and concentrations of Cu and Zn are below the TEC values in the open lake areas. Whereas, concentrations of Ni and Cr are surpassing the PEC values and Cu and Zn are surpassing the TEC values in the north bays due to the high level of human contamination, where they were with EFs over 1.2, denoting higher potential eco-risks.  相似文献   
108.
Thick rhyolite sheets occur within the middle Palaeozoic cauldron subsidence complexes in Victoria. Well‐preserved eutaxitic and vitroclastic textures in the basal regions of the Rubicon, Jemba, and Ryans Creek rhyolites provide evidence of an ash‐flow origin. Subsequent recrystallization during cooling has masked these primary textures towards the central and upper parts of the rhyolitic sheets. All three rhyolites show dense welding throughout and the major zonation observed is in the degree of granophyric recrystallization.

Despite the turbulent ash‐flow emplacement and the possibility of post‐eruptive chemical modification, the mineralogical and chemical trends within vertical sequences in the Rubicon and Jemba Rhyolites are essentially continuous and represent the inverted variation within the original magma body. The bulk compositions of the rhyolites suggest that conditions of water saturation were closely approached or attained within the magma chamber. The chemical variation with increasing height and phenocryst content in the rhyolites can be summarized as: increasing K, Ca, Ba and Sr, and decreasing Na and Rb. Whereas this variation is in accord with frac‐tionation theories, it is more likely to have resulted from the partial fusion process believed to have been responsible for the generation of the acid magmas.  相似文献   
109.
The Devonian Lake Boga Granite in northern Victoria, while almost entirely under thin Murray Basin cover, is one of the largest plutons in the western Lachlan Fold Belt. Its only exposure is a quarry penetrating the Cenozoic sediments. In the quarry, prominent pod pegmatites and miarolitic cavities suggest a high level of emplacement. The granite, a non-magnetic, fractionated S-type, contains a large range of accessory minerals, including primary uranium- and REE-bearing phosphates and oxides, and primary copper sulfides. Monazite-series minerals show an exceptionally wide range of compositions, from normal monazite-(Ce) through cheralite (Ca – Th-rich) to rare huttonitic monazite (Th-rich) and brabantite; U contents in monazite also vary widely (0 – 7.9 wt%). Primary low-Ca uraninites are well preserved and are unusual in having low Th/U and LREE. Late-stage cavity fluorapatite crystals up to several centimetres across show intricate elemental zoning patterns with extreme U gradients (<10 – 6900 ppm) in some crystals. New 40Ar – 39Ar ages for magmatic biotite, muscovite and K-rich feldspar average 365 ± 3 Ma, which approximates the emplacement age of the granite. This is supported by a 377 ± 12 Ma U – Th – Pb (CHIME) age for primary uraninite. New whole-rock geochemical data support earlier observations: the granite is strongly fractionated (SiO2 70.7 – 76.0 wt%; 4.2 – 0.6 wt% FeOt) and peraluminous (ASI = 1.23 – 1.45), and has slightly elevated Na2O and P2O5 (0.30 wt%) contents compared with other fractionated S-type granites from the Lachlan Fold Belt. Trace-element abundances are typical of fractionated granites, although U and Cu concentrations vary strongly and reach >60 and ≈1400 ppm, respectively. REE patterns also vary strongly, from LREE-enriched with moderate Eu depletion, to flat with strong Eu depletion. The flattest of the REE patterns, in samples with FeOtotal < 1%, are characterised by M-type tetrad effects. These and other samples also show low (subcrustal average) and variable Zr/Hf (35 – 16) and Nb/Ta (8 – 4) ratios; these and other unusual elemental fractionations are related to changes in elemental partitioning during the late magmatic stage, when felsic peraluminous magma and high-temperature magmatic fluid coexisted.  相似文献   
110.
A case study is presented to assess the use of sedimentary chemical indicators for estuarine health. Reliable and efficient estuarine indicators are essential for management and monitoring purposes. Estuarine and fluvial sediments from Brisbane Water estuary were analysed for heavy metals to assess the quality of sediments and to determine the source and dispersion of contaminants in the estuary. Brisbane Water, 50 km north of Sydney, is a shallow (~5 m in main water body), wave-dominated barrier estuary with a generally sparsely developed catchment, except in the north where it is urbanised and industrialised. Heavy-metal loadings calculated for sub-catchments and the distribution of metals in surficial sediment identified Narara Creek, which drains the urbanised northern part of the catchment, as the main source of contaminants. Vertical profiles of sedimentary contaminants show that contamination continues to increase rapidly in all parts of the waterway to the present day. Concentrations of Cu, Pb and Zn in sediment adjacent to Narara Creek exceeded lower guideline levels, although moderate bioavailability (~40% for Cu, Pb and Zn) suggests the risk posed by sediments to benthic populations is low. Sediments in all parts of Brisbane Water show evidence of minor anthropogenic influence with maximum human-induced change (up to 5× enrichment) in the north of the estuary. Results demonstrate the use of sediment-bound heavy metal as an appropriate indicator of estuarine health.  相似文献   
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