Isotope composition of Medieval lead glasses reflecting early silver production in Central Europe

The lead isotope composition of 32 lead glasses excavated from strata of the twelfth to early fifteenth century in six countries of NW Europe made the predominance of the Harz Mountains in this period of the Medieval European lead and silver production highly probable. Post-Variscan vein type galena, Devonian syngenetic hydrothermal ore (Rammelsberg) and blended ore from both deposits in the Harz were used. Our evaluation of 200 mining sites in Germany, Britain and Ireland also demonstrated that minor lead sources for lead glass were located in Bavaria/Bohemia and England. Lead ores from the Rhenohercynian orogenic belt in Germany are derived from rock sources close to the upper continental crust composition in ²³⁸U/²⁰⁴Pb of about 10 and Th/U of about 4. The ores in Central England originated from rocks with ²³⁸U/²⁰⁴Pb of about 11. Received: 24 September 1996 / Accepted: 17 January 1997     

Geochemical processes in the saltwater–freshwater transition zone: comparing results of a sand tank experiment with field data

Geochemical processes, occurring in a stable transition zone between saltwater and freshwater, were simulated in a 2D, multi-layer flow chamber experiment. Mixing, calcite dissolution, and oxidative degradation of organic matter were identified as the main controlling factors. The results of the chamber experiment were compared to field data and verified by thermodynamic modeling. Similarity in most ion distributions suggests the general applicability of the experimental method. Differences in the redox conditions between field and experiment were reflected by the oxidants involved in the mineralization of organic carbon; while field data show evidence of sulfate reduction, the presence of oxygen in the laboratory experiment resulted in the reoxidation of sulfides.     

Significance of Europium anomalies in silicate melts and crystal-melt equilibria: a re-evaluation

Although europium speciation in silicate melts partly reflects prevailing oxygen fugacities, melt composition and structure play the major role in determining Eu²⁺/ Eu³⁺ ratios and europium partitioning into mineral phases. Experimental evidence by different investigators on the magnitude of the compositional effect on Eu²⁺/Eu³⁺ provides consistent results only if account is taken of the oxygen buffer system employed in the experiments. The medium-dependent reduction of europium can be understood in terms of the preferential stabilization of Eu²⁺ by a strong aluminosilicate complex in the melt phase, and to a much lesser degree by metasilicate complexes. The stability of these complexes increases as the field strength of the associated cation species decreases. Hence Eu²⁺-aluminosilicate complexes are preferentially stabilized relative to trivalent lanthanides in melts of appropriate composition and their presence minimizes the enthalpy of the melt. The influence of these complexes is particularly pronounced in melts with a high feldspathic component and a strongly polymerized structure. Their petrogenetic influence is best documented through the behaviour of europium relative to the other lanthanides during anhydrous anatexis in high-grade metamorphic terrains and in the anomalous europium partition coefficients of phenocryst phases which formed during the crystallization of highly silicic magmas.     

Some aspects of the succession and structure in the lower palaeozoic rocks of the southern uplands of scotland

Lower Palaeozoic successions in the Southern Uplands are much thicker than previously supposed and sedimentation may have lasted well into Ludlow times. Volcanic rocks are Arenig and Glenkiln in age and are often interbedded with greywackes and shales. Lapworth's concept of the structure as an anticlinorium and a synclinorium is rejected and it is suggested that the rocks have been folded into a series of compound monoclines which face north-westwards. These are probably cut by strike faults which bring up the older beds to the north.

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Zusammenfassung Die altpaläozoischen Schichtfolgen in den Südlichen Hochlanden sind viel mächtiger, als bisher angenommen wurde, und die Ablagerung kann bis ins Ludlow gereicht haben. Vulkanite haben Arenig- und Glenkiln-Alter; sie wechsellagern oft mit Grauwacken und Tonschiefern.Lapworths Vorstellung, der tektonische Bau sei ein Antiklinorium und ein Synklinorium, wird bestritten. Es wird angenommen, daß die Gesteine zu zusammengesetzten Monoklinen gefaltet wurden, deren steile Flügel nordwestwärts weisen. Sie werden wahrscheinlich durch streichende Verwerfungen zerschnitten, die die älteren Schichten im Norden herausheben.

     

Comparative phylogeography of African rain forest trees: A review of genetic signatures of vegetation history in the Guineo-Congolian region

The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.     

Structure of magnetite lodes at the Estyunino iron deposit in the central Urals

The structure of magnetite lodes is determined by iron and sulfur distribution, as well as texture and structure of ore. These features have been revealed by documentation of cores from ore intervals in exploration boreholes penetrating two main lodes 21 and 22 of the Estyunino iron deposit. The documentation of cores was accompanied by sampling for microscopic examination of texture and structure of ore and selection of Fe and S contents in ore. Then these data were summarized as sections of the lodes. It was established that the structure of magnetite lodes is characterized by conformable ore layers distinguished by texture, structure, and Fe and S contents. Banded and spotty ores containing less than 50% magnetite are predominant. Layers of homogeneous massive ore are infrequent. The textural pattern indicates a volcaniclastic nature of host rocks. The spotty texture is characteristic of hyaloclastites with vitreous shards. The banded texture with oriented distribution of fiamme is inherent to volcaniclastic rocks. In both cases, magnetite selectively replaces dark-colored vitreous fragments and is also dispersed in the salic matrix and lava fragments. No indications of crosscutting superposed relationships are observed. The available data can be satisfactorily explained by an impregnation-metasomatic mode of ore deposition.     

Structural and magnetic fabric studies of recess structures in the western Himalaya: Implications for 1905 Kangra earthquake

Kinematic information from deformation structures and magnetic fabrics are used to infer recent tectonics around Kangra and Dehradun recesses, western Himalaya. Three types of magnetic fabrics (Type I & II, III, and IV) are identified based on the angle between K3 axis and bedding pole. It was observed that Kangra recess shows more mature fabric type IV as compared to Dehradun recess, where orientation of K3 axes and tectonic fabric reveals dominance of superposed deformation. In the vicinity of Dehradun recess, normal faults occur in un-indurated Quaternary fan deposits confirming their recent formation. The observations are in conformity with earlier studies that during the 1905 Kangra earthquake, the Main Boundary Thrust (MBT) (or one of its subsidiary thrusts) near Kangra showed thrusting whereas the MBT near Dehradun underwent either normal faulting or post seismic adjustments characteristic of normal faulting. The thrusting could be a result of subsurface processes whereas the normal faulting was a result of prevailing surface strains.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

Period variations in BZ Eridani

The O-C diagram of BZ Eri has been presented for the first time, and the period variations present in the system have been analysed. In all, eight period decreases and eight period increases are noticed. Of these, four period decreases and seven period increases are appreciable. The strongest period changes are noticed in the interval 1960 to 1962. The total period change in different portions of the O-C diagram ranges from 1.17×10^–3 d to 3.96×10^–6 d. The trend of the period variation appears to have reversed around the year 1980.