The temperature dependent,infrared absorption cross-sections for the chlorofluorocarbons: CFC-11, CFC-12, CFC-13, CFC-14, CFC-22, CFC-113, CFC-114, and CFC-115

The infrared absorption cross-sections for eight commonly used halogenated methanes and ethanes have been measured as a function of temperature from 203 to 293 K. High resolution spectra (0.03 cm^-1) have been used to derive integrated band strengths and peak cross-sections associated with the spectral features in the infrared region from 600 to 1500 cm^-2. The values obtained in this study are compared to those from previous reports, and recommendations are made for uses in atmospheric sensing and radiative energy transfer models. The observed temperature dependence in the spectral features is also discussed.     

Influence of regional structure on the development and quality of the Upper Elkhorn no. 2 coal bed, eastern Kentucky

The Upper Elkhorn No. 2 coal bed (Middle Pennsylvanian Breathitt Formation) in eastern Kentucky exhibits thickness and coal quality trends which suggest that peat deposition was contemporaneous with tectonism. The coal thickens and has high vitrinite and low ash and sulfur content the Belfry anticline in Pike Country. T in the vicinity of the Floyd Country channel, a basement trough. In both cases other Pennsylvanian coals exhibit similar trends, suggesting that the penecontemporaneous tectonism persisted at least through a portion of the Carboniferous.     

Plutonic xenoliths from Martinique,Lesser Antilles: evidence for open system processes and reactive melt flow in island arc crust

The Lesser Antilles Volcanic Arc is remarkable for the abundance and variety of erupted plutonic xenoliths. These samples provide a window into the deeper crust and record a more protracted crystallisation history than is observed from lavas alone. We present a detailed petrological and in situ geochemical study of xenoliths from Martinique in order to establish their petrogenesis, pre-eruptive storage conditions and their contribution to construction of the sub-volcanic arc crust. The lavas from Martinique are controlled by crystal–liquid differentiation. Amphibole is rarely present in the erupted lavas, but it is a very common component in plutonic xenoliths, allowing us to directly test the involvement of amphibole in the petrogenesis of arc magmas. The plutonic xenoliths provide both textural and geochemical evidence of open system processes and crystal ‘cargos’. All xenoliths are plagioclase-bearing, with variable proportions of olivine, spinel, clinopyroxene, orthopyroxene and amphibole, commonly with interstitial melt. In Martinique, the sequence of crystallisation varies in sample type and differs from other islands of the Lesser Antilles arc. The compositional offset between plagioclase (~An₉₀) and olivine (~Fo₇₅), suggests crystallisation under high water contents and low pressures from an already fractionated liquid. Texturally, amphibole is either equant (crystallising early in the sequence) or interstitial (crystallising late). Interstitial amphibole is enriched in Ba and LREE compared with early crystallised amphibole and does not follow typical fractionation trends. Modelling of melt compositions indicates that a water-rich, plagioclase-undersaturated reactive melt or fluid percolated through a crystal mush, accompanied by the breakdown of clinopyroxene, and the crystallisation of amphibole. Geothermobarometry estimates and comparisons with experimental studies imply the majority of xenoliths formed in the mid-crust. Martinique cumulate xenoliths are inferred to represent crystal mushes within an open system, through which melt can both percolate and be generated.     

Tectonic significance of syn-rift sediment packages across the Gabon-Cabinda continental margin

The tectonic development of a continental margin is recorded in the stratigraphic successions preserved along and across the margin in terms of stratal relationships (e.g., onlap, downlap, truncation), lithofacies, biostratigraphy, and paleo-water depths. By using these observations coupled to a kinematic and flexural model for the deformation of the lithosphere, we have elucidated the tectonic significance of the preserved stratigraphy that comprises the Gabon-Cabinda margin of west Africa. Two hinge zones, an Eastern and Atlantic, formed along the Gabon-Cabinda margin in response to three discrete extensional events occuring from Berriasian to Aptian time. The Eastern hinge zone demarcates the eastern limit of a broadly distributed Berriasian extension that resulted in the formation of deep anoxic, lacustrine systems as evidenced by the silts and shales of the Sialivakou and lower Djeno Formations and the regressive packages of the upper Djeno Formation. Approximately 1.5 to 2 km of asymmetric footwall uplift was induced across the Eastern hinge zone in response to the mechanical unloading of the lithosphere during this first phase of rifting. In contrast, the Atlantic hinge, located approximately 90 km west of the Eastern hinge, marks the eastern limit of a second phase of extension that began in the Hauterivian. Footwall uplift and rotation exposed earlier syn-rift and pre-rift sediments to at least wavebase causing varying amounts of erosional truncation across the Atlantic hinge zone along much of the Gabon-Cabinda margins. We interpret the thickness variations of reworked clastic sediment of this age (e.g. the Melania Formation) between the hinge zones as indicative of variations in the degree of uplift and erosional truncation of the Atlantic hinge. For example, the absence of Melania Formation across the Congo margin implies that uplift of the Atlantic hinge was relatively minor compared to that across the Cabinda and Gabon margins, the latter being characterized by significant thicknesses of Melania Formation (or equivalent). Material eroded from the Cabinda and Gabon Atlantic hinge zone may in part account for the thick wedge of sediment deposited seaward of the Gabon-Cabinda Atlantic hinge (the Erva Formation). Our modelling suggests that this wedge of reworked elastics represents deposition by along-axis gravity flows within a deep water (≈2 km) environment. A third and final phase of extension in the late Barremian-early Aptian was responsible for breaching the continental lithosphere to form the ocean/continent boundary and thus the installation of open marine conditions. Elsewhere, the environments will tend to be marginal marine to brackish, depending on the efficiency of the Atlantic hinge zone to act as a barrier to marine enchroachment. This third rift phase reactivated both the Eastern and Atlantic hinge0zones thereby creating accomodation for the Marnes Noires Formation (and equivalent) source rock deposition between the hinges and the Falcão source rock equivalent seaward of the Atlantic hinge. Two possible scenarios exist for the lateral distribution of the Marnes Noires Formation. If the reactivated rift flank topography across the Atlantic hinge was significant, then sedimentation would be restricted between the hinge zones within discrete lacustrine settings (e.g., Congo margin). Alternatively, if hinge zone uplift was relatively minor, then a coral-rimmed archipelago may have developed parallel to the margin with restricted communication across the Atlantic hinge zone (e.g., Cabinda margin). In this latter scenario, dilution of the Marnes Noires source rocks by terrigenous input from the eroding Atlantic hinge zone should be relatively minor thereby enhancing source rock quality. Furthermore, potential marine upwelling outboard of the Atlantic hinge zone is likely the cause for the production and accumulation of organic-rich material associated with the Falcão source rock of the Kwanza basin. By late Aptian time, the remaining accomodation between the hinge zones was partially filled by across- and along-axis prograding deltaic systems of the Argilles Vertes and Tchibota Formations. The progradation and interaction of the Argilles Vertes depositional lobes resulted in the formation of residual paleo-relief. Subsequent marine incursions and flooding of this paleo-relief led to the development of basal conglomerates (the Chela ‘lag’ unconformity) grading upward into fine-grained sands and evaporites. Consequently, an inverse relationship should exist betweeb evaporite thickness (in particular, the lower members) and the thickness of the underlying Argilles Vertes and Tchibota Formations. Variations in Loeme evaporite thickness is a consequence of stratigraphic and structural control with salt instability influencing local variability.Our modelling suggests the occurrence of two distinct evaporite sequences on the Congo margin, an earlier evaporite deposited seaward (west) of the Atlantic hinge during the second and third rift phases and the late Aptian Loeme Formation deposited between the hinge zones. An evaporite sequence seaward of the Atlantic hinge is inferred on the basis of extensive diapirs and salt tectonic structures observed in seismic data. In order to match the distribution and thickness of the observed post-salt stratigraphy across the basin, however, we require large paleowater depths west of the Atlantic hinge during the later Aptian. The existence of large paleowater depths precludes the formation of thick evaporite sequences within the outer basin. Consequently, we propose that the evaporites seaward of the Atlantic hinge were formed during the syn-rift development of the margin and are not contemporaneous with the post-rift Loeme salts deposited between the hinge zones. This double salt hypothesis is consistent with observations from the conjugate Brazilian margin.     

Two sulphur isotope provinces deduced from ores in the Mount Isa Eastern Succession,Australia

The sulphur isotopic characteristics of ore deposits in the Australian Mount Isa Eastern Succession are not well known, unlike those of the Western Succession. In this study new detailed analyses are provided for recently discovered Eastern Succession mineralisation, such as the Starra and Osborne BIF-hosted Cu-Au ores, the Dugald River sediment-hosted Pb-Zn prospect, and four vein-hosted Cloncurry-style Cu±Au deposits (Hampden, Mt Elliot/Swan, Mt Cobalt, and the Answer Mine). All of the deposits of the Eastern Succession have ³⁴S_sulphide between –8 and +9%., regardless of their genesis. Empirically a moderate (³⁴S range averaging close to 0%. characterises Starra-style Cu-Au and Pegmont Pb-Zn BIF ores, whereas shear and vein-style Cu mineralisation populations are tighter and do not average close to 0%. This is a particularly surprising result for Dugald River, where a larger isotopic variation more typical of stratiform sediment-hosted Pb-Zn ores in the region might have been expected. By comparison, Western Succession stratiform Pb-Zn and vein-style Cu deposits span a huge range of-15 to 51%. Large sulphur isotope ranges typify sulphate evaporite or organic sulphur-rich sedimentary successions. The lack of such variation in the Eastern Succession in turn suggests that primary evaporite sequences there were halite-dominated but sulphate-poor, and/or contained only limited volumes of organic-sulphur-rich sediment. Eastern Succession sequences were therefore less likely hosts for giant stratiform Pb-Zn deposits, because of their paucity of sulphur, although local sulphur sources permitted small deposits such as Dugald River to develop. Sedimentary conditions were more favourable for the development of sulphur-poor synsedimentary hydrothermal systems such as Starra, Osborne, and Pegmont, although sulphur isotope evidence is equivocal about the origin of these. Epigenetic deposits close to the Williams Batholith (Mt Dore, Hampden) owe their clustering around 0%. to their granitic fluid source.     

Synthesis of zinc oxide–montmorillonite composite and its effect on the removal of aqueous lead ions

Acta Geochimica - Lead adsorption of zinc oxide-coated ACOR montmorillonite was investigated in batches and under reducing conditions at ambient temperature. The presence of zinc oxide coating...     

Role of melt during deformation in the deep crust

Deformation in the deep crust is strongly influenced by the presence of melt. Injected melt (or magma) weakens the crust because strain will tend to localize where melt is present. The amount of strain a pluton may accommodate is dependent on the length of time it takes for a pluton to crystallize and the strain rate. For plutons that intrude into rocks which are near the solidus temperature of the melt, crystallization times can be quite long (> 1Myr).
Partial melting of deep crustal rocks can lead to melt-enhanced embrittlement. This occurs because the volume change for most melting reactions is positive. Therefore, when the rate of melt production outpaces the rate at which melt can leave the system, the melt pressure increases. Eventually, the melt pressure may become sufficiently high that the melting rocks behave in a brittle fashion and fracture.
Conjugate sets of dilatant shear fractures filled with melt occur in migmatite from the Central Gneiss belt (Canada); this suggests that melt-enhanced embrittlement occurred in these rocks. An expression which relates the magnitude of differential stress to the angle between conjugate dilatant shear fractures is derived. Assuming that migmatite has a small tensile strength, differential stresses are ≤ 20 MPa in migmatitic rocks at the time melt-enhanced embrittlement occurs. The occurrence of melt-enhanced embrittlement shows that a switch in deformation mechanism from plastic flow to cataclasis is possible in the deep crust during melting. Furthermore, repeated episodes of melt-enhanced embrittlement in migmatitic rocks may be an efficient mechanism for extracting melt from partially melted terrains.     

Variationally adjusted surface winds

This paper describes a one-level variational adjustment process for producing mass-consistent surface winds in the Barrow Strait area, N.W.T. To achieve this result, the continuity equation is employed as a physical constraint. The variational technique adjusts mean winds (vertically averaged through the planetary boundary layer); therefore, a relationship is required between surface and mean winds. Use is made of existing velocity profiles, but interpolation may be used between surface and geostrophic winds. The model was found to be strongly dependent upon specification of boundary-layer height. Channeling effects are not readily seen until topography begins to protrude through the boundary layer. The model might thus be better suited to areas where shallow inversion layers are well defined. By application of the variational adjustment, errors in continuity are reduced by six orders of magnitude. Upon comparison of the variational technique with a diagnostic, one-level, primitive equation model, median errors between computed and observed surface winds were found to be comparable.     

The role of topography in controlling throughflow generation: A discussion

The distributions of specific catchment area and specific dispersal area values over the hillside studied by Anderson and Burt (1978) relate much more closely to the observed distributions of soil water matric potential than do the occurrences of contour concavity on which the authors rely. Highest potential always occurred in the zone of large specific catchment area except immediately after rainfall, when it occurred in the zone of small dispersal area. Isolines of low potential persistently conformed to those of specific dispersal area.