Sea‐level response at Nain,Labrador, to atmospheric pressure and wind

Abstract

Two years of subtidal sea‐level data from Nain, Labrador, are analysed in terms of local atmospheric pressure and the two components of geostrophic wind or stress. Frequency‐dependent response coefficients are determined by multiple regression analysis involving inversion of the cross‐spectral matrix of the inputs. At very low frequencies the response to pressure is isostatic and the wind stress coefficients are consistent with those determined by Thompson et al. (1985) from analysis of a longer series of monthly means. There is very little change in the response between icy and ice‐free seasons. The wind, or stress, coefficients correspond to geostrophic set‐up by a narrow longshore current but do not show as much of an increase of phase lag with increasing frequency as expected. The pressure response is less than isostatic and lags as the frequency increases from zero to about 0.02 cph. Possible reasons for this are discussed. Removal of wind as well as pressure effects ffom the sea‐level data makes only minor changes to the monthly mean residual sea‐level.     

Harmful algal bloom species and phosphate-processing effluent: field and laboratory studies

In 2002, the Florida Department of Environmental Protection began discharging phosphate-processing effluent into Bishop Harbor, an estuary within Tampa Bay. Because of concerns that the effluent would serve as a nutrient source for blooms of the toxic dinoflagellate Karenia brevis, a field monitoring program was established and laboratory bioassays were conducted. Several harmful algal bloom (HAB) species, including Prorocentrum minimum and Heterosigma akashiwo, were observed in bloom concentrations adjacent to the effluent discharge site. Blooms of diatoms were widespread throughout Bishop Harbor. K. brevis was observed with cell concentrations decreasing with increasing proximity to the effluent discharge site. Bioassays using effluent as a nutrient source for K. brevis resulted in decreased cell yields, increased growth rates, and increased time to log-phase growth. The responses of HAB species within Bishop Harbor and of K. brevis to effluent in bioassays suggested that HAB species differ in their response to phosphate-processing effluent.     

Tracing dissolved O2 and dissolved inorganic carbon stable isotope dynamics in the Nyack aquifer: Middle Fork Flathead River, Montana, USA

The geochemistry and microbiology of shallow groundwater aquifers is greatly influenced by the concentration of dissolved oxygen gas (DO); however, the mechanisms that consume DO in groundwater (e.g., biotic or abiotic) are often ambiguous. The use of stable isotopes of molecular O₂ (δ¹⁸O-DO), in conjunction with stable isotopes of dissolved inorganic carbon (δ¹³C-DIC), has potential to discriminate between the various mechanisms causing DO depletion in subsurface waters.Here we report the results of spatial and seasonal changes in δ¹⁸O-DO and δ¹³C-DIC at the Nyack floodplain aquifer along the Middle Fork of the Flathead River near West Glacier, Montana, USA. Over a short, well constrained flow path (∼100 m) near a main recharge zone of the floodplain, the δ¹⁸O-DO consistently increased as DO concentrations decreased with distance from the recharge source. Concurrently, DIC concentrations increased and δ¹³C-DIC values decreased. These observations are explained by community respiration coupled with dissolution of calcite from cobbles in the aquifer matrix. When these results are compared to data from wells distributed over the entire floodplain (several km) a much less predictable relationship was observed between DO concentration and δ¹⁸O-DO. Many wells with low DO concentrations (e.g., <125 μmol L⁻¹ or 4 mg L⁻¹) had anomalously low δ¹⁸O-DO values (e.g., <20‰). Mass balance calculations show that approximately equal amounts of O₂ may be contributed to the aquifer by diffusion from the vadose zone and by advection from the river recharge. Calculations presented here suggest that diffusion across a narrow air-water interface can contribute isotopically light δ¹⁸O-DO to the saturated zone. Possible contributions of light δ¹⁸O-DO from other processes, such as isotopic exchange and radial oxygen loss from plant roots in or near the water table, are compared and evaluated.     

Space-Time scales of internal waves

Abstract

We have contrived a model E(αω) α μ^?1ω^?p+1(ω ²?ω _i ²)^?+ for the distribution of internal wave energy in horizontal wavenumber, frequency-space, with wavenumber α extending to some upper limit μ(ω) α ω ^r-1 (ω ²?ω _i ²)^½, and frequency ω extending from the inertial frequency ω _i to the local Väisälä frequency n(y). The spectrum is portrayed as an equivalent continuum to which the modal structure (if it exists) is not vital. We assume horizontal isotropy, E(α, ω) = 2παE(α₁, α₂, ω), with α₁, α₂ designating components of α. Certain moments of E(α₁, α₂, ω) can be derived from observations. (i) Moored (or freely floating) devices measuring horizontal current u(t), vertical displacement η(t),…, yield the frequency spectra F _(u,η,…)(ω) = ∫∫ (U ², Z ²,…)E(α₁, ∞₂, ω) dα₁ dα₂, where U, Z,… are the appropriate wave functions. (ii) Similarly towed measurements give the wavenumber spectrum F _(…)(α1) = ∫∫… dα₂ dω. (iii) Moored measurements horizontally separated by X yield the coherence spectrum R(X, ω) which is related to the horizontal cosine transform ∫∫ E(α1, α2 ω) cos α₁ Xdα₁ dα₁. (iv) Moored measurements vertically separated by Y yield R(Y, ω) and (v) towed measurements vertically separated yield R(Y, α₁), and these are related to similar vertical Fourier transforms. Away from inertial frequencies, our model E(α, ω) α ω ^?p-r for α ≦ μ ω ω ^r, yields F(ω) ∞ ω ^?p, F(α₁) ∞ α₁ ^?q, with q = (p + r ? 1)/r. The observed moored and towed spectra suggest p and q between 5/3 and 2, yielding r between 2/3 and 3/2, inconsistent with a value of r = 2 derived from Webster's measurements of moored vertical coherence. We ascribe Webster's result to the oceanic fine-structure. Our choice (p, q, r) = (2, 2, 1) is then not inconsistent with existing evidence. The spectrum is E(∞, ω) ∞ ω ^?1(ω ²?ω _i ^{2 ?1}, and the α-bandwith μ ∞ (ω ²?ω _i ²)⁺ is equivalent to about 20 modes. Finally, we consider the frequency-of-encounter spectra F([sgrave]) at any towing speed S, approaching F(ω) as S ≦ S _o, and F(α₁) for α₁ = [sgrave]/S as S ≧ S _o, where S _o = 0(1 km/h) is the relevant Doppler velocity scale.     

Detection of radiation pressure acting on 2009 BD

We report the direct detection of radiation pressure on the asteroid 2009 BD, one of the smallest multi-opposition near-Earth objects currently known, with H ∼ 28.4. Under the purely gravitational model of NEODyS the object is currently considered a possible future impactor, with impact solutions starting in 2071. The detection of a radiation-related acceleration allows us to estimate an Area to Mass Ratio (AMR) for the object, that can be converted (under some assumptions) into a range of possible values for its average density. Our result AMR = (2.97 ± 0.33) × 10⁻⁴ m² kg⁻¹ is compatible with the object being of natural origin, and it is narrow enough to exclude a man-made nature. The possible origin of this object, its future observability, and the importance of radiation pressure in the impact monitoring process are also discussed.     

An Elliptical Model for Deformation Due to Groundwater Fluctuations

Historically, surface subsidence as a result of subsurface groundwater fluctuations have produced important and, at times, catastrophic effects, whether natural or anthropogenic. Over the past 30?years, numerical and analytical techniques for the modeling of this surface deformation, based upon elastic and poroelastic theory, have been remarkably successful in predicting the magnitude of that deformation (Le Mouélic and Adragna in Geophys Res Lett 29:1853, 2002). In this work we have extended the formula for a circular-shaped aquifer (Geertsma in J Petroleum Tech 25:734–744, 1973) to a more realistic elliptical shape. We have improved the accuracy of the approximation by making use of the cross terms of the expansion for the elliptic coordinates in terms of the eccentricity, e, and the mean anomaly angle, M, widely used in astronomy. Results of a number of simulations, in terms of e and M developed from the transcendental Kepler equation, are encouraging, giving realistic values for the elliptical approximation of the vertical deformation due to groundwater change. Finally, we have applied the algorithm to modeling of groundwater in southern California.     

Pilot studies for the North American Soil Geochemical Landscapes Project – Site selection, sampling protocols, analytical methods, and quality control protocols

In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada sampled and chemically analyzed soils along two transects across Canada and the USA in preparation for a planned soil geochemical survey of North America. This effort was a pilot study to test and refine sampling protocols, analytical methods, quality control protocols, and field logistics for the continental survey. A total of 220 sample sites were selected at approximately 40-km intervals along the two transects. The ideal sampling protocol at each site called for a sample from a depth of 0–5 cm and a composite of each of the O, A, and C horizons. The <2-mm fraction of each sample was analyzed for Al, Ca, Fe, K, Mg, Na, S, Ti, Ag, As, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y, and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO₃, HClO₄, and HF. Separate methods were used for Hg, Se, total C, and carbonate-C on this same size fraction. Only Ag, In, and Te had a large percentage of concentrations below the detection limit. Quality control (QC) of the analyses was monitored at three levels: the laboratory performing the analysis, the USGS QC officer, and the principal investigator for the study. This level of review resulted in an average of one QC sample for every 20 field samples, which proved to be minimally adequate for such a large-scale survey. Additional QC samples should be added to monitor within-batch quality to the extent that no more than 10 samples are analyzed between a QC sample. Only Cr (77%), Y (82%), and Sb (80%) fell outside the acceptable limits of accuracy (% recovery between 85 and 115%) because of likely residence in mineral phases resistant to the acid digestion.A separate sample of 0–5-cm material was collected at each site for determination of organic compounds. A subset of 73 of these samples was analyzed for a suite of 19 organochlorine pesticides by gas chromatography. Only three of these samples had detectable pesticide concentrations. A separate sample of A-horizon soil was collected for microbial characterization by phospholipid fatty acid analysis (PLFA), soil enzyme assays, and determination of selected human and agricultural pathogens. Collection, preservation and analysis of samples for both organic compounds and microbial characterization add a great degree of complication to the sampling and preservation protocols and a significant increase to the cost for a continental-scale survey. Both these issues must be considered carefully prior to adopting these parameters as part of the soil geochemical survey of North America.     

Comparison of satellite and ship observations for total cloud amount

The data series of monthly clouldiness over global ocean from COADS was compared with that of from satellite Nimbus-7 during April 1979 to March 1985. The correspondence between them is good. Both the two methods of observation can provide useful information of the distribution of cloudiness and the two data sets can be mutually complementary.