Effects of core formation

Two sets of earth models have been generated which simulate the process of core formation in the earth. The results allow the evaluation of the distribution of energy release by core formation and thus an estimate of the early temperature profile following core formation. The process itself is likely to have taken 20 Ma or less, although a longer induction period during which some metal phase exists as a melt is probable. Much of the energy (half or more) ends up in a hot core with the mantle relatively cold. These results suggest the occurrence of mantle wide convection, leading to homogenization and the possible stripping of some elements from the mantle.     

Core formation in terrestrial planets

Calculations of the radial distribution of the energy released in core formation indicate that the cores of all the terrestrial planets may be expected to receive a disproportionate share of the gravitational energy released. Since the model of the process used in these calculations favors transfer of energy to the mantle, it is likely that other reasonable models of the process will result in even more energy being deposited in the cores of the early planets. The calculations also show that it is necessary for a certain amount of core phase to separate and accumulate, before the energy released by gravitational settling is sufficient to supply the latent heat of fusion of the core phase. The amount of melting required to reach this point varies according to the total mass of the planet, and mass fraction of core, but is not particularly great (<5% for the Earth to ～ 37% for the Moon). In the case of the Moon, this amount of segregation, although large, amounts to a surface layer about 260 km thick, similar to the proposed depth of early wholesale melting. Core separation in terrestrial planets appears to be a self-sustaining process even for fairly small bodies, provided that a small amount of a dense potential core phase is present. Although it seems likely to occur rapidly (within 10⁶–10⁷ years) even for small (Moon-size) bodies, detailed kinetic models will be necessary to specify the time scale.     

Radiance and color of the sky at twilight: Perturbations caused by stratospheric haze

Layers of stratospheric aerosol with optical thicknesses as small as 10^–4 cause noticeable perturbations in the monochromatic logarithmic brightness gradient,G, and the color ratio,C, of the twilight sky. Modeling of the twilight's radiant properties shows that definite single-valued relationships exist between maxima inC or minima inG and optical thickness, , physical thickness h, and mean altitude, , of stratospheric layers. It is therefore possible to determine , h and and monitor their variations by performing either single wavelength measurements ofG or two-wavelength spectrophotometric measurements ofC. The presence of haze in the lower troposphere and the occurrence of multiple scattering both have relatively minor influences on the recovery of the stratospheric dust properties, provided that 10< <30 km.Formal mathematical inversions of the single-scattering twilight equations are possible in principle, but difficult in practice because of non-linearities. Inversions incorporating an iterative linearization process with constrained smoothing, successfully recovered the features of the haze layer, but tended to oversmooth the vertical profile and underestimate the mean altitude of the haze layer.     

Polychlorinated biphenyls in the Brisbane River estuary, Australia

The concentrations of PCBs in water, sediments, fish (6 species), crustacea (3 species), molluscs (1 species), polychaetes (mixed species) and birds (1 species) from the Brisbane River estuary were determined. Levels were comparable to other similar situations elsewhere. No relationship was found between trophic class and PCB concentration although pelicans at the highest trophic level examined exhibited the highest muscle tissue concentration (i.e., 15.7 mg kg⁻¹ on a wet weight basis). The pattern of distribution of PCBs within body tissues of fish was closely related to lipid content.     

Measurements of Reaction Coefficients of NO2 and HONO on Aerosol Particles

The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO₂ afford a reaction coefficient in the range (2.8–10) × 10^-4 and for HONO, (2.8–4.6) × 10^-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO₂. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies.     

Evaluating GCM Output with Impact Models

This study uses empirical agricultural impact models to compare the U.S. climate change predictions of 16 General Circulation Models (GCMs). The impact analysis provides a policy-relevant index by which to judge complex climate predictions. National aggregate impacts vary widely across the 16 GCMs because of varying regional and seasonal patterns of predicted climate change. Examining the predicted impacts from the full set of GCMs reveals that the seasonal detail in the GCM predictions is so noisy that it is not significantly different from a constant annual change. However, a consistent regional pattern does emerge across the set of models. Nonetheless, aggregating climate change across seasons and regions within the United States, using a national-annual climate change provides a reasonable and efficient approximation to the expected impact predicted by the 16 GCM models.     

A new solution for a partially penetrating constant‐rate pumping well with a finite‐thickness skin

A mathematical model describing the constant pumping is developed for a partially penetrating well in a heterogeneous aquifer system. The Laplace‐domain solution for the model is derived by applying the Laplace transforms with respect to time and the finite Fourier cosine transforms with respect to vertical co‐ordinates. This solution is used to produce the curves of dimensionless drawdown versus dimensionless time to investigate the influences of the patch zone and well partial penetration on the drawdown distributions. The results show that the dimensionless drawdown depends on the hydraulic properties of the patch and formation zones. The effect of a partially penetrating well on the drawdown with a negative patch zone is larger than that with a positive patch zone. For a single‐zone aquifer case, neglecting the effect of a well radius will give significant error in estimating dimensionless drawdown, especially when dimensionless distance is small. The dimensionless drawdown curves for cases with and without considering the well radius approach the Hantush equation (Advances in Hydroscience. Academic Press: New York, 1964) at large time and/or large distance away from a test well. Copyright © 2007 John Wiley & Sons, Ltd.     

Jet Deflection by a Quasi-Steady-State Side Wind in the Laboratory

We present experimental data on the steady state deflection of a highly supersonic jet by a side-wind in the laboratory. The use of a long interaction region enables internal shocks to fully cross the jet, leading to the development of significantly more structure in the jet than in previous work with a similar setup (Lebedev et al., 2004). The ability to control the length of the interaction region in the laboratory allows the switch between a regime representing a clumpy jet or wind and a regime similar to a slowly varying mass loss rate. The results indicate that multiple internal oblique shocks develop in the jet and the possible formation of a second working surface as the jet attempts to tunnel through the ambient medium.     

Assessing possible changes in flood frequency due to climate change in mid‐sized watersheds in New York State,USA

The frequency of flooding is often presumed to increase with climate change because of projected increases in rainfall intensities. In this paper, using 50‐plus years of historical discharge and meteorological data from three watersheds in different physiographic regions of New York State, USA, we find that annual maximum stream discharges are associated with 20% or less of the annual maximum rainfall events. Instead of rainfall events, approximately 20% of annual maximum stream discharges are associated with annual maximum snowmelt events while 60% of annual maximum discharges are associated with moderate rainfall amounts and very wet soil conditions. To explore the potential for changes in future flood risk, we employed a compound frequency distribution that assumes annual maximum discharges can be modelled by combining the cumulative distribution functions of discharges resulting from annual maximum rainfall, annual maximum snowmelt, and occurrences of moderate rain on wet soils. Basing on a compound frequency distribution comprised of univariate general extreme value (GEV) and gamma distributions, we found that a hypothetical 20% increase in the magnitude of rainfall‐related stream discharge results in little change in 96th percentile annual maximum discharge. For the 99th percentile discharge, two waterbodies in our study had a 10% or less increase in annual maximum discharge when annual maximum rainfall‐related discharges increased 20% while the third waterbody had a 16% increase in annual maximum discharges. Additionally, in some cases, annual maximum discharges could be offset by a reduction in the discharge resulting from annual maximum snowmelt events. While only intended as a heuristic tool to explore the interaction among different flood‐causing mechanisms, use of a compound flood frequency distribution suggests a case can be made that not all waterbodies in humid, cold regions will see extensive changes in flooding due to increased rainfall intensities. Copyright © 2011 John Wiley & Sons, Ltd.