Bubble nucleation in rhyolite and dacite melts: temperature dependence of surface tension

Surface tension (σ) profoundly influences the ability of gas bubbles to nucleate in silicate melts. To determine how temperature impacts σ, experiments were carried out in which high-silica rhyolite melts with 5 wt% dissolved water were decompressed at temperatures that ranged from 775 to 1,085°C. Decompressions were also carried out using dacite melts with 4.3 wt% dissolved water at 1,150°C. Water bubbles nucleated in rhyolite only when decompressions exceeded 95 MPa at all temperatures. Bubbles nucleated in number densities that increased as decompression increased and at hotter temperatures at a given amount of decompression. After correcting decompression amounts for temperature differences, values for σ were estimated from nucleation rates and found to vary between 0.081 and 0.093 N m⁻¹. Surface tension decreases as temperature increases from 775 to 875°C, but then increases as temperature increases to 1,085°C. Those values overlap previous results, but only when melt viscosity is less than 10⁴ Pa s. For low-viscosity rhyolite, there is a strong correlation of σ with temperature, in which σ increases by 6.9 × 10⁻⁵ N m⁻¹ C⁻¹. That variation is robust for 5–9 wt% dissolved water, as long as melt viscosity is ≤10⁴ Pa s. More viscous rhyolite deviates from that correlation probably because nucleation is retarded in stiffer melts. Bubbles nucleated in dacite when decompressions exceeded 87 MPa, and occured in one or more events as decompression increased. Surface tension is estimated to be 0.083 (±0.001) N m⁻¹ and when adjusted for temperature agrees well with previous results for colder and wetter dacite melts. At a given water content, dacite melts have lower surface tensions than rhyolite melts, when corrected to a fixed temperature.     

Application of the littoral cell concept to managing a protected atoll: Palmyra Atoll National Wildlife Refuge

The recognition of littoral sediment cells has proven valuable to coastal zone management in many areas of the world because it emphasises that sediment transport and deposition relate to physical processes rather than to administrative boundaries and that sedimentary units are self-contained. To date, cells identified for shoreline management planning are often extensive, extending for tens to hundreds of km. We suggest that the concept is also applicable to the management of atoll coastlines which, although spatially very small overall, consist of isolated segments with efficient intervening sediment sinks. As an example, Palmyra Atoll, a protected wildlife refuge in the northern Line Islands, is undergoing natural major changes resulting from sediment-related processes. Defining sediment cells as integral parts of management units here will aid decision-making necessary for the protection of specific areas, potentially giving savings in research effort and remedial costs and minimising disruption to other sensitive areas of the reserve. Similar benefits would apply to the management of the coastlines of other atolls.     

Land cover effects on soil infiltration capacity measured using plot scale rainfall simulation in steep tropical lowlands of Central Panama

Understanding land use/land cover (LULC) effects on tropical soil infiltration is crucial for maximizing watershed scale hydro-ecosystem services and informing land managers. This paper reports results from a multiyear investigation of LULC effects on soil bulk infiltration in steep, humid tropical, and lowland catchments. A rainfall simulator applied water at measured rates on 2 × 6 m plots producing infiltration through structured, granulated, and macroporous Ferralsols in Panama's central lowlands. Time-lapse electrical resistivity tomography (ERT) helped to visualize infiltration depth and bulk velocity. A space-for-time substitution methodology allowed a land-use history investigation by considering the following: (a) a continuously heavy-grazed cattle pasture, (b) a rotationally grazed traditional cattle pasture, (c) a 4-year-old (y.o.) silvopastoral system with nonnative improved pasture grasses and managed intensive rotational grazing, (d) a 7 y.o. teak (Tectona grandis) plantation, (e) an approximately 10 y.o. secondary succession forest, (f) a 12 y.o. coffee plantation (Coffea canephora), (g) an approximately 30 y.o. secondary succession forest, and (h) a >100 y.o. secondary succession forest. Within a land cover, unique plot sites totalled two at (a), (c), (d), (e), and (g); three at (b); and one at (f) and (h). Our observations confirmed measured infiltration scale dependency by comparing our 12 m² plot-scale measurements against 8.9 cm diameter core-scale measurements collected by others from nearby sites. Preferential flow pathways (PFPs) significantly increased soil infiltration capacity, particularly in forests greater than or equal to 10 y.o. Time-lapse ERT observations revealed shallower rapid bulk infiltration and increased rapid lateral subsurface flow in pasture land covers when compared with forest land covers and highlighted how much subsurface flow pathways can vary within the Ferralsol soil class. Results suggest that LULC effects on PFPs are the dominant mechanism by which LULC affects throughfall partitioning, runoff generation, and flow pathways.     

Dark matter subhaloes in numerical simulations

We use cosmological Λ cold dark matter (CDM) numerical simulations to model the evolution of the substructure population in 16 dark matter haloes with resolutions of up to seven million particles within the virial radius. The combined substructure circular velocity distribution function (VDF) for hosts of 10¹¹ to  10¹⁴ M_⊙  at redshifts from zero to two or higher has a self-similar shape, is independent of host halo mass and redshift, and follows the relation  d n /d v = (1/8)( v _cmax/ v _cmax,host)⁻⁴  . Halo to halo variance in the VDF is a factor of roughly 2 to 4. At high redshifts, we find preliminary evidence for fewer large substructure haloes (subhaloes). Specific angular momenta are significantly lower for subhaloes nearer the host halo centre where tidal stripping is more effective. The radial distribution of subhaloes is marginally consistent with the mass profile for   r ≳ 0.3 r _vir  , where the possibility of artificial numerical disruption of subhaloes can be most reliably excluded by our convergence study, although a subhalo distribution that is shallower than the mass profile is favoured. Subhalo masses but not circular velocities decrease towards the host centre. Subhalo velocity dispersions hint at a positive velocity bias at small radii. There is a weak bias towards more circular orbits at lower redshift, especially at small radii. We additionally model a cluster in several power-law cosmologies of   P ∝ kⁿ   , and demonstrate that a steeper spectral index, n , results in significantly less substructure.     

Episodic intraplate deformation of stable continental margins: evidence from Late Neogene and Quaternary marine terraces,Cape Liptrap,Southeastern Australia

The Waratah Fault is a northeast trending, high angle, reverse fault in the Late Paleozoic Lachlan Fold Belt at Cape Liptrap on the Southeastern Australian Coast. It is susceptible to reactivation in the modern intraplate stress field in Southeast Australia and exhibits Late Pliocene to Late Pleistocene reactivation. Radiocarbon, optically stimulated luminescence (OSL), and cosmogenic radionuclide (CRN) dating of marine terraces on Cape Liptrap are used to constrain rates of displacement across the reactivated Waratah Fault. Six marine terraces, numbered Qt₆–Tt₁ (youngest to oldest), are well developed at Cape Liptrap with altitudes ranging from ～1.5 m to ～170 m amsl, respectively. On the lowest terrace, Qt₆, barnacles in wave-cut notches ～1.5 m amsl, yielded a radiocarbon age of 6090–5880 Cal BP, and reflect the local mid-Holocene sea level highstand. Qt₅ yielded four OSL ages from scattered locations around the cape ranging from ～80 ka to ～130 ka. It formed during the Last Interglacial sea level highstand (MIS 5e) at ～125 ka. Inner edge elevations (approximate paleo high tide line) for Qt₅ occur at distinctly different elevations on opposite sides of the Waratah Fault. Offsets of the inner edges across the fault range from 1.3 m to 5.1 m with displacement rates ranging from 0.01 mm/a to 0.04 mm/a. The most extensive terrace, Tt₄, yielded four Early Pleistocene cosmogenic radionuclide (CRN) ages: two apparent burial ages of 0.858 Ma ± 0.16 Ma and 1.25 Ma ± 0.265 Ma, and two apparent exposure ages of 1.071 Ma ± 0.071 Ma (¹⁰Be) and 0.798 Ma ± 0.066 Ma (²⁶Al). Allowing for muonic production effects from insufficient burial depths, the depth corrected CRN burial ages are 1.8 Ma ± 0.56 Ma and 2.52 Ma ± 0.88 Ma, or Late Pliocene. A Late Pliocene age is our preferred age. Offsets of Tt₄ across the Waratah Fault range from a minimum of ～20 m for terrace surface treads to a maximum of ～70 m for terrace bedrock straths. Calculated displacement rates for Tt₄ range from 0.01 mm/a to 0.04 mm/a (using a Late Pliocene age, ～2 Ma), identical to the rates calculated for the Last Interglacial terrace, Qt₅. This indicates that deformation at Cape Liptrap has been ongoing at similar time-averaged rates at least since the Late Pliocene. The upper terraces in the sequence, Tt₃ (～110 m amsl), Tt₂ (～140 m) and Tt₁ (～180 m) are undated, but most likely correlate to sea level highstands in the Neogene. Terraces Tt1–Tt4 show an increasing northward tilt with age.The Waratah Fault forms a prominent structural boundary in the Lachlan Fold Belt discernible from airborne magnetic and bouger gravity anomalies. Seismicity and deformation are episodic. Episodic movement on the Waratah Fault may be coincident with sea level highstands since the Late Pliocene, possibly from increased loading and elevated pore pressure within the fault zone. This suggests that intervals between major seismic events could be on the order of 100 ka.     

Tracking UVCS/SOHO Responsivity with Observations of <Emphasis Type="Italic">ζ</Emphasis> Tau

We have tracked the spectral responsivity of the ultraviolet channels of the UVCS (Ultraviolet Coronagraph Spectrometer) instrument on SOHO by repeated observations of a stable hot star. We demonstrate first that the ultraviolet spectral irradiance of the Be star ζ Tau (HD 37202) for the 100- to 125-nm wavelength range has been sufficiently constant for our purposes when measured periodically over the course of the SOHO mission. We then use ζ Tau as a radiometric transfer standard to determine an average decrease beginning in November of 1998 of 13.0% per year in the responsivity of the UVCS O vi channel for wavelengths near H i Ly α and for a particular UVCS unvignetted aperture used for science observations. The calibration tracking method involves separating two ζ Tau spectral regions that are overlapped on part of the detector. The change in the responsivity of UVCS/SOHO began in late 1998 as determined by comparison of simultaneous observations of the corona carried out with UVCS/SOHO and the freshly-calibrated UVCS instrument on the Spartan 201 satellite in early November of 1998. B. Valcu now at BrainLAB, Inc, 3 Westbrook Corporate Ctr., Tower 3, Suite 400, Westchester, IL 60154, USA, e-mail: bogdan.valcu@brainlab.com or Bogdan_valcu@hotmail.com     

Long-term Evolution of the Outgassing of Comet Hale-Bopp From Radio Observations

C/1995 O1 (Hale-Bopp) has been observed on a regular basis since August 1995 at millimetre and submillimetre wavelengths using IRAM, JCMT, CSO and SEST radio telescopes. The production rates of eight molecular species (CO, HCN, CH₃OH, H₂CO,H₂S, CS, CH₃CN,HNC) have been monitored as a function of heliocentric distance(r_h from 7 AU pre-perihelion to 4 AU post-perihelion. As comet Hale-Bopp approached and receded from the Sun, these species displayed different behaviours. Far from the Sun, the most volatile species were found in general relatively more abundant in the coma. In comparison to other species, HNC, H₂CO and CS showed a much steeper increase of the production rate with decreasing r_h. Less than 1.5 AU from the Sun, the relative abundances were fairly stable and approached those found in other comets near 1 AU. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about10 K at 7 AU to 110 K around perihelion. The expansion velocity of the gaseous species, derived from the line shapes, also increased with a law close tor_h ³. This revised version was published online in July 2006 with corrections to the Cover Date.     

First Results from the Soho Ultraviolet Coronagraph Spectrometer

The SOHO Ultraviolet Coronagraph Spectrometer (UVCS/SOHO) is being used to observe the extended solar corona from 1.25 to 10 R⊙ from Sun center. Initial observations of polar coronal holes and equatorial streamers are described. The observations include measurements of spectral line profiles for HI Lα and Lβ, Ovi 1032 Å and 1037 Å, Mgx 625 Å, Fexii 1242 Å and several others. Intensities for Mgx 610 Å, Sixii 499 Å, and 520 Å, Sx 1196 Å, and 22 others have been observed. Preliminary results for derived H⁰, O⁵⁺, Mg₉₊, and Fe¹¹⁺ velocity distributions and initial indications of outflow velocities for O⁵⁺ are described. In streamers, the H⁰ velocity distribution along the line of sight (specified by the value at e^-1, along the line of sight) decreases from a maximum value of about 180 km s^-1 at 2 R⊙ to about 140 km s^-1 at 8 R⊙. The value for O⁵⁺ increases with height reaching a value of 150 km s^-1 at 4.7 R⊙. In polar coronal holes, the O⁵⁺ velocity at e^-1 is about equal to that of H⁰ at 1.7 R⊙ and significantly larger at 2.1 R⊙. The O⁵⁺ in both streamers and coronal holes were found to have anisotropic velocity distributions with the smaller values in the radial direction.     

Ground-Truthing 11- to 12-kHz side-scan sonar imagery in the Norwegian–Greenland Sea: Part II: Probable diapirs on the Bear Island fan slide valley margins and the Vøring Plateau

SeaMARC II (11- to 12-kHz) side-scan sonar revealed hundreds of small strong-backscatter spots, tens to 500?m in diameter, along the lips of the Bear Island fan slide valley. New bathymetry, deep-tow side-scan, deep-tow profiles, heatflow, and gravity cores were collected for ground-truth. These mounds are probably mud diapirs (or mud-built mounds) typically 10–75?m high, formed by glacial sediment mobilized by Late Pleistocene slide events. The mounds are arranged along NNE trending lines, suggesting control by intrasedimentary faults ca. 0.5–1 km apart. Diapirs examined on the Vøring Plateau exhibit WNW structural control. No heatflow anomaly was found in four stations on or next to diapirs in either area.     

Simulation of sulfate-dependent sulfate reduction using Monod kinetics

A simple computer code is presented for simulating the dependence of sulfate reduction on sulfate concentration using Monod kinetics. Unlike previous models, the code provides a numerical initial value problem solution, rather than a two-point boundary value solution, for the Monod model using a search procedure to find the correct starting value for the derivative of sulfate concentration with respect to depth. Accordingly the code is not restricted to cases where sulfate vanishes at finite depth but also can be used to model situations where organic matter is exhausted before total depletion of sulfate can occur. In such situations, the code demonstrates that profiles generated using Monod kinetics differ significantly from those generated using the simple sulfate-independent model proposed by Berner (1964), even when the asymptotic concentration of sulfate at depth remains well above the Monod saturation constant.