激光探针质谱及单颗粒矿物^40Ar／^39Ar法年龄的测定

将掺钕的钇铝榴石（Ｎｄ：ＹＡＧ）激光器与高精密ＭＭ１２００质谱计、电子倍增器联网，应用连续激光质谱对单颗粒矿物、光片样品进行微区４０Ａｒ／３９Ａｒ测年、坪年龄和等时线年龄研究。在光片上测定南极乔治王岛北海岸玄武岩等时线年龄（５２．３８±１．０５）Ｍａ和贵州绿豆岩年龄（２３９．１６±１４．１３）Ｍａ，两者与实际地质背景吻合。对两个中生代和太古代单颗粒黑云母进行连续激光质谱阶段升温４０Ａｒ／３９Ａｒ坪年龄谱测定，获得与常规法相一致的坪年龄谱     

Dye adsorption on electrochemical exfoliated graphene oxide nanosheets: pH influence,kinetics and equilibrium in aqueous solution

Graphene oxide nanosheets were synthesized by electrochemical exfoliation. X-ray diffraction, scanning electron microscopy, atomic force microscopy, Raman spectrometry and Fourier transform infrared spectrometry were used to characterize crystal structure, particle size, thickness and function groups of the nanosheets. The nanosheets were examined for adsorption of methyl orange, an anionic dye, in aqueous solution at different pHs and temperatures. The maximum adsorption capacity of methyl orange on graphene oxide nanosheets obtained from the Langmuir isotherm was 138.69 mg/g at pH 2.0, which is larger than that of other carbonaceous adsorbents. The large adsorption affinity of graphene oxide nanosheets to methyl orange might be due to the presence of hydrogen bonding and π–π interaction between methyl orange and graphene oxide nanosheets. Adsorption kinetics followed a pseudo-second-order kinetic model, and the isotherm adsorption results were fitted with Langmuir isotherm model in a monolayer adsorption manner. The thermodynamic studies indicated that the adsorption reaction was a spontaneous physisorption process.     

Temporal and Spatial Distribution of the Late Devonian (Famennian) Strata in the Northwestern Border of the Junggar Basin, Xinjiang, Northwestern China

The base of the Saerba Member (Mbr) of the Hongguleleng Formation (Fm.) probably lies in the Famennian Palmatolepis crepida Zone; the Longkou Mbr is probably a sedimentary wedge that thins out northwards; the Duguer Mbr has an approximate age from the upper part of the Pa. marginifera Zone or the Lower Pa. rugosa trachytera Zone through the top of the Pa. perlobata postera Zone; the Wulan Mbr has an age approximately corresponding to the whole Pa. gracilis expansa Zone. In the Bulongguoer section, the Lower Mbr of the Hongguleleng Fm. corresponds to Famennian Pa. crepida Zone through Pa. marginifera Zone; the Middle Mbr probably ranges from the Pa. r. trachytera Zone through the Pa. g. expansa Zone. The basal Namu Mbr of the Heishantou Fm. is probably the product during and after the Hangenberg Event in the upper part of the Siphonodella praesulcata Zone, which is still within the Devonian. In this context, the underlying Chasi Mbr may approximately correspond to the lower part of the S. praesulcata Zone (before the Hangenberg Event). Lateral distribution of strata indicates that the Upper Devonian in the Gennaren and Saerba areas each constitutes a structure of syncline, which differs from the previous recognition of a monocline structure.     

Accumulation and speciation of selenium in evaporation basins in California,USA

The accumulation of selenium in evaporation basins (or ponds) in the San Joaquin Valley, California is of a great concern due to its potential hazards to environments. In this study, the accumulation, speciation and concentrations of Se were examined in waters as well as sediments in a system of the evaporation ponds. A significant decrease in the total dissolved Se concentration in Cell 1 in which drainage water with higher Se concentration was pumped from Inlet Channels indicated that the immobilization of Se was active in the Cell 1 and resulted in the higher Se concentration in sediments compared to the terminal cell such as Cell 9. The percentage of reduced Se species such as selenite [Se(IV)] and org-Se of total Se in drainage waters was also found increased in Cell 1 compared to Inlet Channels. The total dissolved Se concentrations in water along flow paths from Cell 1 were relatively constant except for terminal cells such as Cells 9 and 10, which showed higher total dissolved Se concentrations due to evapoconcentration. The percentage of reduced Se forms of total Se was inversely proportional to the percentage of Se(VI) depending on the redox condition of evaporation ponds along the flow paths. Sequential extractions of Se species in sediments indicated that organic associated Se and elemental Se were prevalent forms in sediments in the ponds system. The higher concentrations of elemental Se and organic associated Se in sediments in Cell 1 indicated that the immobilization of Se was active in the sediments compared to Cell 9, while the percentage of both fractions of total Se in sediments in Cells 1 and 9 was relatively constant. The organic materials from algae might provide carbon sources for Se reduction and Se sink in sediments in its elemental and organic associated forms.     

南水北调西四环暗涵工程穿越桥梁监控量测技术应用

南水北调西四环暗涵工程为京石段控制性工程,下穿北京市西四环路桥梁30余座,桥梁的安全至关重要。在暗涵施工过程中对桥梁实施了有效的监控量测技术,通过自动化监测和常规监测手段获取数据,然后对监测数据进行详细分析、对比,以研究暗涵下穿桥梁施工过程中桥梁的受力变形协调过程。结果表明:墩柱差异沉降小于允许沉降的80%;墩柱倾斜值小于允许值的30%。监控工作做到了过程预警、过程控制,规避了工程风险,对类似工程具有借鉴意义。     

Variations of Hydrodynamics and Submarine Groundwater Discharge in the Yellow River Estuary Under the Influence of the Water-Sediment Regulation Scheme

The “Water-Sediment Regulation Scheme” (WSRS) is critically important to the hydrologic evaluation of the Yellow River estuary since a huge pulse of water and sediment are delivered into the sea during a short period. We used the natural geochemical tracers radium (²²³Ra, ²²⁴Ra, ²²⁶Ra) and radon (²²²Rn) isotopes as well as other hydrological parameters to investigate the mixing variations and submarine groundwater discharge (SGD) in the Yellow River estuary under the influence of the 2013 WSRS. Dramatically elevated radium and radon isotopic activities were observed during this WSRS compared with activities measured during a non-WSRS period. Radium “water ages” indicated that the offshore transport rate nearly tripled when the river discharge increased from 400 to 3400 m³/s. We calculated the SGD flux in the Yellow River estuary based on a radium mass balance model as well as radium and radon time-series models. The SGD flux was estimated at 0.02~0.20 m/day during a non-WSRS period and 0.67~1.22 m/day during the 2013 WSRS period. The results also indicate that large river discharge tends to lead more intense SGD along the river channel direction with a large amount of fresh SGD.     

Effects of size and strain rate on the mechanical behaviors of rock specimens under uniaxial compression

Size and strain rate are two key factors that dramatically influence the estimation of rock mechanical behaviors. To better understand the effects of size and strain rate on measured rocks, rock specimens with six different sizes were tested at six different strain rates under uniaxial compression using the MTS 815 Rock Mechanics Test System. Having determined that the size and strain rate significantly affect the peak strain, peak stress, elastic modulus, acoustic emission (AE), and failure pattern of the rock specimens, the relation was established between the strength and the size and strain rate of red sandstone. And the variation was revealed among the size and strain rate, the AE, and the failure pattern. It turned out that the peak stress was negatively correlated with the rock size and was positively correlated with the strain rate. When the length to diameter ratio (L/D) of the rock specimen was less than 2.0, the AE appeared mildly. The AE quantities gradually increased before the peak stress, and then sharply decreased after the peak stress. The failure pattern of the rock specimen was relatively complicated, with a fracture plane appearing along the axial direction. Conical failure type was also presented. When the L/D ratio of the specimen was greater than 2.0, the AE characteristics of red sandstone showed the radical model. There were relatively few AE rings before the peak stress. But the AE rings increased suddenly and dramatically during the peak stress. The rock specimens primarily failed with a single shear plane. Moreover, with an increase in the strain rate, the AE activities were enhanced and the AE quantities increased. When the strain rate of the rock specimen was less than 5.0?×?10^?4/s, the rock specimen failed with a shear or tensile-shear pattern. And when the strain rate was greater than 5.0?×?10^?4/s, the rock specimen tended to fail in a conical pattern.     

盐湖相低熟油脂肪酸的组成与分布特征

对泌阳凹陷碱性盐湖相、舞阳凹陷盐湖相、襄城凹陷膏盐湖相、南阳凹陷淡水湖相低熟油脂肪酸组成和分布特征进行了分析与研究。结果表明这些不同盐湖相的低熟原油的脂肪酸为丰度不同的饱和正构酸、不饱和正构酸、少量异构酸、类异戊二烯酸及脂肪酸乙酯系列化合物。脂肪酸的组成和分布反映了原始有机质的来源。     

Screening Effect of the Diffusive Boundary Layer in Sediments of Lake Aha in the Suburbs of Guiyang City,Guizhou Province

The redox cycle of iron and manganese is a major geochemica process at the boundary layers of lake sediments.Lake Aha,which lies in the suburbs of Guiyang City,Guizhou Province,China,is a medium-sized artificial reservoir with seasonally anoxic hypolimnion,Long-term sedimentary accumulation of iron and manganese resulted in their enrichment in the upper sediments,In the anoxic season,Fe^2 and Mn^2 ,formed by diological oxidation,would diffuse up to overlying waters from sediments.However,the concentration of oxidation,would diffuse up to overlying waters from sediments,However,the concentration of Fe^2 increased later and decreased earlier than that of Mn^2 .Generally,sulfate reduction occurred at 6 cm below the sediment-water interface.Whereas,in the anoxic season.the reduction reached upper sediments,inhibiting the release of Fe^2 ,The Fe concentration of anoxic water is quickly decreased from high to low as a result of reduction of the suplhur system.