Variations of Hydrodynamics and Submarine Groundwater Discharge in the Yellow River Estuary Under the Influence of the Water-Sediment Regulation Scheme

The “Water-Sediment Regulation Scheme” (WSRS) is critically important to the hydrologic evaluation of the Yellow River estuary since a huge pulse of water and sediment are delivered into the sea during a short period. We used the natural geochemical tracers radium (²²³Ra, ²²⁴Ra, ²²⁶Ra) and radon (²²²Rn) isotopes as well as other hydrological parameters to investigate the mixing variations and submarine groundwater discharge (SGD) in the Yellow River estuary under the influence of the 2013 WSRS. Dramatically elevated radium and radon isotopic activities were observed during this WSRS compared with activities measured during a non-WSRS period. Radium “water ages” indicated that the offshore transport rate nearly tripled when the river discharge increased from 400 to 3400 m³/s. We calculated the SGD flux in the Yellow River estuary based on a radium mass balance model as well as radium and radon time-series models. The SGD flux was estimated at 0.02~0.20 m/day during a non-WSRS period and 0.67~1.22 m/day during the 2013 WSRS period. The results also indicate that large river discharge tends to lead more intense SGD along the river channel direction with a large amount of fresh SGD.     

Calculation method for thickness of discontinuous boundary layer of engineering pavement

The boundary layer is a buffer layer of water and heat exchange between the atmosphere and permafrost.Based on the atmospheric boundary layer and heat transfer theory,we established a method for determining the boundary layer thickness of engineering pavement(asphalt and sand pavement)in permafrost region.The boundary layer can be divided into the Boundary Layer Above Surface(BLAS)and the Boundary Layer Below Surface(BLBS).From in-situ monitoring data,the thickness of BLAS was determined through the laminar thickness,and the thickness of BLBS was determined through ground temperature,the heat conduction function,and the mean attenuation function(α).For asphalt pavement,the BLAS thickness varied between 2.90 and 4.31 mm and that of BLBS varied between 28.00 and 45.38 cm.For sand pavement,the BLAS thickness varied between 2.55 and 3.29 mm and that of BLBS varied between 15.00 and 46.44 cm.The thickness varied with freezing and thawing processes.The boundary layer calculation method described in this paper can provide a relatively stable boundary for temperature field analysis.     

Spatiotemporal distribution and historical evolution of polders in the Dongting Lake area,China

Dongting Lake is the largest lake in the middle reaches of the Yangtze River in China. For centuries, people inhabiting the Dongting Lake area have been reclaiming land and constructing dams for flood resistance, agricultural production, and rural settlement, forming geographical entities known as polders. In this study, the regional spatial distributions of polders in the Dongting Lake area in 1949, 1998, and 2013 were obtained using historical maps and modern remotely sensed data, revealing changes since the establishment of the People’s Republic of China. Nanxian County was then selected to demonstrate polder changes at the county level, because it has undergone the most dramatic changes in the area. Different polder change models for the Datonghu, Yule, and Renhe polders were analyzed for eight periods: 1644 (the early Qing Dynasty), 1911 (the late Qing Dynasty), 1930 (the Republic of China), 1949 (the People’s Republic of China), 1963, 1970, 1998, and 2013. Three resulting polder evolution models are: 1) reclaiming polders from lakes, 2) integrating polders by stream merging, and 3) abandoning polders for flood release. The polder evolution models demonstrate the wisdom of local people in using land resources according to the specific regional conditions. Throughout their long-term historical evolution, the spatial distribution of polders in the Dongting Lake area tended to be homogeneous, and the degree of human disturbance tended to be stable. However, a shift occurred, from pure polder area growth or removal to more comprehensive management and protection of the regional environment.     

Curvedness feature constrained map matching for low-frequency probe vehicle data

Map matching method is a fundamental preprocessing technique for massive probe vehicle data. Various transportation applications need map matching methods to provide highly accurate and stable results. However, most current map matching approaches employ elementary geometric or topological measures, which may not be sufficient to encode the characteristic of realistic driving paths, leading to inefficiency and inaccuracy, especially in complex road networks. To address these issues, this article presents a novel map matching method, based on the measure of curvedness of Global Positioning System (GPS) trajectories. The curvature integral, which measures the curvedness feature of GPS trajectories, is considered to be one of the major matching characteristics that constrain pairwise matching between the two adjacent GPS track points. In this article, we propose the definition of the curvature integral in the context of map matching, and develop a novel accurate map matching algorithm based on the curvedness feature. Using real-world probe vehicles data, we show that the curvedness feature (CURF) constrained map matching method outperforms two classical methods for accuracy and stability under complicated road environments.     

Altitudinal trends in δ<Superscript>13</Superscript>C value,stomatal density and nitrogen content of <Emphasis Type="Italic">Pinus tabuliformis</Emphasis> needles on the southern slope of the middle Qinling Mountains,China

In this study, a coniferous tree species (Pinus tabuliformis Carr.) was investigated at a moderate-altitude mountainous terrain on the southern slope of the middle Qinling Mountains (QLM) to detect the trends in carbon isotope ratio (δ¹³C), leaf nitrogen content (LNC) and stomatal density (SD) with altitude variation in north-subtropical humid mountain climate zone of China. The results showed that LNC and SD both significantly increased linearly along the altitudinal gradient ranging from 1000 to 2200 m, whereas leaf δ¹³C exhibited a significantly negative correlation with the altitude. Such a correlation pattern differs obviously from that obtained in offshore low-altitude humid environment or inland high-altitude semi-arid environment, suggesting that the pattern of increasing δ¹³C with the altitude cannot be generalized. The negative correlation between δ¹³C and altitude might be attributed mainly to the strengthening of carbon isotope fractionation in plants caused by increasing precipitation with altitude. Furthermore, there was a remarkable negative correlation between leaf δ¹³C and LNC. One possible reason was that increasing precipitation that operates to increase isotopic discrimination with altitude overtook the LNC in determining the sign of leaf δ¹³C. The significant negative correlation between leaf δ¹³C and SD over altitudes was also found in the present study, indicating that increases in SD with altitude would reduce, rather than enhance plant δ¹³C values.     

Antialgal and antilarval activities of bioactive compounds extracted from the marine dinoflagellate <Emphasis Type="Italic">Amphidinium carterae</Emphasis>

With the global ban on the application of organotin-based marine coatings by the International Maritime Organization, the development of environmentally friendly, low-toxic and nontoxic antifouling compounds for marine industries has become an urgent need. Marine microorganisms have been considered as a potential source of natural antifoulants. In this study, the antifouling potential of marine dinoflagellate Amphidinium carterae, the toxic and red-tide microalgae, was investigated. We performed a series of operations to extract the bioactive substances from Amphidinium carterae and tested their antialgal and antilarval activities. The crude extract of Amphidinium carterae showed significant antialgal activity and the EC₅₀ value against Skeletonema costatum was 55.4 μg mL^?1. After purification, the isolated bioactive substances (the organic extract C) exhibited much higher antialgal and antilarval activities with EC₅₀ of 12.9 μg mL^?1 against Skeletonema costatum and LC₅₀ of 15.1 μg mL^?1 against Amphibalanus amphitrite larvae. Subsequently, IR, Q-TOFMS, and GC-MS were utilized for the structural elucidation of the bioactive compounds, and a series of unsaturated and saturated 16- to 22-carbon fatty acids were detected. The data suggested the bioactive compounds isolated from Amphidinium carterae exhibited a significant inhibiting effect against the diatom Skeletonema costatum and Amphibalanus amphitrite larvae, and could be substitutes for persistent, toxic antifouling compounds.     

The modeled atmospheric and oceanic response to the South China Sea SST anomaly

The sensitivity of the global atmospheric and oceanic response to sea surface temperature anomaly (SSTA) throughout the South China Sea (SCS) is investigated using the Fast Ocean-Atmosphere Model (FOAM). Forced by a warming SST, the experiment explicitly demonstrates that the responses of surface air temperature (SAT) and SST exhibit positive anomalous center over SCS and negative anomalous center over the Northern Pacific Ocean (NPO). The atmospheric response to the warm SST anomalies is characterized by a barotropical anomaly in middle-latitude, leading to a weak subtropical high in summer and a weak Aleutian low in winter. Accordingly, Indian monsoon and eastern Asian monsoon strengthen in summer but weaken in winter as a result of wind convergence owing to the warm SST. It is worth noting that the abnormal signals propagate poleward and eastward away in the form of Rossby Waves from the forcing region, which induces high pressure anomaly. Owing to action of the wind-driven circulation, an anomalous anti-cyclonic circulation is induced with a primary southward current in the upper ocean. An obvious cooling appears over the North Pacific, which can be explained by anomalous meridional cold advection and mixing as shown in the analysises of heat budget and other factors that affect SST.     

An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.