Predicting the dependency of a degree of saturation on void ratio and suction using effective stress principle for unsaturated soils

The paper presents an approach to predicting variation of a degree of saturation in unsaturated soils with void ratio and suction. The approach is based on the effective stress principle for unsaturated soils and several underlying assumptions. It focuses on the main drying and wetting processes and does not incorporate the effects of hydraulic hysteresis. It leads to the dependency of water retention curve (WRC) on void ratio, which does not require any material parameters apart from the parameters specifying WRC for the reference void ratio. Its validity is demonstrated by comparing predictions with the experimental data on four different soils taken over from the literature. Good correlation between the measured and predicted behaviour indirectly supports applicability of the effective stress principle for unsaturated soils. Copyright © 2009 John Wiley & Sons, Ltd.     

A new Late Holocene sea-level record from the Mississippi Delta: evidence for a climate/sea level connection?

A detailed relative sea-level (RSL) record was constructed for the time interval 600–1600 AD, using basal peat to track sea level and containing 16 sea-level index points that capture ～60 cm of RSL rise. The study area is in the Mississippi Delta where the spring tidal range is ～0.47 m, the impact of ocean currents on sea-surface topography is limited, and crustal motions are well constrained. Age control was obtained by AMS ¹⁴C dating and most ages represent weighted means of two subsamples. Sample elevations were determined by combining differential GPS measurements with optical surveying. All index points were plotted as error boxes using 2σ confidence intervals for the ages, plus all vertical errors involved in sampling and surveying, as well as the indicative range of the samples. A striking clustering of sea-level index points between ～1000 and ～1200 AD suggests a possible acceleration in the rate of RSL rise. Removal of the long-term trend (0.60 mm yr^?1) allows for the possibility of a sea-level oscillation with a maximum amplitude of ～55 cm. However, given the size of the error boxes the possibility that oscillations did not occur cannot be entirely ruled out. Comparison of the new RSL record with various proxy climate records suggests that sea level in this area may have responded to hemispheric temperature changes, including the Medieval Warm Period and the Little Ice Age. However, given the error margins associated with this reconstruction, it is stressed that this causal mechanism is tentative and requires corroboration by high-resolution sea-level reconstructions elsewhere.     

Some Insights into Topographic,Elastic and Self-gravitation Interaction in Modelling Ground Deformation and Gravity Changes in Active Volcanic Areas

Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic, elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation and gravity changes depend on such effects.     

The GTC: An Advanced 10m Telescope for the ORM

The Gran Telescopio CANARIAS (GTC) is a high performance 10-m class telescope whose construction has been promoted by the IAC (Instituto de Astrofísica de Canarias). It will be installed at the Roque de los Muchachos Observatory (ORM), in the island of La Palma. First light is planned for end-2002. The key science drivers for the project are image quality, operational efficiency and reliability, as emphasized in the Conceptual Design Document which was finished in mid-97. The Preliminary Design is now proceeding on all aspects of the project. The GTC Project is presently funded at the 70% level by Spain. The scientific drives behind the GTC project are described here, as well as the current technical, managerial, and operational baseline. This revised version was published online in July 2006 with corrections to the Cover Date.     

Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.     

Equivalent-linear site response analysis on the site of the historical Trakošćan Castle,Croatia, using HVSR method

This paper presents a major extension of seismic vulnerability research project on the site of Trako??an Castle based on the initial horizontal-to-vertical-spectral-ratio (HVSR) results from Stanko et al. (2016). The estimated HVSR site frequencies and HV amplification at Trako??an Castle can only be used as an indication of the initial soil site frequency and amplification, so-called natural soil model, corresponding to the subsoil profile without the influence of an earthquake. The equivalent-linear (EQL) site response analysis has been carried out for different earthquake scenarios for a maximum input rock peak ground acceleration (PGA_ROCK) that corresponds to return periods of 95 (0.08 g), 475 (0.18 g) and 1000 years (0.31 g). The aim of the research is to evaluate structural seismic design responses and to determine type and degree of damage caused by local site effect, which is the result of an alluvial basin and topographic influences. The main objective of this research is the formation of local microseismic zones based on an EQL analysis: surface spectral acceleration and amplification maps at the predominant frequency. Based on the HVSR frequency response of the core structure of Trako??an Castle and the Tower itself (fundamental and higher frequency modes), maps of surface spectral acceleration and soil amplification at different frequencies (3, 5 and 10 Hz) are developed for different input PGA_ROCK levels (0.08, 0.18 and 0.31 g) to evaluate seismic response of the Castle. Observed amplifications are correlated with ground motion polarization and directionality of the ground motion from the alluvial basin to the hilltop. Shortening of predominant frequencies (lengthening of the period), particularly in the alluvial basin, has been observed with higher input PGA_ROCK in the EQL analysis. This effect is not manifested in the Trako??an hill, and predominant frequencies match HVSR frequencies. The use of certain geophysical survey methods at historical sites is a big problem, because terrain features (e.g. steep hills, mountains, ridges, slopes, cliffs) create lack of space and make it impossible to carry out geophysical investigation. Microtremor measurements at historical sites can overcome this limitation and provide local seismic response and vulnerability behaviour of historical monuments without destroying their authenticity. Also, computational modelling can greatly improve the results. The EQL site response analysis on the site of Trako??an Castle has confirmed and improved the results of seismic response and vulnerability based on HVSR method.     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.     

Anthropogenic subsidence in the Mexicali Valley,Baja California,Mexico, and slip on the Saltillo fault

Deep fluid extraction in the Cerro Prieto geothermal field (CPGF) has caused subsidence and induced slip on tectonic faults in the Mexicali Valley (Baja California, Mexico). The Mexicali Valley is located in the southern part of the Salton Trough, at the boundary between the Pacific and North American plates. The Valley is characterized by being a zone of continuous tectonic deformation, geothermal activity, and seismicity. Within the Cerro Prieto pull-apart basin, seismicity is concentrated mainly in swarms, while strong earthquakes have occurred in the Imperial and Cerro Prieto transform faults, that are the eastern and western bound of the basin. Since 1973, fluid extraction at the CPGF has influenced deformation in the area, accelerating the subsidence and causing rupture (frequently as vertical slip or creep) on the surface traces of tectonic faults. Both subsidence and fault slip are causing damage to infrastructure like roads, railroad tracks, irrigation channels, and agricultural fields. Currently, accelerated extraction in the eastern part of CPGF has shifted eastwards the area of most pronounced subsidence rate; this accelerated subsidence can be observed at the Saltillo fault, a southern branch of the Imperial fault in the Mexicali Valley. Published leveling data, together with field data from geological surveys, geotechnical instruments, and new InSAR images were used to model the observed deformation in the area in terms of fluid extraction. Since the electricity production in the CPGF is an indispensable part of Baja California economy, extraction is sure to continue and may probably increase, so that the problem of damages caused by subsidence will likely increase in the future.     

Geochemical and structural evolution of micas in the Rožná and Dobrá Voda pegmatites,Czech Republic

Summary The chemistry, structural parameters, polytypism, optical properties and Rb-Sr isotopes were examined in 11 to 60 samples of biotite, muscovite and lepidolite from the pegmatites at Roná (the type locality of lepidolite; 323 ± 4Ma) and Dobrá Voda (306 ± 9Ma) in western Moravia. At both localities, early endocontact biotite is followed inwards by muscovite and lepidolite, which is concentrated in and around the core. At Roná, a 1M lepidolite follows after 2M₁ muscovite but all later generations of lepidolite are 2M₂, close to Tri₅₀ Ply₅₀ and in part associated with muscovite 2M₁. At Dobrá Voda, all lepidolite types are 1M and free of muscovite, and the late varieties approximate Tri₃₀ Ply₇₀. At both localities, a trend of increasing HF is indicated during the progress of mica crystallization, culminating in precipitation of topaz. Polytypism of lepidolite is not correlatable with any compositional or growth feature, or their combination. Throughout the mica crystallization, Rb/Cs decreases but K/Rb becomes reversed after an initial decrease. Boron is partitioned preferentially into muscovite (up to 1.10 wt.% B₂O₃) but Be, Zn, Mn and Sc are enhanced in lepidolite. A slight increase in Fe, Ba and Cl in the last generation of lepidolite might be possibly due to mixing of residual pegmatite fluids with metamorphic pore solutions.

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Geochemische und strukturelle Entwicklung der Glimmer in den Pegmatiten von Roná und Dobrá Voda, Tschechische Republik

Zusammenfassung In 11 bis 60 Proben von Biotit, Muskovit und Lepidolith aus den Pegmatiten von Roná (Typlokalität des Lepidoliths; 323 ± 9 Ma) in Westmähren wurden Chemie, Struktur-parameter, Polytypie, optische Eigenschaften und Rb-Sr-Isotopie untersucht. An beiden Lokalitäten wird früher Biotit an Endokontakten nach Innen von Muskovit und Lepidolith gefolgt, letzterer ist in und um den Kern konzentriert. In Roná folgt 1M-Lepidolith auf 2M₁-Muskovit, aber alle späteren Lepidolithgenerationen sind 2M₂, nahe Tri₅₀Ply₅₀ und zum Teil mit 2M₁-Muskovit vergesellschaftet. In Dobrá Voda sind alle Lepidolithe vom Typ 1M und frei von Muskovit, die späten Varietäten kommen Tri₅₀Ply₅₀ nahe. An beiden Lokalitäten ist während des Fortschreitens der Glimmerkristallisation eine Tendenz von steigendem HF angezeigt, die in der Ausfällung von Topas ihren Höhepunkt findet. Die Polytypie des Lepidoliths kann nicht mit irgendeiner Eigenheit der Zusammensetzung oder des Wachstums korreliert worden, auch nicht mit einer Kombination von diesen. Während der ganzen Glimmerkristallisation nimmt Rb/Cs ab, aber die Tendenz von K/Rb ändert sich nach anfänglichem Abfall. Das Bor verteilt sich bevorzugt auf den Muskovit (bis zu 1.10 Gew. -% B₂O₃), aber die Be-, Zn-, Mn- und Sc-Gehalte sind im Lepidolith erhöht. Ein leichter Ansteig von Fe, Ba und Cl in der letzten Lepidolithgeneration könnte vielleicht durch eine Mischung von pegmatitischen Restlösungen mit metamorphen Porenlösungen verursacht sein.

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With 9 Figures     

Ag-rich Tetrahedrite in the El Zancudo Deposit,Colombia: Occurrence,Chemical Compositions and Genetic Temperatures

Chemical compositions of tetrahedrite—Ag-rich tetrahedrite—freibergite solid solutions (Ag-rich tetrahedrite_ss) and homogenization temperatures of fluid inclusions in quartz and carbonates of seventeen samples from nine veins in the El Zancudo deposit, Antioquia, Colombia, were investigated to reveal the origin of silver in Ag-rich tetrahedrite_ss, to derive their crystallization temperatures and to examine the relationship between chemical compositions of Ag-rich tetrahedrite_ss and their crystallization temperatures. The ores consist of arsenopyrite, pyrite, sphalerite, Ag-rich tetrahedrite_ss, galena, boulangerite, andorite, owyheeite, diaphorite, jamesonite, miargyrite, bournonite, chalcopyrite, and electrum. Ag-rich tetrahedrite_ss forms about 10 volume % of the total ores and is one of the most common and widely distributed sulfosalts in this deposit. Ag-rich tetrahedrite_ss is rich in Ag (1.13 to 31.02 wt%) and Sb (22.93 to 29.82 wt%), and poor in As (0.06 to 2.43 wt%), consistent with the reported incompatibilities of Ag and As in Ag-rich tetrahedrite_ss. The Zn/(Zn + Fe)-, Ag/(Ag + Cu)- and Sb/(Sb + As + Bi)-atomic ratios exhibit some variations among the veins. Ag-rich tetrahedrite_ss with higher Ag/(Ag + Cu) ratios coexist with diaphorite, whereas those with lower ratios are not associated with this sulfosalt. Ag-rich tetrahedrite_ss in the assemblages of Ag-rich tetrahedrite_ss+ sphalerite and of Ag-rich tetrahedrite_ss+ bournonite + galena shows no Zn ↔ Fe and Cu ↔ Ag variations between core and rim, respectively, negating the possibility of solid state reaction during cooling. Ag-rich tetrahedrite_ss is thus regarded as primary phase. Homogenization temperatures of primary fluid inclusions in quartz and carbonates co-existing with Ag-rich tetrahedrite_ss define the mineralization temperatures of 134 to 263°C. Independent crystallization temperatures of Ag-rich tetrahedrite estimated based on Zn/(Zn + Fe) and Ag/(Ag + Cu) ratios of the Ag-rich tetrahedrite_ss associated with silver minerals such as miargyrite, andorite and diaphorite using Sack's thermochemical database lie in a range between 170 and ∼250°C. Both results are thus in good agreement.