Observations of NO2 and O3 during thunderstorm activity using visible spectroscopy

Simultaneous observations for the total column densities of NO2, O3 and H2O were carried on using the porta-ble Spectrometer (438-450 nm and 400-450 nm) and the visible Spectrometer (544.4-628 nm) during premonsoon thunderstorms and embedded hail storm activity at Pune (18o32’N & 73o51’E), India. These observations confirm the fact that there is an increase in O3 and NO2 column densities during thunderstorms. The increase in O3 was observed following onset of thunderstorm, while the increase in NO2 was observed only after the thunder flashes occur. This implies that the production mechanisms for O3 and NO2 in thunderstorm are different. The observed column density of NO2 value (1 to 3 × 1017molecules · cm-2) during thunderstorm activity is 10 to 30 times higher than the value (1 × 1016molecules · cm-2) of a normal day total column density. The spectrometric observations and observations of thunder flashes by electric field meter showed that 6.4 × 1025molecules / flash of NO2 are produced. The increased to-tal column density of ozone during thunderstorm period is 1.2 times higher than normal (clear) day ozone concentra-tion. The multiple scattering in the clouds is estimated from H2O and O2 absorption bands in the visible spectral re-gion. Considering this effect the calculated amount of ozone added in the global atmosphere due to thunderstorm ac-tivity is 0.26 to 0.52 DU, and the annual production of ozone due to thunderstorm activity is of the order of 4.02 × 1037 molecules /year. The annual NO2 production may be of the order of 2.02 × 1035molecules / year.     

The role of fluid inclusions in mineral exploration—An attempt on the Bihar Mica Belt of India

Fluid inclusions and melt inclusions have been considered as possible guides for mineral exploration by many researchers. However, the minuteness of the fluid inclusions and the multiplicity of generations within the same deposit have always posed serious problems in the proper utilization of fluid-inclusion data in prospecting.Fluid inclusions preserve a valid and comprehensive record of the fluids coexisting with host minerals at the time of crystallization. A careful comparison of fluid-inclusion parameters and deposit characteristics enables one to distinguish between economically significant and insignificant zones of pegmatites.A systematic study of different pegmatites in an area of about 100 km² in the central part of the Bihar Mica Belt, India, was made. Mineralogical, fluid-inclusion, and melt-inclusion data of the principal mineral constituents like quartz, beryl, and apatite were collected. Thirty-three occurrences were chosen for the study. Pegmatites were grouped into economically significant (commercial) and barren (noncommercial) types. The fluid-inclusion parameters used in this study are size, population, presence of liquid carbon dioxide, salinity, and temperature of homogenization.Economically significant pegmatites and barren pegmatites have distinctly different populations of fluid inclusions. Economic pegmatites show a preponderance of highly saline, polyphase fluid inclusions, commonly with liquid carbon dioxide; these fluid inclusions homogenize over a wide range of temperature. Their size ranges from 50 m to 10 m. On the other hand, quartz of barren pegmatites is characterized by the preponderance of vapor-rich biphase inclusions, which homogenize at a relatively narrower but higher range of temperature. Fluid inclusions that contain halite daughter crystals are rare. The average size of the fluid inclusions in barren pegmatites is smaller (5 m to 20 m). Melt inclusions are more abundant in the barren pegmatites.     

Retrieval of chlorophyll from the sea-leaving radiance in the Arabian sea

Error estimates in chlorophyll retrieval in the sea from satellite data have always been higher compared to the errors in retrieval of sea surface temperature or wind speed from satellite data. This is due to the higher percentage of noise in optical signals compared to infrared or microwave signals reaching the satellite. The noise is introduced both at the sea surface itself and also while signal passes passage through atmosphere. In the present work, we have attempted to investigate the noise introduced at the sea surface. During the validation experiment of the optical sensor MOS-B onboard Indian Remote Sensing Satellite IRS-P3, simultaneous measurements of chlorophyll concentration and sea leaving radiance have been made along the satellite passes in the Arabian sea. The algorithms used in the present studies are not found to give satisfactory values of chlorophyll in about 30% of cases. The possible sources of errors in retrieving chlorophyll concentration have been discussed.     

Evaluation of hydrological effect of stakeholder prioritized climate change adaptation options based on multi-model regional climate projections

An integrated process involving participatory and modelling approaches for prioritizing and evaluating climate change adaptation options for the Kangsabati reservoir catchment is presented here. We assess the potential effects of climate change on water resources and evaluate the ability of stakeholder prioritized adaptation options to address adaptation requirements using the Water Evaluation And Planning (WEAP) model. Two adaptation options, check dams and increasing forest cover, are prioritized using pair-wise comparison and scenario analysis. Future streamflow projections are generated for the mid-21^st century period (2021–2050) using four high resolution (~25 km) Regional Climate Models and their ensemble mean for SRES A1B scenario. WEAP simulations indicate that, compared to a base scenario without adaptation, both adaptation options reduce streamflow. In comparison to check dams, increasing forest cover shows greater ability to address adaptation requirements as demonstrated by the temporal pattern and magnitude of streamflow reduction. Additionally, over the 30 year period, effectiveness of check dams in reducing streamflow decreases by up to 40 %, while that of forest cover increases by up to 47 %. Our study highlights the merits of a comparative assessment of adaptation options and we conclude that a combined approach involving stakeholders, scenario analysis, modelling techniques and multi-model projections may support climate change adaptation decision-making in the face of uncertainty.     

Petrogenesis of fractionated basaltic lava flows of Poladpur-Mahabaleshwar formation around Mahabaleshwar,Western Ghats,India

Geochemical investigations of Wai sub-group volcanic flows (in and around Mahabaleshwar) have been undertaken to determine the petrogenetic processes involved in the formation of volcanic flows. In comparison to the Ambenali Formation, Mahabaleshwar Formation flows were affected more by crustal materials, which left a signature consisting of enriched levels of K, Rb, Ba, Ti and P. Ratios of Nb/Zr and Ba/Y were sensitive to fractional crystallization; Mahabaleshwar formation flows showed the highest Nb/Zr ratios. Ba was noted as a boundary marker element between the Ambenali (47.3 to 63.9 ppm Ba) and Mahabaleshwar (83.1 to 180 ppm) formations. The general trend of incompatible element concentrations increasing from lower Poladpur to upper Mahabaleshwar flows with increasing Zr and the linear array on the plot are consistent with the fractionation of olivine and clinopyroxene. MgO ranged from 4.8 to 7.1 wt%, TiO₂ from 1.8 to 4.6 wt%, SiO₂ from 47 to 52 wt% and Al₂O₃ from 12 to15.5 wt%. The Mg number (Mg#) was much lower, ranging from 36 to 50. The K₂O/ P₂O₅ ratio showed the role of assimilation in the basaltic flows. TiO₂, Y, Zr, Nb and Mg# were used to determine fractional crystallization, whereas Ba, Rb, K₂O and SiO₂ were used for monitoring the fractional crystallization effects of crustal contamination. The range of Zr/Y and TiO₂ > 1.8 wt% appears to have been generated by fractional crystallization starting from enriched mafic precursors.     

Simultaneous measurements of ozone and its precursors on a diurnal scale at a semi urban site in India

Simultaneous observations of surface ozone (O₃) with its precursors namely, carbon monoxide (CO) and oxides of nitrogen (NO_x) have been taken on diurnal scale from a tropical semi-urban site, Pune (18.54°N, 73.81°E) in India. We present the data for one year (2003–2004) period to study the salient features of these trace gases. The peak in amplitude of ozone is found during the noontime whereas in CO and NO_X it is observed in the morning hours between 0800 and 0900 H. The concentration of these pollutants drop down considerably during southwest monsoon months and the diurnal pattern also become very weak. The diurnal trends of these gases are found to be different for different seasons, which are specific to the receptor site. Model simulations using 3-D chemical-transport model with regional emission inventories and observed winds have also been carried out. The comparison of model results with observations, on seasonal basis yielded a reasonable qualitative agreement. The relative role of local emissions and long range transport in the diurnal pattern for different seasons has been outlined, which reveals that the ozone is highly influenced by regional/long range transport in this region. The effect of precursor amounts in the morning on afternoon ozone peak levels has been investigated using the lag correlation study, which reveals that a time lag of 5–7 h is required for most of these precursor gases to photo-chemically produce ozone to its maximum potential. Results are discussed in the light of available topographic and meteorological conditions.     

Warming SST of Bay of Bengal and decrease in formation of cyclonic disturbances over the Indian region during southwest monsoon season

Low-pressure system (LPS), a major rain-bearing synoptic circulation, forming over the Indian region, including Bay of Bengal and Arabian Sea plays a vital role in performance of southwest monsoon over the country. The term LPS includes lows, depressions and cyclonic storms. According to the intensities, LPS are categorized into two, one only low-pressure areas (LPA) and the other more intense systems like depressions/storms (DDS). Statistical analysis reveals some significant results. Decadal analysis shows that there is a significant increase(decrease) in the frequency and duration of LPA(DDS) during the monsoon season for the recent decades. SST of Bay of Bengal also increased significantly during recent period. It is also observed that frequency and duration of LPA(DDS) show significant positive(negative) trend and sea surface temperature (SST) of the Bay of Bengal shows significant positive trend for the period after 1960. The total frequency of LPS has neither increased nor decreased significantly but the duration of LPS has significantly increased. This means, while the average total formation of the systems remains the same, the duration has increased. It seems that there are some atmospheric and oceanic conditions which are responsible for not allowing the intensification of lows into depressions. The frequency and duration of LPA(DDS) during the monsoon season are positively(negatively) correlated with SSTs of the Bay of Bengal during winter, pre-monsoon and monsoon season indicating warmer SST of the Bay of Bengal may not be favourable for intensifying lows into depressions.     

A fuzzy approach to classify physico-mechanical rock property with varying pH of the surrounding medium

The information on the soundness of rock is very important for enduring safety and stability of miming, marine and civil structures. The present paper mainly deals with a fuzzy approach to determine the effect of acidic watery environment on the rock strength of the sandstone rock sample. Fuzzy inference system developed here intelligently predicts the competency of the rock, based on experimental data used for the model development. The approach used would be able to predict the relative rock strength at any range of acidic to basic watery environment for any geotechnical investigation or application to achieve long-term durability.