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991.
YUAN Xuyin DENG Xu SHEN Zhiyong GAO Yun 《中国地球化学学报》2007,26(4):384-393
The species of Cu, Pb, Zn, Cd and Cr in sediments of the Taihu Lake, China, have been analyzed using the sequential chemical extraction method. Variations in the chemical fractions of these metals and their geographic distributions have also been studied. For all five metals, the residual fraction is highest but the exchangeable fraction is lowest among all the fractions. Compared to other metals, Cd has the highest percentage in the exchangeable fraction, and Cr is associated mainly with the residual fraction. Cu in the organic fraction and Pb in the Fe-Mn fraction are the important species, whereas the lowest percentages are found for Cd in the organic fraction, Cu in the Fe-Mn oxide fraction and Pb in the carbonate fraction. With respect to spatial differences, the total contents in the non-residual fractions of the metals in bay sediments are found to be higher than those in other sediments. The fractions of Cd, Cu and Cr showed significant variations in different regions. The fractions of Pb and Zn, however, did not show significant variations in spatial distribution, suggesting different amounts and different paths of anthropogenic input for the metals. Comparisons of the metal speciation indicated that Cd might be the most bioavailable metal, followed by Pb. 相似文献
992.
We measured the amount of arsenic, chromium, copper, lead, nickel, vanadium, and zinc accumulated over a five-year period
from 1997 to 2002 in surface sediments of seven salt marshes along the New Brunswick coast of the Bay of Fundy, Canada. Study
sites extended from outer to inner Bay, spanning a gradient in tidal range (6–12 m) and mean sediment deposition rate (0.27–1.76
cm yr−1). In each study site, metal concentrations were measured in low and high marsh areas. Concentrations of chromium, nickel,
and zinc appear to be within their natural range, while arsenic, lead, and vanadium are enriched in some sites. Calculated
sediment metal loadings rates showed variability among marsh sites that closely followed sediment deposition patterns, suggesting
sediment deposition rate is the driving factor of short-term metal accumulation in Fundy marshes. The value of salt marshes
as a sink for metals may be enhanced by high sedimentation rates. 相似文献
993.
Vulnerability assessment in a volcanic risk evaluation in Central Mexico through a multi-criteria-GIS approach 总被引:1,自引:1,他引:1
José Fernando Aceves-Quesada Jesús Díaz-Salgado Jorge López-Blanco 《Natural Hazards》2007,40(2):339-356
The Valley of Toluca is a major industrial and agricultural area in Central Mexico, especially the City of Toluca, the capital
of The State of Mexico. The Nevado de Toluca volcano is located to the southwest of The Toluca Basin. Results obtained from
the vulnerability assessment phase of the study area (5,040 km2 and 42 municipalities) are presented here as a part of a comprehensive volcanic risk assessment of The Toluca Basin. Information
has been gathered and processed at a municipal level including thematic maps at 1:250,000 scale. A database has been built,
classified and analyzed within a GIS environment; additionally, a Multi-Criteria Evaluation (MCE) approach was applied as
an aid for the decision-making process. Cartographic results were five vulnerability maps: (1) Total Population, (2) Land
Use/Cover, (3) Infrastructure, (4) Economic Units and (5) Total Vulnerability. Our main results suggest that the Toluca and
Tianguistenco urban and industrial areas, to the north and northeast of The Valley of Toluca, are the most vulnerable areas,
for their high concentration of population, infrastructure, economic activity, and exposure to volcanic events. 相似文献
994.
I. González M. M. Jordán T. Sanfeliu M. Quiroz C. de la Fuente 《Environmental Geology》2007,52(7):1243-1251
In southern Chile, with a mild and rainy climate, high levels of heavy metals have been detected in many gold placer deposits.
Many of the contaminants pose risks to human life, and consequently damage the trofic chain in this environment. The study
zones selected correspond to the handicraft gold-bearing sands of Rio Gato (Los Muermos), Carelmapu and Cucao. These are all
located in the X Region of “Los Lagos” in Chile. The type of methodology used in the characterization of the associated mineralization
consists of testing each representative sample with a grain size distribution, statistical parameter analysis and a mineralogical
analysis, using a binocular magnifying glass, a petrographic microscope, XRD and SEM/EDX. The chemical composition was defined
by means of X ray fluorescence and micro-chemical analysis. The results of the study about sediments in southern Chile are
presented. The major concentrations of heavy minerals are generally located in areas of dynamic river energy. In the samples,
more than 70% of the heavy minerals were distributed among grain sizes corresponding to thin sand with good grain selection
(meshes of 0.25–0.06 mm). The main mineral phases present in the analysed samples were gold, zircon, olivine, ilmenite, hornblende,
hypersthene, hematite, garnet, chromite, chlorite, augite, amphibolitic-epidote, etc. The main heavy metals found as a result
of the study were mercury, lead, cadmium, chrome, tellurium, indium, zinc, cobalt, copper, platinum, gold, etc., and as well
some less common elements like cerium, praseodymium, gadolinium, neodymium, samarium and lanthanum. This research work is
only a starting point for carrying out a risk probability mapping of heavy metals and the mineralogy of the Cucao, Carelmapu
and Rio Gato gold-bearing sands. 相似文献
995.
Isabelle Letard Philippe Sainctavit Catherine Deudon 《Physics and Chemistry of Minerals》2007,34(2):113-120
Pyrrhotite (Fe7S8) is a natural iron sulphide that can participate in rock magnetisation. Its electronic structure is not yet surely described.
X-ray magnetic circular dichroism (XMCD) at Fe L2,3 edges on Fe7S8, coupled with multiplet calculations, shows that iron is present only as Fe2+ in this magnetic iron sulphide. It reveals a strong magnetic orbital moment. XMCD at Fe and S K edges shows the quite strong
polarization of both Fe and S in Fe7S8. 相似文献
996.
Syntectonic plutons emplaced in shallow crust often contain intermediate-to low-temperature deformation microstructures but
lack a high-temperature, subsolidus deformation fabric, although the relict magmatic fabric is preserved. The Proterozoic
Vellaturu granite emplaced at the eastern margin of the northern Nallamalai fold belt, south India during the late phase of
regional deformation has a common occurrence of intermediate-to low-temperature deformation fabric, superimposed over magmatic
fabric with an internally complex pattern. But high-T subsolidus deformation microstructure and fabric are absent in this
pluton. The main crystal plastic deformation and fluid enhanced reaction softening was concentrated along the margin of the
granite body. Resulting granite mylonites show Y-maximum c-axis fabric in completely recrystallized quartz ribbonds, dynamic recrystallization of perthites, and myrmekite indicative
of fabric development under intermediate temperature (∼ 500–400°C). The weakly-deformed interior shows myrmekite, feldspar
microfracturing and limited bulging recrystallization of quartz. The abundance of prism subgrain boundaries is indicative
of continuing deformation through low-temperature (∼ 300°C). The relative rates of cooling influenced by advective heat transfer
and deformation of the pluton seem to control the overall subsolidus fabric development. The rapid advective heat transfer
from the interior in the early stages of subsolidus cooling was followed by slow cooling through intermediate temperature
window as a well-developed phyllosilicate rich mylonitic skin around the granite body slowed down conductive heat loss. Low-T
crystal plastic deformation of quartz was effected at a late stage of cooling and deformation of the shallow crustal granite
body emplaced within the greenschist facies Nallamlai rocks. 相似文献
997.
Fadong Li Xianfang Song Changyuan Tang Changming Liu Jingjie Yu Wanjun Zhang 《Environmental Geology》2007,53(3):687-696
The groundwater in headwater region is an important recharge source for the adjacent mountain-front plain. In order to reveal
the relationship among precipitation, soil water and groundwater, from June to September in 2004, stable isotopes (deuterium
and oxygen-18) in precipitation and soil waters at the depths of 10, 20, 30, 50, 70, 90, and 110 cm were analyzed at two sites
covered by black locust (Robinia Pseudoacia L.) (Site A) and grass predominated by Themeda triandra (T. japonica (Willd.) Tanaka) and Bothriochloa ischaemum (B. ischaemum (L.) Keng) (Site B) in an experimental catchment at Taihang Mt., North China, respectively. The δ18O of precipitation in daily rain events shows large variations (−13.3 to −4.3‰) with a mean of 8.1‰. The δ18O and δ D of soil waters along profiles in two sites suggest that the influence of canopy cover was just up to 10 cm in top
soil water. The soil water moved over the zero flux plane at 70 cm in-depth is expected to escape the evaporative effect at
the end of September in both sites. The results show that the stable isotope, instead of tritium as tradition, can be used
to trace the soil water behaviors based on the movement of isotopic peak along the vertical profiles in this semi-arid and
semi-humid mountainous region. The infiltration depths of soil water in Taihang Mt. are 12 and 10 mm/day from June to September
in 2004 in Site A and Site B, respectively. Tracing by stable isotope, recharge fluxes of soil water to local groundwater
are of 3.8 and 3.2 mm/day in Site A and Site B, respectively. The results provide desirable information for assessment of
local groundwater resources.
An erratum to this article can be found at 相似文献
998.
The Izmir-Ankara-Erzincan suture zone of Turkey is a broad zone of ophiolitic mélange containing numerous fragmented blocks
ranging in age from Triassic to Cretaceous. Stratigraphic sequences for various mélange units are compared, together with
the geochemistry of associated basaltic pillow lavas of Cretaceous age. A review of geochemical data for the pillow lavas
demonstrate: (a) a dominant group of alkalic basalts with enriched incompatible elements, variable Zr/Y and Zr/Nb ratios,
and (b) a range of tholeiitic basalts with slightly depleted to mildly enriched (normalized) rare earth patterns, (La/Yb)N 0.4-3.0, and generally low Zr/Y ratios. The alkalic basalts can be chemically matched to Pacific Ocean seamounts, although
the close association of red radiolarites and cherts suggests that many basalts represent the margins of such structures,
rather than the main seamount edifice. Nd-Sr isotope data are typical for ocean island basalts and represent an admixture
of a dominant EM-1 source and a depleted MORB-like source. Enhanced δ18O compositions are a consequence of submarine alteration and not crustal contamination. Tholeiitic compositions have affinities
with both N- and E-type MORB, although most are probably representative of tholeiitic ocean islands. Overall the basalts are
mainly representative of structures built on the ocean floor, rather than the oceanic crust itself, being scraped off the
subducting crust and preserved in the mélange of the accretionary wedge. 相似文献
999.
Allen P. Nutman Vickie C. Bennett Clark R. L. Friend Kenji Horie Hiroshi Hidaka 《Contributions to Mineralogy and Petrology》2007,154(4):385-408
The Eoarchaean (>3,600 Ma) Itsaq Gneiss Complex of southern West Greenland is dominated by polyphase orthogneisses with a
complex Archaean tectonothermal history. Some of the orthogneisses have c. 3,850 Ma zircons, and they vary from rare single
phase metatonalites to more common complexly banded migmatites. This is due to heterogeneous strain, in situ anatexis and
granitic veining superimposed during younger tectonothermal events. In the single-phase tonalites with c. 3,850 Ma zircon,
oscillatory-zoned prismatic zircon is all 3,850 Ma old, but shows patchy ancient loss of radiogenic Pb. SHRIMP spot analyses
and laser ablation ICP-MS depth profiling show that thin (usually < 10 μm) younger (3,660–3,590 Ma and Neoarchaean) shells
of lower Th/U metamorphic zircon are present on these 3,850 Ma zircons. Several samples with this simple zircon population
occur on islands near Akilia. In contrast, migmatites usually contain more complex zircon populations, with often more than
one generation of igneous zircon present. Additional zircon dating of banded gneisses across the Complex shows that samples
with c. 3,850 Ma igneous zircon are not just a phenomenon restricted to Akilia and adjacent islands. For example, migmatites
from Itilleq (c. 65 km from Akilia) contain variable amounts of oscillatory-zoned 3,850 Ma and 3,650 Ma zircon, interpreted,
respectively, as the rock age and the time of crustal melting under Eoarchaean metamorphism. With only 110–140 ppm Zr in the
tonalites and likely magmatic temperatures of >850°C, zircon solubility–melt composition relationships show that they were
only one-third saturated in zircon. Any zircon entrained in the precursor magmas would thus have been highly soluble. Combined
with the cathodoluminesence imaging, this demonstrates that the c. 3,850 Ma oscillatory zoned zircon crystallised out of the
melt and hence gives a magmatic age. Thus the rare well-preserved tonalites and palaeosome in migmatites testify that c. 3,850 Ma
quartzo–feldspathic rocks are a widespread (but probably minor) component in the Itsaq Gneiss Complex. C. 3,850 Ma zircon
with negative Eu anomalies (showing growth in felsic systems) also occurs as detrital grains in rare c. 3,800 Ma metaquartzites
and as inherited grains in some 3,660 Ma granites (sensu stricto). These demonstrate that still more c. 3,850 Ma rocks were present, but were recycled into Eoarchaean sediments and crustally
derived granites. The major and trace element characteristics (e.g. LREE enrichment, HREE depletion, low MgO) of the best-preserved
c. 3,850 Ma rocks are typical of Archaean TTG suites, and thus argue for crust formation processes involving important contributions
from melting of hydrated mafic crust to the earliest Archaean. Five c. 3,850 Ma tonalites were selected as the best preserved
on the basis of field criteria and zircon petrology. Four of these samples have overlapping initial ɛNd (3,850 Ma) values from +2.9 to +3.6± 0.5, with the fourth having a slightly lower value of +0.6. These data provide additional
evidence for a markedly LREE-depleted early terrestrial mantle reservoir. The role of c. 3,850 Ma crust should be considered
in interpreting isotope signatures of the younger (3,800–3,600 Ma) rocks of the Itsaq Gneiss Complex.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
1000.
Analysis of kinematic seismic response of tapered piles 总被引:2,自引:0,他引:2
Mahmoud Ghazavi 《Geotechnical and Geological Engineering》2007,25(1):37-44
In the present work, a two-phase analysis is used to assess the lateral movement of a tapered pile due to kinematic seismic
loading resulted from earthquakes. First, the free-field horizontal displacement of the ground due to earthquake is estimated
using available theory of wave propagation. Second, these estimated soil movements are imposed on the taper pile in a closed-form
solution to compute the pile response. The governing differential equation for an arbitrary pile segment is obtained, which
includes the free-field horizontal movement estimated from the first phase. The equation is solved explicitly to obtain the
horizontal deflection. Parametric studies show that tapered piles tend to be more flexible than uniform piles of the same
volume and length under earthquake loading, which is soundly interesting. 相似文献