Sensitivity of near-surface Tropical Instability Waves to submonthly wind forcing in the tropical Atlantic

This study demonstrates the sensitivity of the near-surface properties in the tropical Atlantic Ocean to the high-frequency of the winds in numerical simulations. At intra-seasonal timescales (2–50 days), two distinct period ranges dominate the variability in the upper ocean: periods between 2 and 20 days, which are essentially wind-forced and periods between 20 and 50 days, due mostly to Tropical Instability Waves (TIWs). Using a numerical model forced by different wind fields, it is shown that the characteristics of the intra-seasonal variability in the ocean surface mixed-layer are strongly dependent on the wind forcing. Submonthly winds are shown to force large variability in the upper ocean that can strikingly decrease the amplitude of the TIWs in the mixed-layer and their imprint on the horizontal distribution of sea surface temperatures. Wind products containing too much energy at submonthly periods thus prevent wind-forced simulations from reproducing a realistic surface signature of TIWs, when compared to satellite observations of sea surface temperature. In addition, submonthly wind variability may be responsible for part of the observed interannual variability of the TIW signature in the temperature. The impact of submonthly winds is strongest in the mixed-layer: beneath the mixed-layer, all simulations show similar characteristics of the TIWs.     

Changes in ostracod assemblages and morphologies during lake‐level variations of Lago Cardiel (49°S), Patagonia,Argentina, over the last 15.6 ka

Changes in the ostracod assemblages from two sediment cores collected from Lago Cardiel in southeastern Patagonia (49°S) reflect the main regional abrupt climatic changes over the last 15.6 cal. ka BP. Shifts in species abundance and switches in dominances suggest that these were mainly driven by variable salinity. During the Late Pleistocene, Limnocythere rionegroensis was abundant and dominant, indicating waters with high salinity and prevalence of evaporative processes. Between 12.6 and 10.8 cal. ka BP, Lago Cardiel expanded markedly and reached an Early Holocene highstand of +55 m above present lake level. A major change in ostracod assemblage in which Limnocythere patagonica appears as the dominant species in parallel with the disappearance of L. rionegroensis and Eucypris aff. cecryphalium mirrored this transitional period between the cold and dry Late Pleistocene and the humid and warm Early Holocene. Over the last 4 cal. ka BP, L. rionegroensis returned to the species assemblage and Riocypris whatleyi increased its abundance pointing towards increasing salinities. The variations in size, shape and ornamentation of L. rionegroensis and R. whatleyi fossil valves were examined using geometric morphometric techniques and further compared to those of modern Patagonian sites. Limnocythere rionegroensis specimens displayed high morphological variability during the evolution of Lago Cardiel. More specifically, the switch in reproductive mode – from sexual to parthenogenetic– and the increase in valve ornamentation around 12.7 cal. ka BP suggest that these changes were promoted by the hydrological alteration that occurred in the Late Pleistocene. This exercise provides a robust range of morphological variation for these proxies, which will be useful in further taxonomic and palaeoenvironmental studies adding more information about different factors influencing the observed morphological trends.     

Evaluation of inundation areas resulting from the diversion of an extreme discharge towards the sea: case study in Tabasco,Mexico

This investigation comprises the hydraulic characterisation of a river located in the Mexican State of Tabasco, including the performance of its flood plain under the action of an extreme river discharge. This is done through the combination of a high‐quality validation dataset, remote sensing information, and a standard 2D numerical model. The dataset was collected during an intensive field campaign that took place in August 2009. In particular, in situ measurements of river discharge, bathymetry, water level, and velocities through a whole tidal cycle are employed along with multi‐spectral satellite imagery. The purpose of this study is twofold. Firstly, the integrated approach comprising the combination of a 2D hydrodynamic model, high‐quality in situ measurements and satellite imagery reduce the uncertainty in the model parameterisation and results. Secondly, it is shown that freely available sources of information, such as the Shuttle Radar Topographic Mission (SRTM) data can be processed and utilized in 2D hydraulic models. This is particularly important in countries where high‐resolution elevation data is not yet available. It is demonstrated that the selected approach is useful when the study of possible consequences in a flood plain induced by an extreme flood discharge are sought. Copyright © 2011 John Wiley & Sons, Ltd.     

Mesoproterozoic evolution of the R��o de la Plata Craton in Uruguay: at the heart of Rodinia?

Mesoproterozoic volcanosedimentary units and tectonic events occurring in the Río de la Plata Craton (RPC) are reviewed. A belt consisting of volcanosedimentary successions exhibiting greenschist-facies metamorphism is exposed in the eastern RPC (Nico Pérez Terrane) in Uruguay. The Parque UTE Group consists of basic volcanics and gabbros at the base (1,492?±?4?Ma, U?CPb on zircon), carbonates in its middle part and interbedded carbonates, shales and acid volcanics (1,429?±?21?Ma, U?CPb on zircon) at the top. The Mina Verdún Group is made up of rhyolites and acid pyroclastics at its base and top, and Conophyton-bearing limestones and massive dolostones in the middle. A U?CPb LA-ICP MS zircon age of 1,433?±?6?Ma is reported here for lapilli-tuffs at the base of the Mina Verdún Group (Cerro de las Víboras Formation). This age shows that the Mina Verdún Group immediately postdates the Parque UTE Group, a fact supported by carbon isotope chemostratigraphy. Both units were deformed and metamorphosed between 1.25 and 1.20?Ga, as shown by K?CAr and Ar?CAr ages. This tectonic event affected most of the RPC and led to the accretion of the Nico Pérez Terrane to the remainder of the RPC along the Sarandí del Yí megashear. We report a U?CPb LA-ICP MS zircon age (upper intercept) of 3,096?±?45?Ma for metatonalites of the La China Complex (Nico Pérez Terrane), which yield a lower intercept age of 1,252?Ma. A proto-Andean, Mesoproterozoic belt is envisaged to account for abundant Mesoproterozoic detrital zircon ages occurring in Ediacaran sandstones of the RPC. If the RPC is fringed at both sides by Mesoproterozoic, Grenville-aged belts it is likely that it occupied a rather central position in Rodinia. A possible location between Laurentia and the Kalahari Craton, and to the south of Amazonia, is suggested.     

Selenium in volcanic environments: A review

Selenium is a chemical element with major environmental implications, due to the extremely narrow range between essential and toxic concentrations. Volcanoes emit significant amounts of Se, which has an enormous impact on the Se cycle and potentially human and animal health. This paper presents a broad overview of the current state of knowledge of major aspects of volcanic derived Se, focussing on the processes in soils and aquifers.     

Aggregation of humic acid in solution: Contributions of different fractions

The role of lipid components in the aggregation of several humic acids isolated from different sources was investigated using surface tensiometry. A combination of aqueous alkaline and organic solvent extractions was used to isolate two humic-like fractions (HA₁ and HA₂) and one lipid-like fraction from each humic acid. Fraction HA₁ represents approximately two-thirds of the total organic carbon of the original humic acid and under alkaline conditions is a weak surfactant that lowers the surface tension of water by only a small amount. The HA₂ fraction represents up to one-third of the humic acid and significantly lowers the surface tension of water. It is also intimately associated with the lipid fraction. Unlike the original humic acid samples, HA₂ does not show micelle-like aggregation over the concentration range studied. Aggregate formation is discussed as an emergent characteristic that results from the interaction of the humic acid’s components with the lipid components serving a facilitative role.     

Present Limnological Conditions and Recent (ca. 340 yr) Palaeolimnology of a Tropical Lake in the Sierra de Los Tuxtlas, Eastern Mexico

The Sierra de Los Tuxtlas is a recently active volcanic field, with eruptions in 1664 and 1792. It holds one of the reserves of tropical evergreen forest in Mexico, as well as several maar lakes. One of them, Lago Verde, was chosen for a three-fold study (1) on its present limnological conditions, (2) on the algal community living in the water column and preserved in the surface sediments; and (3) on its recent history (ca. 340 yr). The palaeolimnological study was based on multiproxy analyses on core material dated by ²¹⁰Pb, ¹³⁷Cs and ¹⁴C. Lago Verde is a small, shallow lake with dilute, slightly alkaline water (CO₃²⁻ + HCO₃⁻ > Cl⁻ > SO₄²⁻, Na⁺ + K⁺ > Ca²⁺ > Mg²⁺). It is turbid, eutrophic, with high phosphorus levels. It is a warm polymictic lake, with thermal and oxygen stratification establishing by midday during the warm months. The lake does not stratify in winter. Diatoms dominate the phytoplankton community in the cold ‘nortes’ season, Cyanobacteria in summer, and Chlorophyta in autumn. Cyanobacteria (Chroococcales) are not well preserved in the surface sediments while Chlorophyta are better preserved. Sedimentary diatoms are well preserved, dominated by the three most abundant species in the water column: Achnanthidium minutissimum, Fragilaria capucina and Aulacoseira granulata. The base of the studied sequences is constrained by the historic eruption of 1664. The period from 1664 to 1963 is characterised by a meso-eutrophic lake. Tropical Forest vegetation reaches maximum values between ca. 1800 and 1963. Between ca. 1785 and 1885 the lake was slightly shallower than in the rest of the 1664–1963 period, probably recording climatic variability. An early pulse of anthropogenic disturbance was recorded by ca. 1921 and after ca. 1963 intense forest clearance and high erosion rates led to a more turbid, more productive, nutrient-rich lake. The highest anthropogenic impact was reached by ca. 1988; afterwards the lake and its basin reached a new balance, with the establishment of the present modern conditions.     

Transtensional fault-termination basins: an important basin type illustrated by the Pliocene San Jose Island basin and related basins in the southern Gulf of California, Mexico

Transtensional basins are sparsely described in the literature compared with other basin types. The oblique‐divergent plate boundary in the southern Gulf of California has many transtensional basins: we have studied those on San Jose island and two other transtensional basins in the region. One major type of transtensional basin common in the southern Gulf of California region is a fault‐termination basin formed where normal faults splay off of strike‐slip faults. These basins suggest a model for transtensional fault‐termination basins that includes traits that show a hybrid nature between classic rift and strike‐slip (pull‐apart) basins. The traits include combinations of oblique, strike‐slip and normal faults with common steps and bends, buttress unconformities between the fault steps and beyond the ends of faults, a common facies pattern of terrestrial strata changing upward and away from the faults into marine strata, small fault blocks within the basin that result in complex lateral facies relations, common Gilbert deltas, dramatic termination of the margin of the basin by means of fault reorganization and boundary faults dying and an overall short basin history (few million years). Similar transtensional fault‐termination basins are present in Death Valley and other parts of the Eastern California shear zone of the western United States, northern Aegean Sea and along ancient strike‐slip faults.