Historical record of heavy metals in a highly contaminated Mediterranean deposit: The Besòs prodelta

The Besòs prodelta, located around a highly populated area, receives the discharge of the Besòs River, one of the most contaminated rivers discharging into the Mediterranean sea. The record of heavy metals accumulated in this prodelta is studied to assess the sedimentary behaviour and the history of the anthropogenic heavy metals in the area.

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dated sediments have allowed the identification of the sedimentation patterns and the elaboration of dated heavy metals and cenospheres profiles, which reflected the evolution of the anthropogenic impact in this marine environment. Sediments accumulated during the 18th and 19th centuries were already affected by a moderate heavy metal contamination. This contamination increased drastically in the sediments accumulated during the last decades. This data is well correlated with the increase in industrialisation, population and energy consumption in the Besòs drainage basin during the last century.     

Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay

A combination of CTD casts, discrete bottle sampling and in situ voltammetric microelectrode profiling was used to examine changing redox conditions in the water column at a single station south of the Bay Bridge in the upper Chesapeake Bay in late July/early August, 2002–2005. Short-term (2–4 h) fluctuations in the oxic/suboxic/anoxic interface were documented using in situ voltammetric solid-state electrodes. Profiles of dissolved oxygen and sulfide revealed tidally-driven vertical fluctuations of several meters in the depth and thickness of the suboxic zone. Bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ also varied over the tidal cycle by approximately an order of magnitude. These data indicate that redox species concentrations at this site varied more due to physical processes than biogeochemical processes. Based on analysis of ADCP data, tidal currents at this station were strongly polarized, with the principal axis of tidal currents aligned with the mainstem channel. Together with the chemical data, the ADCP analysis suggests tidal flushing of anoxic bottom waters with suboxic water from north of the site. The present study is thus unique because while most previous studies have focused on processes across relatively stable redox interfaces, our data clearly demonstrate the influence of rapidly changing physical mixing processes on water column redox chemistry.Also noted during the study were interannual differences in maximum bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺. In 2003, for example, heavy spring rains resulted in severe hypoxia/anoxia in June and early July. While reported storm-induced mixing in late July/early August 2003 partially alleviated the low-oxygen conditions, bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ were still much higher than in the previous year. The latter implies that the response time of the microbial community inhabiting the suboxic/anoxic bottom waters to changing redox conditions is slow compared to the time scale of episodic mixing events. Bottom water concentrations of the redox-sensitive chemical species should thus be useful as a tracer to infer prior hypoxic/anoxic conditions not apparent from ambient oxygen levels at the time of sampling.     

A comparative mineralogical study of gas-related sediments of the Gulf of Cádiz

The Gulf of Cádiz area has been extensively surveyed in recent years and several gas-related fluid escape seafloor structures have been identified. In this study, gravity cores, collected during the ANASTASYA/00 and ANASTASYA/01 cruises, on mud volcanoes, hemipelagic sediments and dredged material from diapiric structures, have been studied. A comparative mineralogical analysis by XRD and SEM of samples from different areas has been performed in order to determine whether there is a characteristic mineralogy related to these fluid escape structures, and also to determine the origin of the mud matrix and constrain the depth of the parent units. The mineralogical analysis reflects the different origins of the different units described in the cores: hemipelagic material of the slope, clays that underlie the mud volcanoes and are discharged at the sea bottom surface, and authigenic and diagenetic minerals possibly involved in the anaerobic oxidation of methane in the mud volcano sediments.     

The distribution of chlorophyll-a and dominant planktonic components in the coastal transition zone off Concepción, central Chile, during different oceanographic conditions

The oceanographic setting and the planktonic distribution in the coastal transition zone off Concepción (∼35-38°S, ∼73-77°W), an area characterized by its high biological production, were assessed during two different seasons: austral spring with equatorward upwelling favorable winds and austral winter with predominately northerly winds. Oceanographic and biological data (total chlorophyll-a, particulate organic carbon, microplankton, large mesozooplankton >500 μm as potential consumers of microplankton) were obtained during two cruises (October 1998, July 1999) together with satellite imagery for wind stress, geostrophic flow, surface temperature, and chlorophyll-a data. The physical environment during the spring sampling was typical of the upwelling period in this region, with a well-defined density front in the shelf-break area and high concentrations of surface chlorophyll-a (>5 mg m⁻³) on the shelf over the Itata terrace. During the winter sampling, highly variable though weakly upwelling-favorable winds were observed along with lower surface chlorophyll-a values (<2 mg m⁻³) on the shelf. In the oceanic area (>100 km from the coast), cyclonic and anti-cyclonic eddies were evident in the flow field during both periods, the former coinciding with higher chlorophyll-a contents (∼1 mg m⁻³) than in the surrounding waters. Also, a cold, chlorophyll-a rich filament was well defined during the spring sampling, extending from the shelf out to 350-400 km offshore. Along a cross-shelf transect, the micro- and meso-planktonic assemblages displayed higher coastal abundances during the spring cruise but secondary peaks appeared in the oceanic area during the winter cruise, coinciding with the distribution of the eddies. These results suggest that the mesoscale features in this region, in combination with upwelling, play a role in potentially increasing the biological productivity of the coastal transition zone off Concepción.     

Increasing imposex in populations of Bolinus brandaris (Gastropoda: Muricidae) in the northwestern Mediterranean.

The muricid gastropod Bolinus brandaris exhibited imposex, a phenomenon linked to the use of organotin biocides. Several stages of imposex development (1-5) could be distinguished and were documented with SEM-photographs for the first time in this species. Additional alterations of the genital tract in females (blocked vulva preventing copulation and deposition of egg capsules) and males (excrecences on the penis and vas deferens) were shown. Imposex intensity on the Catalan coast was very high. The frequency of imposex off Barcelona and Vilanova i la Geltrú was 100%, with all females showing stage 4. Imposex frequency off Sant Carles de la Ràpita was 99.7% and the VDS index scored 3.9. Despite regulations of TBT-containing antifouling paints in Spain since 1990, the present study revealed that frequency and intensity of imposex have increased on the Catalan coast, at least since 1997. However, at present, imposex does not apparently affect the population dynamics of B. brandaris in the studied area, since no serious consequences on female reproduction (only one case of female sterilization) were detected. Gonadal activity and oogenesis were not suppressed or supplanted by spermatogenesis. Sex ratios were not male-biased. Possible sources of organotin biocides are examined.     

Onshore Neogene stratigraphy in the North of the Alboran Sea (Betic Internal Zones): Paleogeographic implications

The Neogene is the period in which the Betic Cordillera, the Rif, and the Alboran Sea acquired their present configuration. The Neogene sediments of the Betic Internal Zones (located directly to the North of the Alboran Sea) show the effects of important periods of deformation. Deposition was clearly controlled by tectonics. Therefore the generation, evolution, and total or partial destruction of basins and the formation of new, often superimposed, basins are common phenomena, according to the locations of the basins in the Betic Cordillera and to the different geodynamic situations.     

Petroleum geochemistry of the Kimmeridge Clay of onshore Southern and Eastern England

The Kimmeridge Clay is considered a major oil source rock for the North Sea hydrocarbon province. The formation is also developed onshore in an organic-rich mudstone facies. This paper examines the possibility of onshore oil generation from the Kimmeridge Clay. Geochemically, onshore basin margin sediments contain rich, potential source horizons with mainly Type l/Type ll oil-prone kerogen, but are immature. Some deeper Cleveland Basin sediments have reached marginal maturity. Burial history reconstruction suggests significant formation palaeoburial depths in central areas of the Cleveland and Wessex Basins. Computed vitrinite isoreflectance contours show the Wealden and Isle of Wight Kimmeridge Clay to be thermally mature. Basin modelling suggests an early Palaeogene onset of oil generation in parts of the Cleveland Basin, while maximum oil generation could have been reached by the formation base in the Isle of Wight area during the late Cretaceous. Although basin subsidence ceased in the Neogene, in the Weald and Isle of Wight, where the formation is still deeply buried, oil generation probably continued for some time during uplift. Thus significant quantities of oil could have been generated. Whether or not this oil is present today however, would depend on the correct timing of suitable migration and trap structures.     

North Pacific Synthesis of the Joint Global Ocean Flux Study: Overview

This special issue is comprised of 13 papers, including this overview, and focuses on the synthesis of the Joint Global Ocean Flux Study (JGOFS) in the North Pacific which took place from 1997 through 2003. The effort was led by the JGOFS North Pacific Synthesis Group, with the aim of quantifying CO₂ drawdown by physical and biological pumps in the North Pacific by identifying and studying the regional, seasonal to inter-annual variations in the key processes, and understanding their regulating mechanisms. Emphasis was placed on the similarities and differences of the biogeochemical regimes in the eastern and western subarctic Pacific. Effort was also made to address the future research directions which arose from the scientific findings during the North Pacific JGOFS process study. A brief overview of the papers from view points of CO₂ drawdown by physical and biological pumps, spatial variability, and temporal variability from seasonal to decadal scales is made, followed by suggestions for the directions of future research. This revised version was published online in July 2006 with corrections to the Cover Date.