From the plutonic root to the volcanic roof of a continental magmatic arc: a review of the Neoproterozoic Araçuaí orogen,southeastern Brazil

International Journal of Earth Sciences - The Araçuaí-West Congo orogen (AWCO) is one of the various components of the Brasiliano/Pan-African orogenic network generated during the...     

Granite emplacement by crustal boudinage: example of the Calmayo and El Hongo plutons (Córdoba,Argentina)

This study deals with the structure and emplacement of the Calmayo and El Hongo trondhjemite plutons (Famatinian belt of Córdoba, Argentina). It provides structural data from the granites and the country rocks and a study of the magnetic fabric in the plutons. New U/Pb geochronological data yield intrusion ages of 512.1 ± 3.4 Ma and 500.6 ± 4.5 Ma for the Calmayo and El Hongo plutons respectively. The El Hongo massif and the southern part of the Calmayo trondhjemite preserve magmatic structures, whereas the northern domain of Calmayo shows the imprint of solid‐state deformation. The main foliation in the country rocks outlines a boudin‐like pattern at the map scale and the granites are located along boudin necks, suggesting that the emplacement of these trondhjemite plutons was linked to large‐scale boudinage of the country rocks.     

Mantle derived crystal-poor rhyolitic ignimbrites: Eruptive mechanism from geochemical and geochronological data of the Piedra Parada caldera,Southern Argentina

Trace elements, isotopic modeling and U-Th-Pb SHRIMP zircon age constraints are used to reconstruct the eruption history and magmatic processes of the Piedra Parada Caldera. In the early Eocene, the crystal-poor Barda Colorada ignimbrite(BCI), having 15% micro-porphyritic crystals with respect to magmatic components, erupted a volume estimated in more than 300 km~3. The Piedra Parada caldera is located in the Patagonian Andes foreland, at the southern end of the calderas field of the Pilcaniyeu Volcanic Belt(PVB). This belt is related to an extensional tectonic setting as a result of the collision of the Farallon-Aluk ridge with South America, which enabled the development of a transform ocean/continental plate margin followed by the detachment of the Aluk plate and the opening of a slab window. The BCI extra-caldera Plateau is a 100 m thick deposit, having a lower unit with high silica(Si O_2 76 wt.%),potassium poor rhyolitic composition(trondhjemitic like magma), and an upper unit with normal to high potassium rhyolitic composition(granitic like magma). A trace elements modeling of the BCI units shows that the BCI lower and upper units did not evolve from fractionation or immiscibility in the shallow magma reservoir. The BCI also have a primitive isotopic signature(initial87 Sr/86 Sr =0.7031-0.7049 and ε_(Nd)= +3.4 to +3.65). Thus, tectonic, compositional and isotopic constraints suggest the fast ascent of high silica magmas to a shallow reservoir, and point to an upper mantle origin for these rhyolitic magmas in a transitional(Orogenic-Anorogenic) tectono-magmatic setting. U-Th-Pb SHRIMP zircon crystallization ages of the Syn-caldera stage BCI units(56 -51.5 Ma) show a protracted life of 5 Ma for this caldera reservoir. The age of 52.9 ± 0.3 Ma is considered the best fit for the possible maximum age for the caldera collapse. The Late-caldera magmatism has trachyandesitic and rhyolitic compositions.The trace element modeling suggests that these rhyolites evolve from the trachyandesites and do not evolve from the BCI residual magma. The trachyandesites have U-Th-Pb SHRIMP zircon crystallization ages of 52 ± 1 Ma, suggesting that the caldera eruption was triggered by the arrival of the trachyandesitic magma.     

Comparison of Linear Regression Models for Quantitative Geochemical Analysis: An Example Using X-Ray Fluorescence Spectrometry

This paper presents statistical aspects related to the calibration process and a comparison of different regression approaches of relevance to almost all analytical techniques. The models for ordinary least-squares (OLS), weighted least-squares (WLS), and maximum likelihood fitting (MLF) were evaluated and, as a case study, X-ray fluorescence (XRF) calibration curves for major elements in geochemical reference materials were used. The results showed that WLS and MLF models were statistically more consistent in comparison with the usually applied OLS approach. The use of uncertainty on independent and dependent variables during the calibration process and the calculation of final uncertainty on individual results using error propagation equations are the novel aspects of our work.     

Characterisation of dispersed organic matter from lower Palaeozoic metasedimentary rocks by organic petrography, X-ray diffraction and micro-Raman spectroscopy analyses

Dispersed organic matter (DOM) concentrates of C-rich rocks from areas with different metamorphic characteristics were studied by organic petrography, X-ray diffraction (XRD) and micro-Raman spectroscopy analysis. The concentrates contain several types of DOM with different morphologies, reflectance, X-ray diffraction and micro-Raman characteristics.Four different morphological types were identified in the two studied areas. The different types have different distributions and their reflectance is quite variable in the four types, with a dominance of the highest reflectance values in the DOM from the area with the highest metamorphic grade.XRD analyses of samples from the areas reveal the presence of fine graphite together with non-graphitised carbons.The Raman spectral profiles show the usual bands G (1582 cm⁻¹) and D1 (1350 cm⁻¹), on the first-order Raman spectrum, and S1 (2700 cm⁻¹) on the second-order spectrum. Additional weaker bands, D2 (1620 cm⁻¹), and more rarely D3 (1500 cm⁻¹) and S2 (2900 cm⁻¹), are present. These are characteristic for disordered carbons in the different types of DOM and in both studied areas. However, the Raman parameters (D1/G intensity area ratio and the frequency and width of G band) indicate variable degrees of organisation in all DOM types.The existence of different types of DOM with different degrees of ordering in the same lithologies and metamorphic grade seems to be related to different organic precursors, as they are graphitised to different extents under the same metamorphic conditions. However, in the same lithologies and metamorphic grade, the existence of various stages of graphitisation within the same type of DOM can only be explained though the interaction of DOM with the metamorphic fluids present in the rocks. The ordering graphitisation process may be due to the existence of metamorphic fluid circulation events with a variety of compositions.     

A spring and wooded habitat at FLK Zinj and their relevance to origins of human behavior

The 1959 discovery of the hominin fossil Zinjanthropus boisei brought the world's attention to the rich records at Olduvai Gorge, Tanzania. Subsequent excavations of archaeological level 22 (FLK Zinj) Bed I uncovered remains of Homo habilis and a high-density collection of fossils and Oldowan stone tools. The occurrence of this unusual collection of bones and tools at this specific location has been controversial for decades. We present paleoecological data that provide new insights into the origin of FLK Zinj. Our recent excavations 200 m north of the site uncovered a 0.5-m-thick tufa mound draped by Tuff IC, in the same stratigraphic horizon as level 22. Stable isotope analyses indicate that the carbonates were deposited by a freshwater spring. Phytolith analysis of the waxy clay under Tuff IC revealed abundant woody dicotyledon and palm phytoliths, indicating that the site was wooded to densely wooded. The time equivalency and close physical proximity of the two environments indicate the two are related. This study has provided the first documented evidence of springs in Bed I and these data have important implications for the interpretation of hominin behavior in meat acquisition and the ongoing debate on scavenging versus hunting.     

Integrated geophysical interpretation for the area located at the eastern part of Ismailia Canal, Greater Cairo, Egypt

The integrated geophysical interpretation for the different geophysical tools such as resistivity and gravity is usually used to define the structural elements, stratigraphic units, groundwater potentiality, and depth to the basement rocks. In the present work, gravity and resistivity data were utilized for detecting the groundwater aquifer and structural elements, as well as the upper and lower surfaces of the subsurface basaltic sheet in an area located at the eastern side of Ismailia Canal, northeastern Greater Cairo, Egypt. Two hundred and ten gravity stations were measured using an Autograv instrument through a grid pattern of 50?×?50 m. The different required corrections were carried out, such as drift, elevation, tide, and latitude corrections. The final corrected data represented by the Bouguer anomaly map were filtered using high- and low-pass filters into regional and residual gravity anomaly maps. The resulting residual gravity anomaly map was used for gravity modeling to calculate the depths to the upper and lower surfaces of the basaltic sheet. The resulting gravity models indicated that the depths to the upper surface of the basaltic sheet are ranged between 26 and 314 m, where the shallower depths were found around the southern and eastern parts. The depths to the lower surface of the basaltic sheet are varied from 86 to 338 m, and the thickness of the basaltic sheet is ranged from 24 to 127 m, where the biggest thicknesses were found around the southern and northern parts of the study area. Forty-two vertical electrical soundings (VES) were carried out using Schlumberger configuration with AB/2 spacings ranged from 1.5 to 500 m. 1D quantitative interpretation was carried out through manual and analytical interpretations. The VES data were also inverted assuming a 3D resistivity distribution. The results from the 3D resistivity inversion indicated that the subsurface section consists of sand, sandstone, and sandy–clays of Miocene deposits overlying the basalts. Such basaltic features (of Oligocene age) are underlain by Gabal Ahmar Formation of Oligocene deposits, which are composed of sand and sandstone. Therefore, two aquifers were deduced in the area. The first is the Miocene aquifer (shallower) and the other is the Oligocene aquifer (deeper).     

Geochemical Constraints on the Origin of the Ni–Cu Sulfide Ores in the Tejadillas Prospect (Cortegana Igneous Complex,SW Spain)

After the discovery of the Aguablanca ore deposit (the unique Ni–Cu mine operating in SW Europe), a number of mafic‐ultramafic intrusions bearing Ni–Cu magmatic sulfides have been found in the Ossa–Morena Zone of the Iberian Massif (SW Iberian Peninsula). The Tejadillas prospect is one of these intrusions, situated close to the border between the Ossa–Morena Zone and the South Portuguese Zone of the Iberian Massif. This prospect contains an average grade of 0.16 wt % Ni and 0.08 wt % Cu with peaks of 1.2 wt % Ni and 0.2 wt % Cu. It forms part of the Cortegana Igneous Complex, a group of small mafic‐ultramafic igneous bodies located 65 km west of the Aguablanca deposit. In spite of good initial results, exploration work has revealed that sulfide mineralization is much less abundant than in Aguablanca. A comparative study using whole‐rock geochemical data between Aguablanca and Tejadillas shows that the Tejadillas igneous rocks present a lower degree of crustal contamination than those of Aguablanca. The low crustal contamination of the Tejadillas magmas inhibited the assimilation of significant amounts of crustal sulfur to the silicate magmas, resulting in the sparse formation of sulfides. In addition, Tejadillas sulfides are strongly depleted in PGE, with total PGE contents ranging from 14 to 81 ppb, the sum of Pd and Pt, since Os, Ir, Ru and Rh are usually below or close to the detection limit (2 ppb). High Cu/Pd ratios (9700–146,000) and depleted mantle‐normalized PGE patterns suggest that the Tejadillas sulfides formed from PGE‐depleted silicate magmas. Modeling has led us to establish that these sulfides segregated under R‐factors between 1000 and 10,000 from a silicate melt that previously experienced 0.015% of sulfide extraction. All these results highlight the importance of contamination processes with S‐rich crustal rocks and multiple episodes of sulfide segregations in the genesis of high‐tenor Ni–Cu–PGE ore deposits in mafic‐ultramafic intrusions of the region.     

Conodont colour alteration indices (CAI) of Upper Ordovician limestones from the Iberian Peninsula

Conodont colour alteration index (CAI) data in Upper Ordovician rocks from several areas of the Variscan domain in the Iberian Peninsula indicate conditions ranging from diagenesis to low-grade metamorphism. In most of the areas, where studies using other indicators, such as illite crystallinity (IC) or where vitrinite reflectance are lacking, the CAI method has permitted a preliminary estimation of the metamorphic grade. In the Almadén syncline (Central-Iberian Zone), where IC studies are available, the thermal conditions inferred from CAI data agree with those obtained by the IC method. In the Puertollano–Almuradiel syncline, the thermal interval obtained primarily from fluid inclusions (270–370°C) overlaps considerably with that obtained from CAI data (180–340°C). In general, cleavage in rocks is present in anchizonal or epizonal conditions, whereas in diagenetic conditions with CAI 2.5, cleavage is scarce. The conodont texture changes with increasing metamorphism, and apatite recrystallisation appears in general with CAI 5. Variation of CAI values within a single sample and/or within short stratigraphic distances observed at several localities is due to hydrothermal activity.     

Assessment of failure susceptibility of soil slopes using fuzzy logic

Generally, the process of land occupation in urban areas involves spaces that are not suitable for construction. In most cases these areas are subject to landslides. Therefore it is mister the development of models to evaluate the susceptibility of occurrence of landslides in these areas. For this, Fuzzy Logic is used herein for modeling such areas where landslides are susceptible to occur and, therefore, a direct evaluation is important. The possibility of capturing the judgment and the modeling of linguistic variables are the main advantages of using Fuzzy Logic. These models are capable to capture the factors directly affecting the slope stability and also the inter-relationship amongst them. These factors were chosen by experts to whom a questionnaire was sent. Fuzzy Logic was then used to transform the linguistic variables into fuzzy number, allowing thus, the calculation of failure potential index (FPI). Herein the MAX-MIN Mamdani strategy for the inference of the rule base was used. This methodology has been applied to identify the susceptibility of landslides in a chaotic occupied urban area of Itaperuna City in northeastern of Rio de Janeiro, Brazil, where some occurrences have been reported.