The boundary layer of the residence time field

The residence time of a tracer in a control domain is usually computed by releasing tracer parcels and registering the time when each of these tracer parcels cross the boundary of the control domain. In this Lagrangian procedure, the particles are discarded or omitted as soon as they leave the control domain. In a Eulerian approach, the same approach can be implemented by integrating forward in time the advection–diffusion equation for a tracer. So far, the conditions to be applied at the boundary of the control domain were uncertain. We show here that it is necessary to prescribe that the tracer concentration vanishes at the boundary of the control domain to ensure the compatibility between the Lagrangian and Eulerian approaches. When we use the Constituent oriented Age and Residence time Theory (CART), this amounts to solving the differential equation for the residence time with boundary conditions forcing the residence time to vanish at the open boundaries of the control domain. Such boundary conditions are likely to induce the development of boundary layers (at outflow boundaries for the tracer concentration and at inflow boundaries for the residence time). The thickness of these boundary layers is of the order of the ratio of the diffusivity to the velocity. They can however be partly smoothed by tidal and other oscillating flows.     

Braided rivers within an arid alluvial plain (example from the Lower Triassic,western German Basin): recognition criteria and expression of stratigraphic cycles

Based on a detailed sedimentological analysis of Lower Triassic continental deposits in the western Germanic sag Basin (i.e. the eastern part of the present‐day Paris Basin: the ‘Conglomérat basal’, ‘Grès vosgien’ and ‘Conglomérat principal’ Formations), three main depositional environments were identified: (i) braided rivers in an arid alluvial plain with some preserved aeolian dunes and very few floodplain deposits; (ii) marginal erg (i.e. braided rivers, aeolian dunes and aeolian sand‐sheets); and (iii) playa lake (an ephemeral lake environment with fluvial and aeolian sediments). Most of the time, aeolian deposits in arid environments that are dominated by fluvial systems are poorly preserved and particular attention should be paid to any sedimentological marker of aridity, such as wind‐worn pebbles (ventifacts), sand‐drift surfaces and aeolian sand‐sheets. In such arid continental environments, stratigraphic surfaces of allocyclic origin correspond to bounding surfaces of regional extension. Elementary stratigraphic cycles, i.e. the genetic units, have been identified for the three main continental environments: the fluvial type, fluvial–aeolian type and fluvial/playa lake type. At the time scale of tens to hundreds of thousands of years, these high‐frequency cycles of climatic origin are controlled either by the groundwater level in the basin or by the fluvial siliciclastic sediment input supplied from the highland. Lower Triassic deposits from the Germanic Basin are preserved mostly in endoreic basins. The central part of the basin is arid but the rivers are supplied with water by precipitation falling on the remnants of the Hercynian (Variscan)–Appalachian Mountains. Consequently, a detailed study of alluvial plain facies provides indications of local climatic conditions in the place of deposition, whereas fluvial systems only reflect climatic conditions of the upstream erosional catchments.     

Sea‐level reconstructions from the Peri‐Vocontian Zone (South‐east France) point to Valanginian glacio‐eustasy

The Valanginian is a period of global environmental change as illustrated by sedimentary, palaeontological, geochemical and climatic perturbations. A production crisis in most of the carbonate platforms suggests important changes in palaeoenvironmental conditions. During the same time interval, a major positive excursion in δ¹³C, the Weissert Event, suggests perturbations of the carbon cycle from the latest Early Valanginian to the Early Hauterivian. In order to better understand the link between these changes, sea‐level fluctuations have been reconstructed in detail from the Middle Berriasian to the earliest Hauterivian. Sections from the Peri‐Vocontian Zone (South‐east France) have been investigated because of the good quality of outcrops on the carbonate platforms, their margins and in the Vocontian Basin. Sections ranging from the most proximal zone (Swiss Jura) to the basin were interpreted in terms of sequence stratigraphy and cyclostratigraphy, and correlated at high resolutions. Using the identified small, medium and large‐scale sequences as well as depositional geometries, sea‐level fluctuations were reconstructed. Two main trends are evidenced during the studied interval: (i) the peak amplitude (magnitude) of the sea‐level fluctuations increased gradually from the Middle Berriasian to the Early Valanginian, and reached a maximum (more than 50 m) from the middle Early Valanginian to the Valanginian/Hauterivian boundary; and (ii) sea‐level variations were quite symmetrical during the Late Berriasian, slightly asymmetrical during the Early Valanginian and strongly asymmetrical (fast sea‐level rise, slow fall) from the latest Early Valanginian to the earliest Hauterivian. Moreover, three orders of sea‐level fluctuations were recognized in the sedimentary rocks of the Peri‐Vocontian Zone. Platform‐basin correlations and cyclostratigraphic interpretations of the basinal sections evidence an astronomical control on the sea‐level variations, mainly by the two eccentricity cycles of 100 and 400 kyr. The increase in the amplitude of the sea‐level fluctuations and their change from symmetrical to asymmetrical can be related to the onset of a major cooling event in the Early Valanginian. Fast transgressions followed by slower regressions would correspond to waxing and waning of high‐latitudinal ice during most of the Valanginian, especially from the latest Early Valanginian to the latest Late Valanginian. Glacio‐eustatic sea‐level fluctuations in tune with the 100 and 400 kyr eccentricity cycles are in agreement with glaciations during the Valanginian.     

INTÉERÉET D'ÉETUDES HYDROLOGIQUES APPROFONDIES SUR DES BASSINS EXPÉERIMENTAUX OCCUPANT PLUSIEURS MILLIERS DE KM2

Abstract

A relationship of hydrologic variables with stream salinity was determined statistically for two ephemeral streams located in western Oklahoma. The hydrologic variables employed in this study are measures of streamflow, precipitation, anteccedent conditions, and agricultural land use.

The best single estimate of stream salinity was achieved by use of those variables classed as direct measures of precipitation, with the greatest variability in stream salinity (51%) being predicted by maximum daily P, the maximum amount of precipitation received at any rain gage zone in the watershed during one month. Maximum daily P predicts nearly double the variability in stream salinity predicted by flow. Antecedent conditions did not correlate well with stream salinity, except for the variable describing the antecedent stream salinity. Similarly, the areal location of precipitation within the watershed and agricultural land use did not correlate significantly with stream salinity, except for a variable designating the distance between the stream gaging station and the rain gage zone receiving the most precipitation for the month.

The best overall estimate of salinity was given by a multiple regression equation chosen on the basis of a factor analysis. This equation accounted for 65 percent of the variability in salinity and emphasized the contribution of variables classed as direct measures of precipitation. In comparing the two streams, the watershed having the most intensive rain gage network produced the best prediction equation.     

Controls on the alluviation of oxbow lakes by bed‐material load along the Sacramento River,California

Differences in the nature and quantity of sediment filling oxbow lakes have significant implications for the evolution of meandering rivers and the development of floodplains, influencing rates of meander migration and the valley width over which migration takes place. In an effort to identify the controls on the alluviation of oxbow lakes by coarse bed material, this study examined the sedimentary records stored within oxbow lakes of the Sacramento River of California, USA, and found that the volume of gravel in storage correlated negatively with the diversion angle separating flow between the river channel and the entrance into each lake. A method was devised for estimating the original channel bathymetry of the studied lakes and for modelling the hydraulic and sediment‐transport effects of the diversion angle within channels recently abandoned by meander cut‐off. The diversion angle determines the width of a flow separation within the abandoned‐channel entrance, reducing the discharge diverted from the river channel and thus limiting the ability of the abandoned channel to transport bed material. Aggradation rates are faster within entrances to abandoned channels with high diversion angles, resulting in the rapid isolation of lakes that store only a small volume of coarse‐grained sediment. Aggradation rates are slower within channel entrances where diversion angles are low, resulting in the slow transitioning of such channels into oxbow lakes with a larger and more extensive accumulation of coarse‐grained sediment. These findings compare well with observations in other natural settings and the mechanism which is described for the control of the diversion may explain why some oxbow lakes remain as open‐water environments for centuries, whereas others are filled completely within decades of cut‐off.     

Treatment of an ECF bleaching effluent with white-rot fungi in an air-lift bioreactor

Pulp and paper mills utilise huge amount of natural resources, inorganic and organic materials along with large volume of water in different stages of paper manufacturing, resulting in a significant volume of effluents. The aim of this work was to investigate the treatment of a bleaching effluent [effluent chlorine free (ECF)] from the cellulose industry with white-rot fungi in an air-lift bioreactor. This effluent was submitted to the biological treatment with three white-rot fungi, and, every 24 h for 120 h, analytical tests were performed to analyse the quality parameters of treatment (COD, phenols, colour, pH). Before and after treatment, the effluent was analysed as its molecular mass distribution and absorptivity in the UV/VIS. Lentinus edodes, Trametes versicolor and Trametes villosa promoted similarly significant reductions in the following characteristics: (a) effluent colour (40–44 %), (b) total phenol (30–51 %) and (c) COD (37–43 %). The UV/visible spectrometry reading of the effluent after the fungi treatment showed a reduction in the absorbance of all wavelengths between 260 and 500 nm. The size exclusion HPLC profile of the effluent was modified, and the treatment promoted changes in the intensity of the peaks associated with compounds of high and low molecular weight. Phenoloxidases were produced during the treatment. T. versicolor produced the highest levels of laccase, and L. edodes was the only fungus that produced peroxidases.     

Variabilité spatiale du signal palynologique dans le bassin de Paris à la limite Dogger–Malm

The drilling of new cores performed for ANDRA in eastern France allowed us to compare palynological data between central and eastern parts of the Paris Basin. Such a comparison, which was also motivated by the existence of a set of geochemical data in contradiction with the first palynological results, showed a spatial differentiation in palynological record from the Oxfordian. Such a palynological signal could result from overlapping of both local and global signals, the latter being in connection with the contemporaneous opening of proto-Atlantic Ocean. It could also be of major palaeogeographic and palaeoclimatic interest. To cite this article: V. Huault et al., C. R. Geoscience 335 (2003).     

Mapping groundwater quality variables using PCA and geostatistics: a case study of Bajo Andarax,southeastern Spain

Abstract

A case study is presented for the application of statistical and geostatistical methods to the problem of estimating groundwater quality variables. This methodology has been applied to the investigation of the detrital aquifer of the Bajo Andarax (Almería, Spain). The use of principal components analysis is proposed, as a first step, for identifying relevant types of groundwater and the processes that bring about a change in their quality. As a result of this application, three factors were obtained, which were used as three new variables (VI: sulphate influence; V2: thermal influence; and V3: marine influence). Analysis of their spatial distribution was performed through the calculation of experimental and theoretical variograms, which served as input for geostatistical modelling using ordinary block kriging. This analysis has allowed a probabilistic representation of the data to be obtained by mapping the three variables throughout the aquifer for each sampling point. In this way, one can evaluate the spatial and temporal variation of the principal physico-chemical processes associated with the three variables VI, V2 and V3 implicated in the groundwater quality of the detrital aquifer.     

Fundamental Problems in Astrophysics

Progress of modern astrophysics requires the access to the electromagnetic spectrum in the broadest energy range. The Ultraviolet is a fundamental energy domain since it is one of the most powerful tool to study plasmas at temperatures in the 3,000–300,000 K range as well as electronic transitions of the most abundant molecules in the Universe. Moreover, the UV radiation field is a powerful astrochemical and photoionizing agent.The objective of this review is to describe the crucial issues that require access to the UV range. A summary has been added to the end with a more classic view of UV needs by astronomical object type; this approach is followed at length in the rest of the contributions of this issue.