Ultrasonic-assisted condensation of chitosan with salicylaldehyde

In order to synthesize an improved adsorbent for heavy metal ions, we studied the condensation reaction of chitosan with salicylaldehyde in ethanol to form a Schiff base. The effect irradiating the reaction using an ultrasonic liquid processor was contrasted with conventional methods. The IR spectra of condensed chitosan prepared by the two methods showed that their molecular structures were identical. The reaction conditions, including solvents, ultrasonic power density and irradiation time, pH, and reactant ratio, were optimized by orthogonal design. A shorter reaction time and a higher product yield were obtained using ultrasonic-assisted synthesis compared with the traditional method. A condensation degree of 89.63% was achieved using the optimized conditions: i.e. ultrasonic irradiation at 180 W for 60 min; 95% ethanol as the solvent, pH 4.0, and salicylaldehyde:chitosan ratio of 6:1.     

地下水位对定点形变观测干扰的抽水实验

抽水所造成的地下水位的变化会即时在局部范围内造成地表的形变，干扰定点地壳形变观测。在蓟县地震台进行的抽水实验表明：这种干扰的幅度与抽水水井到形变监测仪器的距离有关，也和抽水水井水位的最大降深有关。根据实验数据得到了抽水对定点形变观测的影响范围的经验公式。     

中国长江流域洪涝灾害和持续性暴雨的发生特征及成因

主要综述了最近关于中国长江流域洪涝灾害和持续性暴雨发生特征和成因的研究。表明:长江流域洪涝灾害和持续性暴雨的发生频率非常高,并给经济造成了严重损失,长江流域洪涝灾害发生不仅具有准两年周期的年际变化,而且具有明显的年代际变化,从1977年之后,长江流域洪涝灾害和持续性暴雨增多;并且,表明了无论是长江中、下游地区或是长江上游的川东地区持续性暴雨都是在"鞍"型大尺度环流系统的配置下发生,这是由于这种大尺度环流系统的配置不仅利于水汽输送到长江中、下游地区或上游的川东地区,而且利于在"鞍"型中心地区产生垂直对流不稳定,从而引起暴雨中尺度系统的发展。此外,还综述了长江流域洪涝灾害和持续性暴雨发生的成因的研究,这些研究表明了长江流域洪涝灾害和持续性暴雨发生的年际和年代际变化是与大气-海洋-陆面耦合的东亚季风气候系统的变异密切相关。     

利用混沌粒子群算法确定河流水质模型参数

将混沌寻优思想引入到粒子群优化算法中,提出了混沌粒子群算法,这种方法利用混沌运动的随机性、遍历性和规律性等特性对当前粒子群体中的粒子进行混沌寻优.通过这种处理使得粒子群体的进化速度加快,从而改善了粒子群优化算法摆脱局部极值点的能力,提高了算法的收敛速度和精度.并将混沌粒子群算法应用于求解分析瞬时投放示踪剂情况下的一维河流水团示踪试验数据以及确定河流水质参数的函数优化问题,结果表明,混沌粒子群算法的收敛性能明显优于粒子群优化算法.     

Transformation of Carbon and Nitrogen by Earthworms in the Decomposition Processes of Broad-leaved Litters

Earthworms are the important constituents in the decayed food web and the main ecological conditioners in the process of decomposition and nutrient mineralization. The transformation of organic carbon (C) and total nitrogen (N) in the broad-leaved litters ingested by earthworms was researched by means of a laboratory experiment. Experimental samples were collected from broad-leaved Korea Pine mixed forest in Liangshui National Natural Reserve (47°10′50″N, 128°53′20″E) in the northeastern Xiao Hinggan Mountains of Northeast China. The contents of organic C and total N in earthworms, leaf litters and earthworm faeces were analyzed. Results show that the organic C content was in the fol- lowing order: leaf litters>faeces>earthworms, while total N content was contrary to that of the organic C. The organic C contents in the different leaf litters were in the following order: Tilia amurensis>Betula costata>Acer mono, whereas the total N contents in the different leaf litters were: Betula costata>Tilia amurensis>Acer mono. The contents of organic C and total N in the faeces from the different leaf litters were almost consistent with the contents of the leaf litters. After the leaf litters were ingested by earthworms, the organic C, which was transformed to increase earthworms' weights, ac- counted for 3.90%-13.31% of the total ingestion by earthworms, while that in the earthworm faeces accounted for 6.14%-13.70%. The transformed organic C through the other metabolism (e.g., respiration) of earthworms accounted for 75.04%-89.92%. The ingested organic C by earthworms was mostly used for metabolic activities. The N ingested by earthworms was less than organic C. It is estimated that 37.08% of total N was transformed to increase the earthworm's weight, 19.97% into earthworm faeces and 47.86% for the consumption of the earthworm's activities. The earthworms not only increased the content of organic C and total N in the soil, but also decreased the values of C/N in the soil and leaf litters. Earthworms play a major role in the leaf litters' decomposition and transformation.     

近场动力学理论在区域地面沉降建模中的应用研究

地面沉降是由自然和人类活动共同作用导致的缓变性地质灾害,是区域可持续发展的重要影响因素。以往地面沉降在建模时需要地裂缝等不连续结构的位置、走向、深度等信息,在构建微分方程模拟时需假设模型连续,这对开展地面沉降-地裂缝-地面塌陷一体化模拟带来一定的局限性。于2000年出现的近场动力学理论提出以积分形式描述材料受力过程,方法具有无需先验知识与连续性假设的优点,在材料的疲劳、损伤、断裂等模拟研究中展现出良好的应用前景。本文综述了其在岩石水力压裂、滑坡、饱水岩土材料等领域的研究进展;提出了应用近场动力学进行区域地面沉降建模求解的一般方法;结合InSAR技术获取的沉降信息、三维地震频谱谐振勘探技术获取的地下结构与密度信息等,提出了模型的反演调参与优化方法。以北京东部梨园-台湖镇-张家湾镇区域为实验区,建立了其4 km×6 km范围、0.2 km深度的近场动力学地面沉降模型,以实验区地下水位月均下降速率为边界条件,对2007—2010年地面沉降过程进行模拟。模拟结果与实测值的平均绝对误差为18 mm,表明近场动力学在地面沉降建模中有较好的适用性。     

GIS支持下的全球武装冲突数据体系建设评介

地缘环境安全是国家安全的重要组成部分。准确、精细、及时更新的各类地缘冲突信息是全球地缘风险评估和预警的基础。本文全面回顾了以武装冲突为核心的全球地缘冲突数据体系建设的发展历程,剖析了地理时空定位、大数据挖掘等技术的应用进展。在地理信息系统（GIS）技术支持下,对武装冲突内涵和武装冲突事件数据体系总体框架的理解不断深入,生产出一大批高质量的数据集合或数据产品;地缘冲突在主题上逐渐细化,冲突事件记载的空间定位精度从国家发展到更小尺度的地理位置（经纬度）;在网络信息搜索与大数据挖掘技术支持下,武装冲突信息的更新频率从年度更新提高到每小时更新,全球武装冲突数据体系建设初见成效。地缘环境系统科学与地理科学的深度融合、地理大数据与人工智能技术的广泛应用将是推动本学科领域发展的重要动力。     

烟台市牟平区尺坎金矿床地质特征

尺坎金矿床地处胶东东部著名的牟平-乳山金成矿带中,区内金矿主要受区域性牟平-海阳断裂上盘的NNE向断裂控制,沿走向、倾向均具膨胀狭缩现象,中生代燕山早期的岩浆侵入活动为成矿提供了热源,古元古代荆山群变质岩系是金矿的原始矿源层。矿床成因为中温热液充填交代型。     

东濮凹陷新生代断裂特征分析

为了研究东濮凹陷新生代断裂系统的发育特征,通过对凹陷内不同区段地震剖面的解释,根据断层活动速率分析了东濮凹陷新生代断裂的活动特征及其强度,并对凹陷内不同部位的断层特征进行了对比分析。结果显示,东濮凹陷不同区段的断层发育特征既有一定的相似性,又有一定的差异性。断裂发育受到欧亚构造域和滨太平洋构造域的共同影响,同时在各区段受到的影响又有所差异。     

招平断裂带中段深部结构构造——来自地震剖面的证据

玲珑花岗岩岩基东侧的招平断裂带是胶西北矿集区的主要控矿构造之一。布设于招平断裂带中段大尹格庄矿区的地震剖面,揭示了招平断裂带中段深部的结构构造特征,地震剖面显示,玲珑岩基内部有多个类似"拱弧构造"的岩浆侵入形成的弧形界面,由此推测存在2~3期的岩浆活动。剖面显示了3期构造组合样式,第1期为以招平断裂带和宋家河断裂为组合倾向SE的铲式断裂,底部似汇入统一的构造滑脱带;第2期为倾向NW的错断了招平断裂带的反倾伸展断裂;第3期为NE向延伸以花状构造为特征的走滑断裂。前两期反映构造发育处于伸展环境,第3期显示为左行走滑。招平断裂带深部延伸存在分支复合现象,形成由2个主裂面夹持的透镜状岩片。地震反射剖面数据的获得对深刻理解该区域中生代岩浆构造演化过程和深部找矿具有重要的借鉴意义。