Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing

Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing.     

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

珠江口盆地白云凹陷新生代构造演化动力学

白云凹陷构造演化史的研究对在白云凹陷开展油气勘探和深水沉积研究具有重要的意义。通过对断裂与沉积结构平面和剖面特点的分析,结合岩浆活动特点,文中提出白云凹陷是一个复式地堑,推测这种结构特点与凹陷下地壳的强烈韧性减薄和颈缩变形有关,表现为热岩石圈的伸展。其发育机制推测与白云凹陷位于构造转换带上有关,特殊的构造位置使白云凹陷成为强烈构造变形区,岩石圈地壳强烈减薄,伴随伸展过程和地幔上涌,脆性地壳或上地幔中部分熔融物质的出现导致岩石圈强度的急剧降低,在区域伸展应力场下以韧性流变方式减薄。岩浆在构造转换带下聚集并发育主岩浆房,由于白云凹陷南北边缘没有发育正断裂系统,岩浆主要沿垂直伸展的方向运移,因此在珠琼运动一幕和二幕南南东向伸展应力作用下,岩浆向白云凹陷的东部和西部运移至北西向基底深大断裂处,那里由于北西向断裂表现为左行张剪性质而成为压力较低的地区,从而成为岩浆上涌和侵位的地方。在岩浆聚集的地区,活动岩浆体附近的脆性变形被分散的韧性变形所取代,因此在凹陷的东北和西南两个角上,发育了张性和张剪性小断裂群,由于热岩石圈弹性较差,白云凹陷长期持续沉降。白云凹陷的断裂活动和沉积演化史还受到南海海盆扩张活动的影响。     

三峡库区巫山县城新址岩质库岸再造预测

巫山县城新址位于西坪和大宁河两岸.组成该库段的基岩主要为泥岩、粉砂岩、泥灰岩等,岩性较软弱,且地质构造变动强烈,褶皱、断裂发育,岩层破碎,崩塌、滑坡分布较多,库岸再造问题严重;同时,岸坡再造又严重影响着新县城的规划和库岸的防护.因此把稳态坡形类比法应用于巫山县城新址基岩岸坡的再造预测,定量预测库岸的最终再造宽度,以指导新城的规划与建设.     

上海非开挖技术推广应用的现状和未来

阐述了非开挖技术在上海的发展轨迹、应用现状和战略思考，并以翔实和权威的资料论证了有关论点，对全国非开挖技术发展有关情况也有概括性的介绍     

浙江江山石鼓水库除险加固工程技术措施

根据浙江江山石鼓水库大坝的结构构造特点、水库地质条件以及水库病险原因与状况，制定出一套科学完善的病险水库除险加固工程技术措施和施工操作规程，对病险水库进行了全面彻底治理，并取得良好效果。详细介绍了工程病险状况，除险加固方案设计，施工工艺及操作规程，加固效果检测及评价等。     

中国南极软科学研究的意义、现状与展望

本文指出中国的南极研究大多集中在自然科学,而软科学研究相对薄弱,存在着研究领域较少和研究深度不够等不足,这会制约我国在国际南极事务中的话语权、应有权益和国际地位。为了提高中国在国际南极政治和南极事务中的地位,应重视和加强南极软科学研究。文章分析了南极软科学的研究现状和存在的问题,对今后的研究方向和课题进行了展望和讨论,可供极地软科学研究者和管理层参考。     

卤水提锂的萃取体系概述

介绍了国内外萃取法在含锂溶液,尤其在卤水中提取锂的部分研究进展情况,重点对各种萃取体系的机理和特点进行了说明,并对今后我国盐湖卤水萃取法提锂研究的方向进行了总结。     

雅安芦山4.20震后县级单元生态系统风险评价

区域生态风险评价是对各种生态风险及环境问题进行评价和管理的重要手段。针对雅安地震灾区特殊的自然地理及生态环境特征,选取芦山县为研究对象,采用遥感、GIS及SPSS统计分析的方法,通过风险源、风险受体、暴露和易损性分析,建立生态风险综合评价模型,划分生态风险区类型,进而提出生态风险管理对策。结果表明:1)微度和低度生态风险区集中分布在高海拔的森林及草地生态系统,该区生物多样性丰富,抗干扰能力较强,地质灾害及人类活动影响较小;2)中度和高度生态风险区具有沿农田及建设用地生态系统集聚分布的特征,该区地质灾害频繁,地壳活动性较强,生态系统抵抗灾害的能力较差。研究结果可为地震灾区防御、规避风险及安全选址提供科学依据。