Stepping stones and pitfalls in the determination of an anticlockwise P-T-t-deformation path: the low-P, high-T Cooma Complex, Australia

Abstract Low-pressure/high-temperature (low-P/high-T) metamorphic rocks of the Cooma Complex, southeastern Australia, show evidence of an anticlockwise pressure-temperature-time-deformation (P-T-t-D) path, similar to those of some other low-P/high-T metamorphic areas of Australia. Prograde paths are reasonably well constrained in cordierite-andalusite schists, cordierite-K-feldspar gneisses and andalusite-K-feldspar gneisses. These paths are inferred to be convex to the temperature axis, involving increase in pressure with increase in temperature. Evidence of the retrograde path is inconclusive, but is consistent with approximately isobaric cooling, as are available isotopic data on the Cooma Granodiorite, which indicate initially rapid cooling following attainment of peak temperatures. The retrograde path is inconsistent with either a clockwise P-T-t-D path involving rapid or even moderate decompression immediately post-dating the peak of metamorphism, or a path in which the retrograde component simply reverses the prograde component, because both these paths should cross reactions forming cordierite from aluminosilicate, for which no evidence has been observed. Determination of the deformational-metamorphic history of the complex is not straightfoward and depends on careful examination of critical samples. Evidence necessary for successful elucidation of the prograde, and part of the retrograde, deformational-metamorphic history in the Cooma Complex includes: (1) sequentially grown porphyroblasts that can be timed relative to surrounding foliations; (2) partial replacement microstructures providing relative timing of metamorphic reactions that cannot be timed relative to foliation development; (3) a tectonic marker foliation (S4 at Cooma) that allows correlation of foliations from one location to another; and (4) single samples containing all of the foliations and all generations of porphyroblast growth within a single metamorphic zone. The latest two or three foliations involve low strain accumulation, allowing relative timing relationships between foliations and porphyroblasts to be more clearly determined. Sequential porphyroblast growth and foliation development in the cordierite-andalusite schists is examined for situations involving rotation and non-rotation of porphyroblasts relative to geographically fixed coordinates. Although the number of foliations developed varies in the rotational situation, depending on the deformation history proposed, the sequential order of porphyroblast growths does not differ from the non-rotational situation. Thus, whether or not porphyroblasts rotated in the Cooma rocks, the sequence of reactions, and therefore P-T-t paths inferred from the relative timing of porphyroblast growths, remain the same, for the deformational histories evaluated.     

The origin of olivine-plagioclase coronas in metagabbros from the Adirondack Mountains, New York

Olivine-plagioclase coronas in metagabbros from the Adirondack Mountains, New York (USA) are spatially well-organized reaction textures consisting most commonly of sequential layers of orthopyroxene, clinopyroxene, plagioclase, and garnet; the textures are characteristic of diffusion-controlled reaction kinetics. Although similar coronas have been interpreted by previous workers in terms of an isochemical steady-state diffusion model, petrographical relations and material-balance calculations establish that coronas in the Adirondack metagabbros cannot be treated as isochemical and do not form in a single-stage steady-state process; instead they evolve through time in a complex open-system reaction. In this study, the isochemical diffusion model is modified to account for elemental fluxes across the outer boundaries of the coronal reaction band, thereby approximating the open-system behaviour of the coronas. The sequence and relative proportions of product minerals calculated by the open-system steady-state model correspond closely to those observed in coronas of the Adirondacks, over a wide range of values for the relative diffusivities of chemical components involved in the reaction, regardless of the particular method used to determine material balance in the reaction texture. Despite this correspondence, petrographical evidence for successive replacement of coronal product layers reveals that the Adirondack coronas evolved through one or more transient states, rather than forming in a single-stage steady-state process. There is no evidence that the successive replacement of coronal product layers resulted from changes in pressure or temperature, but there is petrographical evidence that these changes resulted from modification of the composition of reactant plagioclase as the corona-forming reaction proceeded. This is confirmed by the fact that the evolution of the coronas over time can be replicated with the open-system diffusion model by simulating the effect of the gradual exhaustion of plagioclase as a source of the Ca and Si components required for reaction. These simulations suggest that successive stages in the evolution of the coronas are characterized by these product sequences: (i) orthopyroxene-clinopyroxene-plagioclase-garnet; (ii) orthopyroxene-clinopyroxene-garnet; and (iii) orthopyroxene-garnet. All of these stages, and the transitions between them, are observed petrographically. Coronas in Adirondack metagabbros appear, therefore, to have originated in a complex, open-system, diffusion-controlled reaction in which the product assemblages changed as the reaction progressed.     

Submergent shorelines in the SW Pacific: evidence for an episodic post-glacial transgression

ABSTRACT High resolution seismic profiles, supported where possible by radiocarbon dates and regional stratigraphic data, indicate that the last post-glacial transgression in the SW Pacific was episodic, comprising major stillstands punctuated by rapid rises in sea-level. On the terrigenous continental shelf east of South Island, New Zealand, a succession of shorelines (S8-S1) are recognized, as follows: S8 =c. ?113 m, 18,000 yr BP; S7 =c. ?88 m, 17,000 yr BP; S6 =c. ?75 m, 15,000 yr BP; S5 =c. ?56 m, 12,000 yr BP; S4 =c. ?46 m, 11,000 yr BP; S3 =c. ?28 m, 9,500 yr BP; S3a =c. ?24 m, 9,000 yr BP; S2 =c. ?9 m, 7,500 yr BP; S1 = 0 m, 6,500 yr BP. With the exception of S8, and possibly S2, the shorelines are associated with wedges of sediment, the size and presence of which imply that (1) sea-level stabilized at some shorelines for a considerable period of time (up to 1-2,000 yr); and (2) the intervening rises of sea-level, estimated to have been at least 10-12 m 10³ yr^?1, were too rapid to allow the reworking of the wedges into a transgressive sediment sheet, as favoured in some current models. On the Great Barrier Reef shelf, off Queensland Australia, shorelines S8-S1 have also been recognized, with a further shoreline feature S4a occurring at c. -39 m. Shorelines S1a (0 m/0 yr BP), Sib (+ 2-3 m/6,000 yr BP) and Sic (0 m/6,500yr BP) are recognized as discrete aspects of the post-6,500 yr BP sea-level behaviour in north-eastern Australia. The rapid rise in sea-level, at least between shorelines S5 (12,000 yr BP) and S3 (9,500 yr Bp), is known to have outpaced reef growth, causing in situ drowning of reefs located along the deeper shorelines. All modern reefs so far drilled and dated began their development at or above S3 (-28 m, 9,500 yr BP). Some of the shorelines, particularly S5, appear to correlate between the northern and southern hemispheres on the basis of age, succession and general depth of occurrence, suggesting (1) that they may be global features controlled by the post-glacial pattern of ice-sheet decay; and (2) that hydro-isostatic adjustment may exert only a minor control on the depth of particular shorelines, at least during the earlier parts of the post-glacial transgression.     

RECOGNITION OF A BIOFILM AT THE SEDIMENT–WATER INTERFACE OF AN ACID MINE DRAINAGE-CONTAMINATED STREAM,AND ITS ROLE IN CONTROLLING IRON FLUX

Material collected over a month on plates attached to the bed of the Afon Goch, Anglesey, a stream highly contaminated by acid mine drainage (AMD), was either examined intact by electron microscopy or suspended and cultured to reveal the presence of microbiota. Certain of the aerobic microbiota were identified, the genus Pseudomonas formed the commonest isolate and cultures of Serratia plymuthica were grown in order to compare the biofilms formed with the material collected in the Afon Goch. The material at the sediment–water interface of the Afon Goch was of similar underlying morphology to that of the cultured biofilms. However, the former had a superficial granular coating of equidimensional (60–100 nm) and evenly spaced iron rich particles (determined by X-ray microanalysis). The sediment–water interface of this AMD-contaminated stream is therefore best described as a highly contaminated biofilm. Evidence from previous work suggests that the streambed is active in iron removal from the water column. The intimate association of iron with microbiota at the streambed, therefore, implies that iron flux prediction may not be possible from physical and chemical data alone but requires knowledge of biofilm physiology and ecology. Microbially mediated metal precipitation, both by single bacteria and by biofilms, has been reported elsewhere but mass balance considerations suggest that this explanation cannot hold good for the large amounts of iron hydroxide depositing from waters of the prevalent pH and redox status. Filtered stream water analyses indicate the presence of colloidal iron hydroxide and also its removal downstream where ochreous (iron hydroxide rich) material accumulates. The process of iron immobilization is likely to be the attraction and physical trapping of colloidal iron hydroxide by extracellular polymeric substances (EPS) which constitute the matrix of biofilms. © 1997 John Wiley & Sons, Ltd.     

Government Intervention in the Muda Irrigation Scheme, Malaysia: 'actors', expectations and outcomes

At the dawn of the third millennium the problems associated with large-scale irrigation lie largely unresolved. The outcomes of government policies rarely correspond with expectations, leading to conflict and misunderstanding between federal governments, local agencies and farmers. This paper examines the mis-match of expectations between policy implementors and policy recipients in the implementation of one government policy (tertlary intervention) in the Muda irrigation scheme, Malaysia. The findings illustrate that this policy is not achieving the productivity increase or water saving expectations for which it was designed. Instead, tertiary intervention has increased the capacity of the farmers to unofficially control the distribution and supply of the water resource and to engage in off-farm productive and non-productive activities. This results in: a significant over-supply of water; the inefficient use of this supply; and a reduction in yields without a reduction in incomes. Importantly, tertiary intervention has enabled the farmers to diversify their livelihood strategies whilst retaining access to the rice-farming culture. The findings presented in this paper serve to illustrate the significance of 'actor'expectations on policy outcomes and agrarian change.     

Evaluation of Unified Model Microphysics in High-resolution NWP Simulations Using Polarimetric Radar Observations

The UK Met Office Unified Model(UM) is employed by many weather forecasting agencies around the globe. This model is designed to run across spatial and time scales and known to produce skillful predictions for large-scale weather systems. However, the model has only recently begun running operationally at horizontal grid spacings of ～1.5 km [e.g.,at the UK Met Office and the Korea Meteorological Administration(KMA)]. As its microphysics scheme was originally designed and tuned for large-scale precipitation systems, we investigate the performance of UM microphysics to determine potential inherent biases or weaknesses. Two rainfall cases from the KMA forecasting system are considered in this study: a Changma(quasi-stationary) front, and Typhoon Sanba(2012). The UM output is compared to polarimetric radar observations in terms of simulated polarimetric radar variables. Results show that the UM generally underpredicts median reflectivity in stratiform rain, producing high reflectivity cores and precipitation gaps between them. This is partially due to the diagnostic rain intercept parameter formulation used in the one-moment microphysics scheme. Model drop size is generally both underand overpredicted compared to observations. UM frozen hydrometeors favor generic ice(crystals and snow) rather than graupel, which is reasonable for Changma and typhoon cases. The model performed best with the typhoon case in terms of simulated precipitation coverage.     

Porphyroblast inclusion trails: the key to orogenesis

Detailed microstructural analysis of inclusion trails in hundreds of garnet porphyroblasts from rocks where spiral-shaped inclusion trails are common indicates that spiral-shaped trails did not form by rotation of the growing porphyroblasts relative to geographic coordinates. They formed instead by progressive growth by porphyroblasts over several sets of near-orthogonal foliations that successively overprint one another. The orientations of these near-orthogonal foliations are alternately near-vertical and near-horizontal in all porphyroblasts examined. This provides very strong evidence for lack of porphyroblast rotation.
The deformation path recorded by these porphyroblasts indicates that the process of orogenesis involves a multiply repeated two-stage cycle of: (1) crustal shortening and thickening, with the development of a near-vertical foliation with a steep stretching lineation; followed by (2) gravitational instability and collapse of this uplifted pile with the development of a near-horizontal foliation, gravitational spreading, near-coaxial vertical shortening and consequent thrusting on the orogen margins. Correlation of inclusion trail overprinting relationships and asymmetry in porphyroblasts with foliation overprinting relationships observed in the field allows determination of where the rocks studied lie and have moved within an orogen. This information, combined with information about chemical zoning in porphyroblasts, provides details about the structural/metamorphic ( P-T-t ) paths the rocks have followed.
The ductile deformation environment in which a porphyroblast can rotate relative to geographic coordinates during orogenesis is spatially restricted in continental crust to vertical, ductile tear/transcurrent faults across which there is no component of bulk shortening or transpression.     

A second natural occurrence of yoderite

A second example of yoderite has been discovered in whiteschists from the Southern Chewore Hills of northern Zimbabwe. The mineral is pale green in colour and occurs in an equilibrium assemblage with talc+chlorite+kyanite+dravite+hematite. There is no quartz present. Recalculated microprobe analyses give a structural formula of Mg₂Al_5.7Fe_0.3Si₄O₁₈(OH)₂, similar to that obtained for the type locality at Mautia Hill, Tanzania, i.e. Mg₂Al_5.6Fe_0.4Si₄O₁₈(OH)₂. Textural relationships and relative proportions of minerals suggest that the yoderite was formed by reaction between talc, chlorite, kyanite and hematite. Experimental evidence suggests high-water-pressure metamorphic conditions at temperatures exceeding a reaction curve that extends between 13  kbar at 590  °C and 21  kbar at 650  °C. The yoderite-bearing whiteschist is associated with a 1.4  Ga dismembered ophiolite. It is proposed that this yoderite occurrence is associated with a relict subduction/suture zone.     

A propensity for n‐ω‐amino acids in thermally altered Antarctic meteorites

Abstract– Asteroids and their fragments have impacted the Earth for the last 4.5 Gyr. Carbonaceous meteorites are known to contain a wealth of indigenous organic molecules, including amino acids, which suggests that these meteorites could have been an important source of prebiotic organic material during the origins of life on Earth and possibly elsewhere. We report the detection of extraterrestrial amino acids in thermally altered type 3 CV and CO carbonaceous chondrites and ureilites recovered from Antarctica. The amino acid concentrations of the thirteen Antarctic meteorites ranged from 300 to 3200 parts‐per‐billion (ppb), generally much less abundant than in amino acid‐rich CI, CM, and CR carbonaceous chondrites that experienced much lower temperature aqueous alteration on their parent bodies. In contrast to low‐temperature aqueously altered meteorites that show complete structural diversity in amino acids formed predominantly by Strecker–cyanohydrin synthesis, the thermally altered meteorites studied here are dominated by small, straight‐chain, amine terminal (n‐ω‐amino) amino acids that are not consistent with Strecker formation. The carbon isotopic ratios of two extraterrestrial n‐ω‐amino acids measured in one of the CV chondrites (δ¹³C approximately ?25‰) are consistent with ¹³C‐depletions observed previously in hydrocarbons produced by Fischer‐Tropsch type reactions. The predominance of n‐ω‐amino acid isomers in thermally altered meteorites hints at cosmochemical mechanisms for the preferential formation and preservation of a small subset of the possible amino acids.     

Initiation and development of the Twelve Mile Bay shear zone: the low viscosity sole of a granulite nappe

Structural, microstructural and petrological data have enabled determination of the mechanical and geochemical processes involved in dynamic weakening and fabric transposition along the margins of a granulite nappe [the Parry Sound domain (PSD)] during transport to mid‐crustal levels of the Grenville Orogen. The data establish a genetic link between outcrop‐scale structures in the southern PSD and the development of the underlying Twelve Mile Bay shear zone (TMBSZ). Following granulite facies metamorphism (～11 kbar/～850 °C) in the southern PSD, the emplacement of pegmatite dykes resulted in hydration reactions within adjacent wall rocks and the development of thin (<1 m) amphibolite facies (～6.5 kbar/～700 °C) shear zones. The shear zones exhibit bulk H₂O and K₂O enrichment and oxygen isotope values similar to the adjacent pegmatites, suggesting metasomatic alteration by pegmatite‐derived fluids. Phase‐equilibrium models indicate that the destabilization of the pre‐existing pyroxene and garnet‐bearing assemblages, as observed within discrete shear zones in the southern PSD and the TMBSZ, requires H₂O‐saturated conditions at these (amphibolite facies) P–T conditions. The spacing between discrete shear zones and the depth of hydration into the adjacent wall rock are of comparable length‐scales (～metres), suggesting that this type of reworking process can be an effective means of hydrating kilometre‐scale areas of crust relatively rapidly. Furthermore, considering the well‐established effects of hydrous fluids on the creep strength of anhydrous minerals, a fracture‐initiated, localized hydration‐and‐shearing process may be an efficient mechanism for weakening strong, dry rocks (e.g. granulites) in the middle to lower orogenic crust.