美国Culberson重晶石-硫磺矿中流体包裹体的研究

Culberson自然硫-重晶石矿床位于美国德克萨斯州的Delaware油气盆地中,是北美最大的自然硫矿床。它产在晚二叠世Ochoan期的Castile组和Salado组的石灰宕夹薄层蒸发岩和有机质灰岩中,重晶石和自然硫是后生的,常交代这两个组地层中的蒸发岩和富含有机质的灰岩,并填充在古喀斯特中。流体包裹体的研究表明：有两个世代的包裹体,即成岩时和方解石后生加大和重晶石中捕获的石油包裹体和流体包裹体。按包裹体的成分和相态可分为一相液体包裹体、二相气液体包裹体和油气包裹体。研究表明,在方解石、重晶石和天青石的同一生长带中可见到含有不同气液比的流体包裹体、空的包裹体和油气包裹体,它们是在一个不混溶的环境中捕获的,因而其均一温度的测定并不可靠。流体包裹体的T_e在-18℃～-24℃之间,属于NaCl- H_2O体系,盐度为2%～10%。有许多油气包裹体,因而其成矿流体应是一个温度小于100℃的油田水．     

Seasonal variations in pore water and sediment geochemistry of littoral lake sediments (Asylum Lake, MI, USA)

Background  

Seasonal changes in pore water and sediment redox geochemistry have been observed in many near-surface sediments. Such changes have the potential to strongly influence trace metal distribution and thus create seasonal fluctuations in metal mobility and bioavailability.     

Pore-scale simulation of entrapped non-aqueous phase liquid dissolution

We investigated the dissolution of non-aqueous phase liquids (NAPLs) in a three-dimensional random sphere-pack medium using a pore-scale modeling approach to advance fundamental understanding and connect rigorously to microscale processes. Residual NAPL distributions were generated using a morphological approach and the entrapped non-wetting phase was quantitatively characterized by calculating volume, orientation, interfacial area, and shape of isolated NAPL regions. With a detailed aqueous-phase flow field obtained by a multiple-relaxation time lattice Boltzmann approach, we solved the advective–diffusive equation in the pore space using a high-resolution, adaptive-stencil finite-volume scheme and an operator-splitting algorithm. We show good agreement between the mass transfer rates predicted in the computational approach and previously published experimental observations. The pore-scale simulations presented in this work provide the first three-dimensional comparison to the considerable experimental work that has been performed to derive constitutive relations to quantify mass transfer from a residual NAPL to a flowing aqueous phase.     

Oxygen isotope ratios of organic matter in arctic lakes as a paleoclimate proxy: field and laboratory investigations

Paleoclimate research based on the stable isotopic composition of lake sediments is often hampered by the lack of preservation of suitable material for isotopic analysis. We examined organic material as a proxy for past water isotopic composition in a series of experiments. First, we cultured aquatic moss under constant illumination, temperature, and water ¹⁸O, and show that new cellulose records source water ¹⁸O precisely (r² = 0.9997). Second, we analyzed paired lakewater and vegetation samples collected from sites spanning strong climatic gradients. In field conditions, the relationship between organic ¹⁸O and water ¹⁸O is more variable, though it is still controlled by environmental water isotopic composition. However, terrestrial mosses in the arctic are often significantly enriched in ¹⁸O relative to aquatic mosses in nearby lakes due to their use of different water sources. Third, we measured ¹⁸O of cellulose extracted from disseminated sedimentary organic material. In the majority of the middle- to high-arctic lakes in this study, the ¹⁸O of disseminated sediment cellulose is greatly enriched relative to the expected values based on lakewater ¹⁸O, suggesting a significant component of terrestrial cellulose. This interpretation is supported by radiocarbon dates from a Holocene sediment core in which ¹⁴C ages of sediment cellulose are 700-5000 yrs older than the enclosing sediments. We conclude that aquatic cellulose can be used as a reliable tracer of lakewater isotope ratios, but terrestrial cellulose often dominates the sedimentary cellulose pool in places such as Baffin Island where sedimentation rates are low enough to allow the degradation of aquatic cellulose. Care must be taken when interpreting sediment cellulose ¹⁸O records where diagenesis has played a role, because terrestrial cellulose is more resistant to degradation, and therefore can predominate in environments with low organic carbon burial.     

Seasonal Influence of the Needle Rush <Emphasis Type="Italic">Juncus roemarianus</Emphasis> on Saltmarsh Pore Water Geochemistry

Previous studies have shown that saltmarsh macrophytes have a significant influence on sediment biogeochemistry, both through radial release of oxygen from roots and also via primary production and release of labile organic exudates from roots. To assess the seasonal influence of the needle rush, Juncus roemarianus, on saltmarsh sediment geochemistry, pore waters and sediments were collected from the upper 50 cm of two adjacent sites, one unvegetated and the other vegetated by Juncus roemarianus, in a Georgia saltmarsh during winter and summer. Pore waters collected at 1- to 2-cm intervals were analyzed for pH, alkalinity, dissolved phosphate, ammonium, Fe(II), Fe(III), Mn(II), sulfide, sulfate, and organic carbon. Sediments were collected at 5-cm intervals and analyzed for iron distribution in the solid phase using a two-step sequential extraction. The upper 50 cm of the sediment pore waters are mostly sulfidic during both winter and summer. The pore water and sediment geochemistry suggest organic matter degradation is coupled mostly to Fe(III) and sulfate reduction. In summer, there is greater accumulation of alkalinity, sulfide, ammonium, and phosphate in the pore waters and lower levels of ascorbate extractable Fe, which is presumed to be comprised primarily of readily reducible Fe(III) oxides, in the sediments, consistent with higher organic matter degradation rates in summer compared to winter. Lower pH, alkalinity, ammonium, and sulfide concentrations in sediments with Juncus, compared to nearby unvegetated sediments, is consistent with release of oxygen into the Juncus rhizosphere, especially during summer.     

Ar-Ar age of mylonites along the Merens Fault, central Pyrenees

Seven mylonitic samples and two coarse muscovites from the central Pyrenees have been dated by the ⁴⁰Ar-³⁹Ar method. Whole rock specimens of mylonite were cut out of thin-section chips allowing complete characterisation of mineralogy and texture. Several specimens showed rising staircase patterns in the range 50–90 Ma, with much higher ages in the highest temperature steps. This is believed to reflect mixing of argon released from micas with excess argon contained in plagioclase and released mainly at high temperatures. One biotite-quartz mylonite gave a plateau age of 93 ± 2 Ma. Other inferred mica ages are about 60–73 Ma for biotite and 50–60 Ma for muscovite; it is probable that biotite contains excess argon and that 50 Ma approximates to the cooling age in the mylonites. One coarse muscovite collected immediately below the major Mérens shear zone gave a Hercynian plateau age, while another collected within the Mérens zone gave a partially reset Hercynian age.Taken together, the data indicate that the shear zones were active in Alpine times < 100 Ma and probably about 50 Ma ago. They are believed to have formed during the early stages of Eocene compression in the Pyrenees. Deformation and resultant uplift probably terminated an important thermal event in this part of the Pyrenean basement, which may have begun at the time of the mid-Cretaceous North Pyrenean metamorphism (90–100 Ma).     

Paleohydrological implications of Holocene peatland development in northern Michigan

Sediment, pollen, and plant macrofossil stratigraphies from two small oligotrophic Chamaedaphne-Sphagnum peatlands provide data about local hydrologic changes in northern Michigan during the Holocene. Gleason Bog started about 8000 yr B.P. as a shallow pond that supported rich fen vegetation. After it was partly filled with peat and sand (about 4000 yr B.P.), the vegetation changed to oligotrophic bog. At Gates Bog paludification starting about 3800 yr B.P. caused peat accumulation over sand without an initial pond phase. The onset of peat accumulation at both sites is attributed to a rise in the water table resulting from the onset of cool and moist late Holocene climates. The water table of Gleason Bog is linked to the water level of adjacent Douglas Lake, which may have undergone a simultaneous rise. The results emphasize the individuality of hydrological conditions and hydroseral development in northern Michigan peatlands.     

The natural occurrence of hydroxide in olivine

Polarized infrared (IR) spectra of olivine single crystals from 17 different localities show a tremendous variability in both mode and abundance of hydroxide (OH) incorporation. Kimberlitic olivines contain the most total OH at an estimated concentration level of 976 H/10⁶Si, whereas olivines from basalts contain the least at 3 H/10⁶Si. Olivines of metamorphic and hydrothermal origin have widely varying concentration levels intermediate between those of basalts and kimberlites. Over 30 distinct OH absorption bands have been identified. Most of these bands are not unique to individual localities but may be found in samples from several different localities. Pleochroism is consistent among localities, but relative band intensities vary. No evidence is found for molecular H₂ in olivine. Hydrous minerals have been identified in olivine by their characteristic OH absorption bands. Serpentine is commonly found and is clearly distinguishable from intrinsic OH. Talc is present in one sample. Prominent OH bands at 3572 and 3525 cm^?1 are attributed to humite group minerals. San Carlos, Arizona, olivines annealed in the presence of H₂O develop absorption bands which are found in natural samples, however the OH absorption spectra of these annealed olivines are not identical to those of any single natural crystal. Sharp-band OH abundances in annealed samples are an order of magnitude lower than the maximum measured in natural specimens. The mechanical properties determined from these annealed olivines may not be directly applicable to mantle olivine because both the OH sites and concentrations are different.     

The provenance and crustal residence ages of British sediments in relation to palaeogeographic reconstructions

24 SmNd isotope analyses of fine-grained Phanerozoic and modern clastic sediments from Britain and Quebec are presented. In combination with published data, they have been used to calculate “crustal residence ages” (t_CR) and to assess the provenance of the British sedimentary mass. Sediments now preserved on either side of the suture formed by the closure of the Iapetus Ocean ca. 400 Ma ago were derived from isotopically distinct source regions. Sediments north of the suture are characterised by1.7 < t_CR < 2.8 Ga, whereas those to the south exhibit a smaller range and an average value of 1.6 Ga. The northern and southern source regions were most probably Laurentia and Gondwana respectively. It seems likely that a third source, perhaps Baltica, provided the lower Palaeozoic Southern Uplands succession. Sediments deposited in southern Britain after the closure of Iapetus were derived mainly from the recycling of older sediments. The tectonic rearrangements which occurred during the Phanerozoic are not reflected in the SmNd isotopic structure of the southern British sedimentary mass, suggesting that the Caledonian and Hercynian orogenies, and even the Grenville orogeny, involved minimal accretion of new mantle-derived material into the British and adjacent continental crust. SmNd analyses of fine-grained clastic sediments provide a powerful sedimentological tool for elucidating palaeogeography, clastic source areas, sediment recycling and maturity, and some aspects of sediment transport.