Gas–water–rock interactions in sedimentary basins: CO2 sequestration in the Frio Formation, Texas, USA

To investigate the potential for the geologic storage of CO₂ in saline sedimentary aquifers, 1600 ton of CO₂ were injected at 1500 m depth into a 24-m sandstone section of the Frio Formation — a regional reservoir in the US Gulf Coast. Fluid samples obtained from the injection and observation wells before, during and after CO₂ injection show a Na–Ca–Cl type brine with 93,000 mg/L TDS and near saturation of CH₄ at reservoir conditions. As injected CO₂ gas reached the observation well, results showed sharp drops in pH (6.5 to 5.7), pronounced increases in alkalinity (100 to 3000 mg/L as HCO₃) and Fe (30 to 1100 mg/L), and significant shifts in the isotopic compositions of H₂O and DIC. Geochemical modeling indicates that brine pH would have dropped lower, but for buffering by dissolution of calcite and Fe oxyhydroxides. Post-injection results show the brine gradually returning to its pre-injection composition.     

The role of buried bedrock valleys on the development of karstic aquifers in flat-lying carbonate bedrock: insights from Guelph, Ontario, Canada

A spatial relationship between high capacity municipal production wells (>5,000 m³/day), completed in a deep bedrock aquifer, and a buried bedrock valley was recognized in the city of Guelph, southwestern Ontario, Canada. Most production wells are completed in a discrete zone, ～60 m below ground surface, within flat-lying dolostones of the Silurian Amabel Formation. Thick overburden and limited subsurface data make characterization of the karstic aquifer difficult. This study integrates hydrogeologic data with models of karst formation, deriving a conceptual model of porosity development as it relates to valley incision. Bedrock valley incision likely occurred prior to the early Wisconsinan age (>60–75 ka). Incision created steep hydraulic gradients within the flat-lying bedrock, and provided the driving force required to integrate regional groundwater flow into karst conduits that drained at the base of the valley. Dissolution in production zone dolostones was favoured over dissolution in shallower bedrock due to abundant bedding plane partings and fossiliferous facies with high intercrystalline porosity. Burial of the valley during subsequent ice advances reduced the valley’s hydraulic influence and the efficacy of the flow system to cause dissolution. The high capacity municipal wells near the buried bedrock valley tap into the now dormant karst aquifer system.     

High-temperature hydrothermal alteration of the Boehls Butte anorthosite: origin of a bimodal plagioclase assemblage

The Boehls Butte anorthosite consists predominantly of an unusual bimodal assemblage of andesine and bytownite–anorthite. Oxygen isotope compositions of the anorthosite were profoundly altered by high temperature, retrograde interaction with meteoric-hydrothermal fluids that varied in composition from isotopically evolved to nearly pristine meteoric water. Oxygen isotope ratios of bulk plagioclase separates are in the range +7.0 to −6.2‰ V-SMOW, however, secondary ion mass spectrometry indicates spot-sized isotope values as low as −16‰. Typical inter- and intra-plagioclase grain variability is 3–6‰, and extreme heterogeneity of up to 20‰ is noted in a few samples. High-temperature hydrothermal alteration of intermediate plagioclase is proposed to explain the origin of bytownite–anorthite in the anorthosite and creation of its unusual bimodal plagioclase assemblage. The anorthite-forming reaction created retrograde reaction-enhanced permeability which, together with rapid decompression, extension, and unroofing of the anorthosite complex, helped to accommodated influx of significant volumes of meteoric-hydrothermal fluids into the anorthosite.     

Hypervelocity capture of particles in aerogel: Dependence on aerogel properties

Capture of high-speed (hypervelocity) particles in aerogel at ambient temperatures of 175-763 K is reported. This extends previous work which has mostly focussed on conducting experiments at ambient laboratory temperatures, even though aerogels are intended for use in cosmic dust capture cells in space environments which may experience a range of temperatures (e.g., the NASA Stardust mission which collected dust at 1.81 AU and putative Mars atmospheric sampling missions). No significant change in track length (normalised to impactor size) was found over the range 175-600 K, although at 763 K a significant reduction (30%) was found. By contrast, entrance hole diameter remained constant only up to 400 K, above this sudden changes of up to 50% were observed. Experiments were also carried out at normal laboratory temperature using a wide range of aerogel densities and particle sizes. It was found that track length normalised to particle size varies inversely with aerogel density. This is a power law dependence and not linear as previously reported, with longer tracks at lower densities. Glass projectiles (up to 100 μm size) were found to undergo a variety of degrees of damage during capture. In addition to the well known acquisition of a coating (partial or complete) of molten aerogel the mechanical damage includes pitting and meridian fractures. Larger (500 μm diameter) stainless steel spheres also showed damage during capture. In this case melting and ablation occurs, suggesting surficial temperatures during impact in excess of 1400 °C. The response of the aerogel itself to passage of particles through it is reported. The presence of fan-like fractures around the tracks is attributed to cone cracking similar to that in glasses of normal density, with the difference that here it is a repetitive process as the particles pass through the aerogel.     

Variation in the life-history traits of a Schilbid catfish,Clupisoma garua (Hamilton, 1822) in the coastal waters of southern Bangladesh

For the first time,the present study reports the life-history traits,comprising length-frequency distribution(LFD),sex ratio(SR),length-weight relationships(LWRs),condition factors(CFs),and relative growth(W_R),of Clupisoma garua in the coastal waters of Bangladesh.A total of 150 specimens ranging from 8.60 to 25.20 cm total length(TL)and 4.26 to 128.80 g body weight(BW)were collected using traditional fishing gear from August 2013 to July 2014.The overall sex ratio of males to females in the study did not dif fer significantly from the expected value of 1:1(χ~2=0.96,P0.05)but there were significant sex differences(P0.05)in the intercepts and slopes of graphs characterizing traits in C.garua.The calculated bvalues for the LWRs were 2.955,2.893 and 2.927 for males,females and combined sexes,respectively,and there was negative allometric growth in all cases(b3).The condition factors(K_A,K_F,K_R)and relative growth(W R)also did not differ significantly(P0.05)between the sexes.This study provides a useful tool for fi shery specialists to evaluate the relative condition of fish and to initiate early management strategies and regulations for the sustainable management of the remaining stocks of this species in the entire coastal region of southern Bangladesh.     

松辽盆地早白垩世火山岩地球化学特征及其构造意义

松辽盆地早白垩世发育基性岩类的橄榄玄武岩、玄武岩,中性岩类的玄武安山岩、安山岩、粗安岩,酸性岩类的粗面岩、粗面英安岩、英安岩和流纹岩。早白垩世火山岩都具有大离子亲石元素(LILE)、轻稀土元素(LREE)相对富集的特征,并具有较低的(~(87)Sr/~(86)Sr)_i值和较高的(~(143)Nd/~(144)Nd)_i值。基性岩类Ce/Nb=1.92～8.31,Th/Nb=0.08～0.44,(~(87)Sr/~(86)Sr)_i=0.7031～0.7047,ε_(Nd)(t)=+1.7～+5.2;中性岩类Ce/Nb=3.70～15.80,Th/Nb=0.34～2.58,(~(87)Sr/~(86)Sr)_i=0.7040～0.7054,ε_(Nd)(t)=0～+3.0;酸性岩类Ce/Nb=4.29～15.80,Th/Nb=0.11～1.02,(~(87)Sr/~(86)Sr)_i=0.7038～0.7066,ε_(Nd)(t)=+1.0～+3.3。基性岩类岩浆主要来自被富集了的亏损地幔源的部分熔融,受混染程度很小;中性岩类岩浆源于年轻地壳组分被来自亏损地幔岩浆的再次部分熔融;酸性岩类浆岩可能主要来自源于亏损地幔的初生地壳部分熔融,并受到了上地壳的混染。晚侏罗世-早白垩世,由于蒙古-鄂霍次克洋关闭引发强烈的挤压造山后,发生的岩石圈拆沉作用致使来自亏损地幔的岩浆熔融上涌导致岩石圈主动伸展拉张,地表则表现出大规模的裂谷断陷作用和大范围的火山活动。这个阶段的伸展拉张以主动拉张为主。     

Origins of cold-wet-oxidizing to hot-dry-reducing rhyolite magma cycles and distribution in the Taupo Volcanic Zone, New Zealand

Slab-derived aqueous fluid components (Ba, Cl) correlate well with oxygen fugacity, and other well-defined characteristics of silicic magmas in the Taupo Volcanic Zone (TVZ) between a cold-wet-oxidizing magma type [R1: amphibole ± biotite; high Sr, low Zr and FeO*/MgO, depleted middle rare-earth elements (MREE)] and a hot-dry-reducing magma type (R2: orthopyroxene ± clinopyroxene; low Sr, high Zr, and FeO*/MgO, less depleted MREE). Oxygen fugacity was obtained from analysis of Fe–Ti oxides and ranges between −0.04 and +2.1 log units (ΔQFM, where QFM = quartz + fayalite + magnetite buffer) and is positively correlated with the bulk-rock Ba/La ratio, indicating that slab-derived fluid is the oxidizing agent in the rhyolites. Chlorine contents in hornblende also correlate with the bulk-rock Ba/La ratio. Hence, high-fluid flux typically correlates with the R1 and low-fluid flux with R2 rhyolite magma types. A geochemical evolution and distribution can be tracked in time and space throughout the central region of the TVZ from 550 ka to present and has revealed two distinct magmatic cycles that vary in length. The first cycle included widespread R1 type magmatism across the central TVZ beginning ca. 550 ka and was directly associated with previously unreported dome-building and ignimbrite-forming volcanism, and led to a voluminous (>3,000 km³) ignimbrite ‘flare-up’ between ca. 340 and 240 ka. The second cycle began roughly 180 ka, erupting ca. 800 km³ of magma, and continues to the present. The duration, rate, and composition of magma production within these cycles appears to be governed by the flux of fluid released from the subducting slab, while the distribution of magmas may be governed more by extension along the central rift axis. Shorter cycles have also been identified and are unrelated to subduction processes, but occur following large, caldera-forming events.