Composition,oxygen isotope geochemistry and origin of smectite in the metalliferous sediments of the Bauer Deep,southeast Pacific

The sediments of the Bauer Deep, an open ocean basin situated on the northwest Nazca Plate in the southeast Pacific, constitute a regional metalliferous deposit dominated by authigenic smectite.Two 2-metre long cores from the Bauer Deep were examined to investigate the nature and origin of the smectite.Infra-red and Mossbauer spectroscopy and wet chemical analysis (LiBO₂ fusion) of isolated smectite, indicate the mineral is a Mg-rich, Al-rich nontronite. Oxygen isotopic compositions for isolated smectite are uniform and translate to a non-hydrothermal temperature of formation of about 3°C. SEM observations show an abundance of well-preserved biogenic opal in surface and near surface sediment but postburial dissolution and transformation of this phase to smectite is evident at depth.Smectite formation is the result of interaction between iron oxyhydroxide, ponded in the Bauer Deep following a hydrothermal origin at the adjacent East Pacific Rise, and biogenic opal. A reaction mechanism is proposed.Regional factors control smectite formation. In particular, formation is inhibited in areas of CaCO₃ accumulation (topographic elevations) but favoured in areas of oxyhydroxide and opal ponding (topographic depressions).     

Distribution and mode of occurrence of zinc and lead in glacial soils

The distribution and mode of occurrence of zinc and lead have been examined in glacial soils developed over a complex Precambrian marble-paragneiss terrain in the Adirondack Mountains of New York. Based on distribution within the soil profiles, zinc is enriched in the B₁ horizon of soils sampled over marble and lead is generally enriched in the A horizon, particularly in soils developed over paragneiss. Contrast is calculated using

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, where is the mean of n_A anomalous and n_B background samples, and S_p is the pooled standard deviation) for zinc, lead and cold-extractable heavy metals in soils sampled over marble and paragneiss. The t-values indicate that the B₁, soil horizon is the most suitable for sampling on a regular basis, even though lead is most concentrated in the A horizon.The distribution of zinc and lead among exchangeable, organic, iron-manganese oxide, clay, silt and sand fractions of B₁ horizons from two anomalous and one background soil indicates that both zinc and lead are tied up principally in iron and manganese oxides. The anomalous samples exhibit zinc enrichment in the Fe-oxide digestion and high Mn/Fe ratios for the Mn-oxide digestion (as well as the total analysis). In terms of total contribution to the sample, significant proportions of zinc in the clastic fraction can be attributed to zinc substitution into clays plus the ineffective removal of Fe-oxides by the ammonium oxalate extraction procedure. Lead, on the other hand, occurs in significant concentrations in clay, silt and sand as well as Fe- and Mn-oxides, probably as a trace constituent in feldspars or adsorbed onto clay surfaces.     

Origin of dacites of Taupo Volcanic Zone, New Zealand

Dacites form a relatively small proportion of lavas in the Taupo Volcanic Zone, New Zealand (5km³), and occur mainly on the eastern side. In this paper their origin is considered in terms of three processes: (a) partial melting of crustal rocks; (b) fractional crystallisation of basalt and andesite; and (c) sub-surface mixing of basic and acid magma. Modelling techniques are used to calculate the most acceptable degree of fractional crystallisation and magma mixing to fit major-element data, and these values are used to compare calculated and observed trace-element values. The success or failure of the model is determined by the closeness of the two sets of values. For partial-melt models, trace-element values alone are calculated by the batch-melting equation.Results indicate that White Island dacite can best be modelled by fractional crystallisation; Manawahe by fractional crystallisation plus limited crustal contamination; Maungaongaonga by partial melting of Western Basement greywacke, and Tauhara by partial melting of this greywacke together with minor mixing with a more basic magma. Results from Parekauau and Horohoro indicate that these lavas are unlikely to have formed by any of the processes examined.     

Chemical and isotopic investigation of warm springs associated with normal faults in Utah

Thermal springs associated with normal faults in Utah have been analyzed for major cations and anions, and oxygen and hydrogen isotopes. Springs with measured temperatures averaging greater than 40°C are characterized by Na + K- and SO₄ + Cl-rich waters containing 10³ to 10⁴ mg/l of dissolved solids. Lower temperature springs, averaging less than 40°C, are more enriched in Ca + Mg relative to Na + K. Chemical variations monitored through time in selected thermal springs are probably produced by mixing with non-thermal waters. During the summer months at times of maximum flow, selected hot springs exhibit their highest temperatures and maximum enrichments in most chemical constituents.Cation ratios and silica concentrations remain relatively constant through time for selected Utah thermal springs assuring the applicability of the geothermometer calculations regardless of the time of year. Geothermometer calculations utilizing either the quartz (no steam loss), chalcedony or Mg-corrected Na/K/Ca methods indicate that most thermal springs in Utah associated with normal faults have subsurface temperatures in the range of 25 to less than 120°C. This temperature range suggests fluid circulation is restricted to depths less than about three kilometers assuming an average thermal gradient of about 40°C/km.Thermodynamic calculations suggest that most thermal springs are oversaturated with respect to calcite, quartz, pyrophyllite, (Fe, Mg)-montmorillonite, microcline and hematite, and undersaturated with respect to anhydrite, gypsum, fluorite and anorthite. Chalcedony and cristobalite appear to be the only phases consistently at or near saturation in most waters. Theoretical evaluation of mixing on mineral saturation trends indicates that anhydrite and calcite become increasingly more undersaturated as cold, dilute groundwater mixes with a hot (150°C), NaCl-rich fluid. The evolution of these thermal waters issuing from faults appears to be one involving the dissolution of silicates such as feldspars and micas by CO₂-enriched groundwaters that become more reactive with increasing temperature and/or time. Solution compositions plotted on mineral equilibrium diagrams trend from product phases such as kaolinite or montmorillonite toward reactant phases dominated by alkali feldspars.Isotopic compositions indicate that these springs are of local surface origin, either meteoric (low TDS, < 5000 mg/l) or connate ground water (high TDS, > 5000 mg/l). Deviations from the meteoric water line are the result of rock-water isotopic exchange, mixing or evaporation. Fluid source regions and residence times of selected thermal spring systems (Red Hill, Thermo) have been evaluated through the use of a σ D-contour map of central and western Utah. Ages for waters in these areas range from about 13 years to over 500 years. These estimates are comparable to those made for low-temperature hydrothermal systems in Iceland.     

Post-collapse volcanic history of calderas on a composite volcano: an example from Roccamonfina,southern Italy

Roccamonfina, part of the Roman Potassic Volcanic Province, is an example of a composite volcano with a complex history of caldera development. The main caldera truncates a cone constructed predominantly of this caldera may have been associated with one of the ignimbritic eruptions of the Brown Leucitic Tuff (BLT) around 385 000 yr BP. The Campagnola Tuff, the youngest ignimbrite of the BLT, however, drapes the caldera margin and must postdate at least the initial stages of collapse. During the subsequent history of the caldera there were several major explosive eruptions. The largest of these was that of the Galluccio Tuff at about 300 000 yr BP. It is likely that there was further collapse within the main caldera associated with these eruptions. It is of note that despite these subsequent major explosive eruptions later collapse occurred within the confines of the main caldera. Between eruptions caldera lakes developed producing numerous lacustrine beds within the caldera fill. Extensive phases of phreatomagmatic activity generated thick sequences of pyroclastic surge and fall deposits. Activity within the main caldera ended with the growth of a large complex of basaltic trachyandestite lava domes around 150 000 yr BP. Early in the history of Roccamonfina sector collapse on the northern flank of the volcano formed the northern caldera. One of the youngest major events on Roccamonfina occurred at the head of this northern caldera with explosive activity producing the Conca Ignimbrite and associated caldera. There is no evidence that there was any linkage in the plumbing systems that fed eruptions in the main and northern calderas.     

Electrodynamic heating and movement of the thermosphere

The theory of dissipation of ionospheric electric currents is extended to include viscosity. In a steady state (i.e. usually above about 140 km altitude) the joule plus viscous heating may be calculated by μ∇²v. E × B/B². At lower altitudes where viscosity may, in some circumstances, be relatively unimportant the joule dissipation is calculated by the usual formula j. (E + v × B). In a prevalent model of the auroral electrojets it is found that the joule heating can be much more intense outside auroral forms than within them. Heating due to auroral electrojets cause a semi-annual variation in the thermosphere. Movement caused by auroral electric fields make a contribution to the super-rotation of the midlatitude upper atmosphere. Random electric fields lead to an eddy ‘viscosity’ or ‘exchange coefficientrs in the upper thermosphere of magnitude ρE_R²/B³t_R²|∇E|. where t_R is the correlation time of the random component of electric fields E_R and ρ is air density. Theoretical conditions for significant heating by field-aligned currents are derived.     

Distances from auroral zones to the magnetic and geographic equators

Distance from auroral zone is a fundamental parameter in studies of disturbances produced in the thermosphere and ionosphere through the action of the solar wind. Calculations showing the great variation of the distances of the auroral “zones” from the magnetic equator and geographic equator are presented in diagrams. An auroral zone proximity index is proposed for use in correlative studies of upper atmosphere and of ionospheric disturbances.