Dissolution mechanisms of water in depolymerized silicate melts: Constraints from H and Si NMR spectroscopy and ab initio calculations

Dissolution of water in magmas significantly affects phase relations and physical properties. To shed new light on the this issue, we have applied ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopic techniques to hydrous silicate glasses (quenched melts) in the CaO-MgO-SiO₂ (CMS), Na₂O-SiO₂, Na₂O-CaO-SiO₂ and Li₂O-SiO₂ systems. We have also carried out ab initio molecular orbital calculations on representative clusters to gain insight into the experimental results.The most prominent result is the identification of a major peak at ∼1.1 to 1.7 ppm in the ¹H MAS NMR spectra for all the hydrous CMS glasses. On the basis of experimental NMR data for crystalline phases and ab initio calculation results, this peak can be unambiguously attributed to (Ca,Mg)OH groups. Such OH groups, like free oxygens, are only linked to metal cations, but not part of the silicate network, and are thus referred to as free hydroxyls in the paper. This represents the first direct evidence for a substantial proportion (∼13∼29%) of the dissolved water as free hydroxyl groups in quenched hydrous silicate melts. We have found that free hydroxyls are favored by (1) more depolymerized melts and (2) network-modifying cations of higher field strength (Z/R²: Z: charge, R: cation-oxygen bond length) in the order Mg > Ca > Na. Their formation is expected to cause an increase in the melt polymerization, contrary to the effect of SiOH formation. The ²⁹Si MAS NMR results are consistent with such an interpretation. This water dissolution mechanism could be particularly important for ultramafic and mafic magmas.The ¹H MAS NMR spectra for glasses of all the studied compositions contain peaks in the 4 to 17 ppm region, attributable to SiOH of a range of strength of hydrogen bonding and molecular H₂O. The relative population of SiOH with strong hydrogen bonding grows with decreasing field strength of the network-modifying cations. Ab initio calculations confirmed that this trend largely reflects hydrogen bonding with nonbridging oxygens.     

长沙现代大厦复合土钉墙基坑支护方案设计

分析了长沙现代大厦基坑的岩土工程条件及周边环境条件，在此基础上对几种基坑支护方案进行了分析论证，并对所采用的复合土钉墙支护方案进行了设计计算。     

MgSO4-NaOH-H2O四元交互体系在200℃水热条件下相互作用的动力学研究

利用七水硫酸镁和氢氧化镁,研究了在200℃水热条件下合成产物的物相及其随时间的变化机制。     

基于PRS的遥感图像地物信息提取模型

点源理论(PRS)是一种面向应用需求的集中信息处理方式。不同尺度、不同分辨率的点都是一定的综合信息场,是客观世界的真实反映。本文在数字图像处理过程中引入点源理论,探讨针对地物空间信息应用服务的遥感信息分析和处理模型,讨论基于点源的图像构造、知识构造及地物模型建造过程,给出基于点源的遥感图像地物提取流程。     

金坛市开发区的数字影像测图

为完善数字化测图功能，通过全数字摄影测量系统(VirtuoZo)的数字影像测图模块(IGS)在金坛市开发区1：500测区中的应用，总结提高测图精度和速度的体会。     

基于多传感器观测信息抗差估计的自适应融合导航

首先利用抗差估计原理构造了基于观测信息的融合导航解，再利用动力学模型信息进行自适应融合，最后利用模拟算例进行多种方案的计算与比较。     

基于受限汉语的GIS路径重建研究

主要研究基于自然语言 (汉语 )的GIS路径重建问题 ,通过分析带有路径表述信息的汉语文本 ,建立了汉语的NLRP句法模型 ,它是由带有空间语义的动作以及作为动作对象的地理要素构成的集合。考虑到自然语言理解实现的需求 ,论文基于NLRP句法模型定义了受限汉语的NLRP文法 ,在此基础上 ,描述了路径重建算法PRA ,并探讨了算法实现中由于空间认知原因带来的不确定性问题以及其解决方案。最后 ,基于该算法进行了相关实例研究 ,从而验证了该算法的正确性     

基于方差分量估计的自适应融合导航

多源传感器观测信息的精度一般不一致,利用方差分量估计理论可以合理地顾及各传感器观测信息在融合导航解中的权比.首先给出基于多源观测信息的融合导航解算模式,进而基于方差分量估计讨论了各传感器观测信息在融合导航解中的合理平衡问题,然后应用自适应因子顾及动力学模型预报信息的贡献,给出了计算过程,并利用模拟数据进行了试算与比较.     

Estimation of ocean primary productivity and its spatio-temporal variation mechanism for East China Sea based on VGPM model

According to calculation results of ocean chlorophyll concentration based on SeaWiFS data by SeaBAM model and synchronous ship-measured data, this research set up an improved model for CaseⅠand CaseⅡwater bodies respectively. The monthly chlorophyll distribution in the East China Sea in 1998 was obtained from this improved model on calculation results of SeaBAM. The euphotic depth distribution in 1998 in the East China Sea is calculated by using remote sensing data of K490 from SeaWiFS according to the relation between the euphotic depth and the oceanic diffuse attenuation coefficient. With data of ocean chlorophyll concentration, euphotic depth, ocean surface photosynthetic available radiation (PAR), daily photoperiod and optimal rate of daily carbon fixation within a water column, the monthly and annual primary productivity spatio-temporal distributions in the East China Sea in 1998 were obtained based on VGPM model. Based on analysis of those distributions, the conclusion can be drawn that there is a clear bimodality character of primary productivity in the monthly distribution in the East China Sea. In detail, the monthly distribution of primary productivity stays the lowest level in winter and rises rapidly to the peak in spring. It gets down a little in summer, and gets up a little in autumn. The daily average of primary productivity in the whole East China Sea is 560.03 mg/m2/d, which is far higher than the average of subtropical ocean areas. The annual average of primary productivity is 236.95 g/m2/a. The research on the seasonal variety mechanism of primary productivity shows that several factors that affect the spatio-temporal distribution may include the chlorophyll concentration distribution, temperature condition, the Yangtze River diluted water variety, the euphotic depth, ocean current variety, etc. But the main influencing factors may be different in each local sea area.     

The causes and environmental effects of land use conversion during agricultural restructuring in Northeast China

During the last decade of the 20th century, extensive conversion in agricultural land use took place in Northeast China. The goal of this study is to ascertain its spatial distribution and regional differentiation, determine its causes, and analyze its environmental impact. Especially we attempt to elucidate how institutional constraints have facilitated the change at a time of agrarian restructuring when newly emerging free market was hybridized with the former planned economy. Information on six categories of land use was mapped from interpretation of Landsat TM images recorded in 1990, 1995 and 2000. Most of land use changes took place during the first half of the decade, coinciding with abrupt and chaotic changes in government directives. Farmland was changed mainly to woodland, water body and built-up areas while woodland and grassland were converted chiefly to farmland. Spatially, the change from farmland to woodland was restricted to the west of the study area. The change from grassland to farmland took place in the grazing and farming interlocked west. These chaotic and occasionally conflicting changes were largely caused by lack of stability and consistency in agricultural land use policies promulgated. They have exerted adverse impacts on the local environment, including land degradation, increased flooding, and modified climate regime.