Mid-infrared lightcurve of Vesta

We present a thermal mid-infrared lightcurve of Asteroid 4 Vesta and use this to infer variations in thermophysical properties over the surface. Vesta was observed over three nights during the May 2007 opposition with the Infrared Telescope Facility on Mauna Kea. Mid-infrared observations are compared to a model based on the Standard Thermal Model which is draped over a Vesta shape model derived from Hubble Space Telescope observations.A visible lightcurve with similar aspect was used to estimate the albedo as Vesta rotates. Shape and albedo can explain some of the features observed in the mid-infrared lightcurve. However, variations in the thermophysical properties, such as the “beaming parameter,” over Vesta’s surface are required to completely explain the observations.In order to match the mid-infrared magnitudes observed of Vesta, a beaming parameter of ∼0.862 is required which is higher than other Main Belt Asteroids such as Ceres and Pallas (0.756), indicating a smoother and/or rockier surface on Vesta. Variations in the beaming parameter with longitude are invoked to reproduce the observed thermal variations. Surface materials with relatively high beaming values, indicating a smoother and/or rockier surface, in the eastern hemisphere of Vesta coincide with locations where impact excavations may have produced surfaces that are younger and brighter relative to the western hemisphere.     

A voluntary reduction in the commercial catch of rock lobster (Jasus edwardsii) in a New Zealand fishery

We describe the development and application of a management procedure (decision rule) that resulted in a voluntary reduction in the commercial catch of spiny rock lobster (Jasus edwardsii) in the lower east coast of North Island of New Zealand. The management procedure was developed from an accepted assessment of the CRA 4 (Wellington‐Hawke's Bay) fishery, which used an integrated length‐based assessment model fitted to commercial fishery catch‐per‐unit‐effort (CPUE) biomass indices, commercial length‐frequency data, and tag‐recapture data. The assessment model had been Bayesian, and used the joint posterior distribution of parameters to predict the effect of 384 alternative harvest control rules on the future size of the CRA 4 stock. The harvest control rules all used CPUE as their input, and generated annual changes in catch, which were then simulated by the population dynamics of the operating model. Uncertainty was added to evaluations through observation error, added to the simulated CPUE observations, and stochastic serial auto‐correlation variation in recruitment. We describe how this management procedure was used to effect a voluntary reduction in catch to address the problem of a rapidly declining population.     

Application of implicit sub-time stepping to simulate flow and transport in fractured porous media

In general, the accuracy of numerical simulations is determined by spatial and temporal discretization levels. In fractured porous media, the time step size is a key factor in controlling the solution accuracy for a given spatial discretization. If the time step size is restricted by the relatively rapid responses in the fracture domain to maintain an acceptable level of accuracy in the entire simulation domain, the matrix tends to be temporally over-discretized. Implicit sub-time stepping applies smaller sub-time steps only to the sub-domain where the accuracy requirements are less tolerant and is most suitable for problems where the response is high in only a small portion of the domain, such as within and near the fractures in fractured porous media. It is demonstrated with illustrative examples that implicit sub-time stepping can significantly improve the simulation efficiency with minimal loss in accuracy when simulating flow and transport in fractured porous media. The methodology is successfully applied to density-dependent flow and transport simulations in a Canadian Shield environment, where the flow and transport is dominated by discrete, highly conductive fracture zones.     

A generalized transformation approach for simulating steady-state variably-saturated subsurface flow

A numerical method is proposed to accurately and efficiently compute a direct steady-state solution of the nonlinear Richards equation. In the proposed method, the Kirchhoff integral transformation and a complementary transformation are applied to the governing equation in order to separate the nonlinear hyperbolic characteristic from the linear parabolic part. The separation allows the transformed governing equation to be applied to partially- to fully-saturated systems with arbitrary constitutive relations between primary (pressure head) and secondary variables (relative permeability). The transformed governing equation is then discretized with control volume finite difference/finite element approximations, followed by inverse transformation. The approach is compared to analytical and other numerical approaches for variably-saturated flow in 1-D and 3-D domains. The results clearly demonstrate that the approach is not only more computationally efficient but also more accurate than traditional numerical solutions. The approach is also applied to an example flow problem involving a regional-scale variably-saturated heterogeneous system, where the vadose zone is up to 1 km thick. The performance, stability, and effectiveness of the transform approach is exemplified for this complex heterogeneous example, which is typical of many problems encountered in the field. It is shown that computational performance can be enhanced by several orders of magnitude with the described integral transformation approach.     

自适应转换波炮域偏移方法的研究与应用

抛开常规的转换点位置估计及极性校正,把检波点作为虚拟震源,利用单程波方程实现转换波记录的炮域偏移处理.由于该方法具有无需寻找转换点位置和进行极性校正的自适应特性,尤其适合于复杂构造转换波记录成像,并且在整个偏移处理流程中减少了估算转换点位置这一环节,有利于偏移精度的进一步提高,同时提高了运算效率.理论模型及实际资料的处理效果论证了该方法的正确性和有效性.     

粤北笋洞花岗岩的形成时代、地球化学特征与成因

笋洞花岗岩体是粤北贵东复式花岗岩体的一个重要组成部分。锆石U-Pb年龄为189.1±0.7Ma,是燕山早期岩浆活动产物。该岩体的主要元素显示富硅、富碱、强过铝质和低 CaO/Na_2O比值等特征;微量元素方面,富集Rb,Th,U,Ce,Sm,Y,亏损 Ba,Sr,P,Ti;LREE轻微富集(LREE/HREE=6.6～8.8,(La/Yb)_N=6.44～10.74),Eu亏损明显(δEu=0.14～0.31);它具有低的ε_(Nd)(t)(-11.4～-9.3),高的δ~(18)O(10.2～12.7‰)、(~(87)Sr/~(86)Sr);(0.72949～0.74923)、~(206)Pb/~(204)Pb(18.180～18.488)、~(207)Pb/~(204)Pb(15.655～15.661)和古老的Nd模式年龄(1762～1933Ma)。上述这些特征表明,笋洞岩体属于典型的壳源型花岗岩,是在地壳伸展-减薄的构造背景下,通过以泥质成分为主的古-中元古代变质沉积岩部分熔融的方式形成。     

TritonX-100－5-Br-PADAP光度法测定铜和镍

研究了非离子型表面活性剂Ｔｒｉｔｏｎ Ｘ－ １００ 存在下,用５ － Ｂｒ － ＰＡＤＡＰ 光度法测定铜、镍的方法。结果表明：在ｐＨ９ ．０ 的硼砂缓冲介质中,５ － Ｂｒ － ＰＡＤＡＰ 与铜和镍生成紫红色络合物,λＣｕｍ ａｘ ＝ ５７５ ｎｍ ,εＣｕ ＝ １ ．０４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ ;λＮｉｍ ａｘ ＝ ５７５ ｎｍ ,εＮｉ ＝ １ ．１４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ 。铜和镍的质量浓度分别在０ ～５６０ μｇ／ Ｌ和０ ～４４０ μｇ／ Ｌ符合比尔定律。加入六偏磷酸钠后,由于偏磷酸镍的形成,镍不再与５ － Ｂｒ － ＰＡＤＡＰ 显色,可通过铜及铜镍总量的测定,计算出镍的含量。用该方法实测了钢样中铜和镍的含量,结果与推荐值相符,对铜和镍５ 次测定的ＲＳＤ均小于５ ％ 。     

Dawn Mission to Vesta and Ceres

The initial exploration of any planetary object requires a careful mission design guided by our knowledge of that object as gained by terrestrial observers. This process is very evident in the development of the Dawn mission to the minor planets 1 Ceres and 4 Vesta. This mission was designed to verify the basaltic nature of Vesta inferred both from its reflectance spectrum and from the composition of the howardite, eucrite and diogenite meteorites believed to have originated on Vesta. Hubble Space Telescope observations have determined Vesta’s size and shape, which, together with masses inferred from gravitational perturbations, have provided estimates of its density. These investigations have enabled the Dawn team to choose the appropriate instrumentation and to design its orbital operations at Vesta. Until recently Ceres has remained more of an enigma. Adaptive-optics and HST observations now have provided data from which we can begin to confidently plan the mission. These observations reveal a rotationally symmetric body with little surface relief, an ultraviolet bright point that can be used as a control point for determining the pole and anchoring a geographic coordinate system. They also reveal albedo and color variations that provide tantalizing hints of surface processes.     

Photometric mapping of Asteroid (4) Vesta’s southern hemisphere with Hubble Space Telescope

We present the surface mapping of the southern hemisphere of Asteroid (4) Vesta obtained from Hubble Space Telescope (HST). From 105 images of Vesta through four filters in the wavelengths best to characterize the 1-μm pyroxene band, we constructed albedo and color-ratio maps of Vesta. These new maps cover latitudes −50° to +20°. The southern hemisphere of Vesta displays more diverse albedo and color features than the northern hemisphere, with about 15 new albedo and color features identified. The overall longitudinal albedo and color variations in the southern hemisphere are comparable with that of the northern hemisphere, with a range of about ±20% and ±10%, respectively. The eastern hemisphere is brighter and displays more diogenitic minerals than the western hemisphere. Correlations between 1-μm band depth and band width, as well as between 1-μm band depth and albedo, are present on a global scale, attributed to pyroxene composition variations. The lack of correlations between albedo and the spectral slope indicates the absence of globalized space weathering. The lack of a global correlation between 1-μm band depth and topography suggests that the surface composition of Vesta is not completely controlled by a single impact. The distribution of compositional variation on Vesta suggests a possible large impact basin. Evidence of space weathering is found in regions, including the bright rim of the south-pole crater where the steepest gravitational slope on Vesta is, and a dark area near a gravitationally flat area. We propose to divide the surface of Vesta into six geological units different from the background according to their 1-μm absorption features and spectral slopes, including two eucrite-rich units, a low-Ca eucrite unit, a diogenite-rich unit, a space weathered unit, and a freshly exposed unit. No evidence of olivine-rich area is present in these data.     

Calculated trends of oh infrared stretching vibrations with composition and structure in aluminosilicate molecules

Ab initio, molecular orbital calculations have been performed on a variety of hypothetical aluminosilicate molecules to investigate relationships among composition, structure, and infrared spectra of OH. Vibrational analyses of the full-optimized molecular geometries at the 3–21G^** level were performed with Gaussian 92 to determine theoretical infrared spectra. Theoretical infrared OH frequencies, ν(OH), shift 10 to 100 cm^?1 with ionic substitutions. The inverse correlation of theoretical infrared OH intensities with OH stretching frequencies in these aluminosilicate molecules is similar to that observed for aluminosilicate glasses (Paterson 1982). O-H bond lengths, H-bond distances, and H?nd angles correlate with frequency. The dominant factor affecting ν(OH) is the H-bond distance, if this distance is less than 2 Å. Beyond H-bond distances of 2 Å, structural and compositional effects exert competitive influences on ν(OH).