Persistent organic pollutants (POPs) in a small, herbivorous, arctic marine zooplankton (Calanus hyperboreus): trends from April to July and the influence of lipids and trophic transfer

Samples of Calanus hyperboreus, a herbivorous copepod, were collected (n = 20) between April and July 1998, and water samples (n = 6) were collected in May 1998, in the Northwater Polynya (NOW) to examine persistent organic pollutants (POPs) in a high Arctic marine zooplankton. Lipid content (dry weight) doubled, water content (r2 = 0.88) and delta15N (r2 = 0.54) significantly decreased, and delta13C significantly increased (r2 = 0.30) in the C. hyperboreus over the collection period allowing an examination of the role of these variables in POP dynamics in this small pelagic zooplankton. The rank and concentrations of POP groups in C. hyperboreus over the entire sampling was sum of PCB (30.1 +/- 4.03 ng/g, dry weight) > sum of HCH (11.8 +/- 3.23) > sum of DDT (4.74 +/- 0.74), sum of CHLOR (4.44 +/- 1.0) > sum of CIBz (2.42 +/- 0.18), although these rankings varied considerably over the summer. The alpha- and gamma-HCH and lower chlorinated PCB congeners were the most common POPs in C. hyperboreus. The relationship between bioconcentration factor (BCF) and octanol-water partition coefficient (Kow) observed for the C. hyperboreus was linear and near 1:1 (slope = 0.72) for POPs with a log Kow between 3 and 6 but curvilinear when hydrophobic POPs (log Kow > 6) were included. Concentrations of sum of HCH. Sum of CHLOR and sum of CIBz increased over the sampling period, but no change in sum of PCB or sum of DDT was observed. After removing the effects of time, the variables lipid content, water content, delta15N and delta13C did not describe POP concentrations in C. hyperboreus. These results suggest that hydrophobic POP (log Kow = 3.86.0) concentrations in zooplankton are likely to reflect water concentrations and that POPs do not biomagnify in C. hyperboreus or likely in other small, herbivorous zooplankton.     

Radar determination of the spatial structure of hydraulic conductivity

Spatial variability of hydraulic conductivity exerts a predominant control on the flow of fluid through porous media. Heterogeneities influence advective pathways, hydrodynamic dispersion, and density-dependent dispersion; they are, therefore, a key concern for studies of ground water resource development, contaminant transport, and reservoir engineering. Ground-penetrating radar contributes to the remote, geophysical characterization of the macroscale variability of natural porous media. On a controlled excavation of a glacial-fluvial sand and gravel deposit in the Fanshawe Delta area (Ontario, Canada), the hydraulic conductivity field of a 45 x 3 m vertical exposure was characterized using constant-head permeameter measurements performed on undisturbed horizontal sediment cores. Ground-penetrating radar data were collected along the excavation face in the form of both reflection and common midpoint surveys. Comparison of geostatistical analyses of the permeameter measurements and the radar data suggests thatthe horizontal correlation structure of radar stack velocity can be used to directly infer the horizontal correlation structure of hydraulic conductivity. The averaging nature of the common midpoint survey is manifest in the vertical correlation structure of stack velocity, making it less useful. Radar reflection data do not exhibit a spatial structure similar to that of hydraulic conductivity possibly because reflections are a result of material property contrasts rather than the material properties themselves.     

Spatial and temporal variability of ground water recharge in central Australia: a tracer approach

Two environmental tracer methods are applied to the Ti-Tree Basin in central Australia to shed light on the importance of recharge from floodouts of ephemeral rivers in this arid environment. Ground water carbon-14 concentrations from boreholes are used to estimate the average recharge rate over the interval between where the ground water sample first entered the saturated zone and the bore. Environmental chloride concentrations in ground water samples provide estimates of the recharge rate at the exact point in the landscape where the sample entered the saturated zone. The results of the two tracer approaches indicate that recharge rates around one of the rivers and an extensive floodplain are generally higher than rates of diffuse recharge that occurs in areas of lower topographic relief. Ground water 2H/1H and 18O/16O compositions are all depleted in the heavier isotopes (delta2H = -67 per thousand to -50 per thousand; delta18O = -9.2 per thousand to -5.7%o) compared with the long-term, amount-weighted mean isotopic composition of rainfall in the area (delta2H = -33.8 per thousand; delta18O = -6.3 per thousand). This indicates that recharge throughout the basin occurs only after intense rainfall events of at least 150 to 200 mm/month. Finally, a recharge map is developed to highlight the spatial extent of the two recharge mechanisms. Floodout recharge to the freshest ground water (TDS <1,000 mg/L) is approximately 1.9 mm/year compared with a mean recharge rate of approximately 0.2 mm/year to the remainder of the basin. These findings have important implications for management of the ground water resource.     

Analytical model for aquifer response incorporating distributed stream leakage

An analytical model of stream/aquifer interaction is proposed that predicts drawdown in an aquifer with leakage from a finite-width stream induced by pumping from a well. The model is formulated based on the assumptions of stream partial penetration, a semipervious streambed, and distributed recharge across a finite-width stream. Advantages of the analytical solution include its simple structure, consisting of the Theis well function with integral modifications. The solution is derived for the semi-infinite domain between the stream and pumping well, which is of primary interest to hydrogeologists. Previous stream/aquifer analytical models are compared to the analytical solution based on dimensionless drawdown profiles. Drawdown in the aquifer near a wide stream was found to be less than that predicted by a solution that ignored stream width. Deviations between the proposed analytical solutions and previous solutions increase as stream width increases. For a hypothetical stream/aquifer system, the proposed analytical solution was equivalent to prior solutions when the ratio of the distance between the stream and aquifer to the stream width was greater than 25. This analytical solution may provide improved estimates of aquifer and streambed leakage parameters by curve fitting experimental field drawdown data.     

A comparative analysis of three habitat suitability models for commercial yield estimation of Tapes philippinarum in a North Adriatic coastal lagoon (Sacca di Goro, Italy)

Habitat Suitability (HS) models have been extensively used by conservation planners to estimate the spatial distribution of threatened species and of species of commercial interest. In this work we compare three HS models for the estimation of commercial yield potential and the identification of suitable sites for Tapes philippinarum rearing in the Sacca di Goro lagoon (Italy) on the basis of six environmental factors. The habitat suitability index (HSI) is based on expert opinion while the habitat suitability conditional (HSC) is calibrated on observational data. The habitat suitability mixed (HSM) model is a two-part model combining expert knowledge and regression analysis: the first component of the model uses logistic regression to identify the areas in which clams are likely to be present; the second part applies the same parameter-specific suitability functions of the HSI model only in the areas previously identified as productive by the logistic component. The HS models were validated on an independent data set and estimates of potential yield of the Goro lagoon were compared. The effectiveness of the three approaches is then discussed in terms of predicted yield and identification of suitable sites for farming.     

晋陕峡谷北段保德-府谷地区唐县面上冲积物的特征及其地貌意义

晋陕峡谷是研究黄河演化的关键河段之一,许多学者对晋陕峡谷以及黄河的演化进行了研究,但还没有形成统一认识,特别是晋陕峡谷区唐县面上是否存在古黄河沉积物以及唐县面是否属于黄河阶地,学术界尚存在不同见解。本文以晋陕峡谷北段保德-府谷地区唐县期基岩侵蚀面上18个沉积剖面的野外观察为基础,在各露头剖面砾石层及现代黄河中采集21个样品进行砾石特征统计分析,结果表明:保德-府谷地区存在与现代黄河峡谷延伸方向一致的唐县期基岩宽谷,其形成时代至少在8.0Ma之前。唐县期宽谷底部各剖面砾石成分复杂性指数大多高于1.5,平均磨圆度接近2或在2以上,以次圆和圆为主,但磨圆度方差在0.5以上,砾石中远源组分比例大,具有长距离搬运和来源丰富的特征,由此推断该地区在中新世中期已经存在一条规模较大的河流,是现代黄河贯穿之前的一部分,即古黄河。晋陕峡谷的下切使唐县期宽谷高出现代河面约170m,成为该地段黄河的最高一级阶地。该地区红土层中下部的砾石透镜体,砾石成分简单,复杂性指数在1左右,磨圆普遍较差,除个别剖面,平均磨圆度都在1.5以下,以次棱角状为主,且不同砾石磨圆程度相差不大,磨圆度方差在0.32以下,具有近源堆积的特点,应该是来自河谷两侧支流的洪积物。