The influence of minerals on the pyrolysis of kerogens

The effect of mineral matter on the laboratory pyrolysis of sediments, kerogens and coals, and of coal macerals mixed with either alumina, bentonite, kaolinite, or calcium carbonate has been investigated. Some minerals are more active than others in effecting changes in the composition of the pyrolysate. The relative content of low molecular weight pyrolysis products is higher for kerogens pyrolyzed in a mineral matrix than for isolated kerogens. Our limited data suggests that this is due to both condensation and gasification of higher molecular weight constituents in the ‘primary’ pyrolysate. Differences in the content of aromatic versus aliphatic compounds have been noted when pyrograms from coal macerals are compared with pyrograms from coal maceral-mineral mixtures. We conclude that mineralogy is important in controlling the composition of kerogen pyrolysis products.     

Coherent integration time limit of a mobile receiver for indoor GNSS applications

There is an emerging requirement for processing global navigation satellite system (GNSS) signals indoor where the signal is very weak and subjected to spatial fading. Typically, longer coherent integration intervals provide the additional processing gain required for the detection and processing of such weak signals. However, the arbitrary physical motion of the handset imputed by the user limits the effectiveness of longer coherent integration intervals due to the spatial decorrelation of the multipath-faded GNSS signal. In this paper, limits of coherent integration due to spatial decorrelation are derived and corroborated with experimental verification. A general result is that the processing gain resulting from direct coherent integration saturates after the antenna has moved through a certain distance, which for typical indoor propagation, is about half a carrier wavelength. However, a refined Doppler search coupled with a prolonged coherent integration interval extends this limit, which is effectively a manifestation of selective diversity.     

Harmonic analysis of cosmic microwave background data – I. Ring reductions and point-source catalogue

We present a harmonic model for the data analysis of an all-sky cosmic microwave background survey, such as Planck , where the survey is obtained through ring-scans of the sky. In this model, resampling and pixelization of the data are avoided. The spherical transforms of the sky at each frequency, in total intensity and polarization, as well as the bright-point-source catalogue, are derived directly from the data reduced on to the rings. Formal errors and the most significant correlation coefficients for the spherical transforms of the frequency maps are preserved. A clean and transparent path from the original samplings in the time domain to the final scientific products is thus obtained. The data analysis is largely based on Fourier analysis of rings; the positional stability of the instrument's spin axis during these scans is a requirement for the data model and is investigated here for the Planck satellite. Brighter point sources are recognized and extracted as part of the ring reductions and, on the basis of accumulated data, used to build the bright-point-source catalogue. The analysis of the rings is performed in an iterative loop, involving a range of geometric and detector response calibrations. The geometric calibrations are used to reconstruct the paths of the detectors over the sky during a scan and the phase offsets between scans of different detectors; the response calibrations eliminate short- and long-term variations in detector response. Point-source information may allow the reconstruction of the beam profile. The reconstructed spherical transforms of the sky in each frequency channel form the input to the subsequent analysis stages. Although the methods in this paper were developed with the data processing for the Planck satellite in mind, there are many aspects which have wider implementation possibilities, including the construction of real-space pixelized maps.     

Hydrogeophysical investigation and estimation of groundwater potentials of the Lower Palaeozoic to Precambrian crystalline basement rocks in Keffi area, north-central Nigeria, using resistivity methods

The use of resistivity sounding and two-dimensional (2-D) resistivity imaging was investigated with the aim of delineating and estimating the groundwater potential in Keffi area. Rock types identified are mainly gneisses and granites. Twenty-five resistivity soundings employing the Schlumberger electrode array were conducted across the area. Resistivity sounding data obtained were interpreted using partial curve matching approach and 1-D inversion algorithm, RESIST version 1.0. The 2-D resistivity imaging was also carried out along two traverses using dipole–dipole array, and the data obtained were subjected to finite element method modeling using DIPRO inversion algorithm to produce a two-dimensional subsurface geological model. Interpretation of results showed three to four geoelectrical layers. Layer thickness values were generally less than 2 m for collapsed zone, and ranged from 5 to 30 m for weathered bedrock (saprolite). Two major aquifer units, namely weathered bedrock (saprolite) aquifer and fractured bedrock (saprock) aquifer, have been delineated with the latter usually occurring beneath the former in most areas. Aquifer potentials in the area were estimated using simple schemes that involved the use of three geoelectrical parameters, namely: depth to fresh bedrock, weathered bedrock (saprolite) resistivity and fractured bedrock (saprock) resistivity. The assessment delineated the area into prospective high, medium and low groundwater potential zones.     

用天然地震探测青藏高原中部地壳、上地幔结构

从西藏南部的定日、嘎拉至青海铜铁山的天然地震探测剖面,实际路线长约２０００ｋｍ,布设了约１１０台便携地震仪,记录了数百次远震和近震事件,采用多种方法进行了资料处理与解释．依据ＳＫＳ,ＰＫＳ,ｐｓ等横波分裂特征计算的青藏高原中部上地幔的地震各向异性表明：研究区各构造单元内的地震各向异性有明显变化,发现上地幔各向异性快速波的偏振方向与造山带的走向不完全一致．在雅江缝合线、崩错－嘉黎、唐古拉山口、昆仑山口几条断裂带处南、北各向异性出现显著的差异,而金沙江缝合线和班公－怒江缝合线的南、北则没有明显的各向异性变化．由Ｐ波走时残差,利用层析技术反演了４００ｋｍ深度内的速度图像,可以看出近地表１００ｋｍ范围内速度的不均匀变化与地表划分的构造单元很吻合,进一步佐证了青藏高原是由不同时期的微板块拼合而成的认识．在青藏高原中部１５０ｋｍ深度以下发现了多处低速区．在金沙江缝合带下方约２００ｋｍ深度处有一长２５０ｋｍ以上、延伸１５０ｋｍ的低速体,推测可能是一地幔柱．利用ＰＳ转换波划分的界面,显示出青藏高原北部具有低速层和高速层交替出现的地壳结构．     

Incoherent radiation from relativistic electrons with power energetic spectrum

It is shown that an incoherent high-frequency radiation from an ensemble of relativistic particles with the power energy distribution is described by a certain general expression which covers practically all the cases of particle radiation in random electromagnetic fields of cosmic radiation sources.     

Planetary-Scale Wave Structures of the Earth’s Atmosphere Revealed from the COSMIC Observations

GPS radio occultation（GPS RO） method,an active satellite-to-satellite remote sensing technique,is capable of producing accurate,all-weather,round the clock,global refractive index,density,pressure,and temperature profiles of the troposphere and stratosphere.This study presents planetary-scale equatorially trapped Kelvin waves in temperature profiles retrieved using COSMIC（Constellation Observing System for Meteorology,Ionosphere,and Climate） satellites during 2006-2009 and their interactions with background atmospheric conditions.It is found that the Kelvin waves are not only associated with wave periods of higher than 10 days（slow Kelvin waves） with higher zonal wave numbers（either 1 or 2）,but also possessing downward phase progression,giving evidence that the source regions of them are located at lower altitudes.A thorough verification of outgoing longwave radiation（OLR） reveals that deep convection activity has developed regularly over the Indonesian region,suggesting that the Kelvin waves are driven by the convective activity.The derived Kelvin waves show enhanced（diminished） tendencies during westward（eastward） phase of the quasi-biennial oscillation（QBO） in zonal winds,implying a mutual relation between both of them.The El Nino and Southern Oscillation（ENSO） below 18 km and the QBO features between 18 and 27km in temperature profiles are observed during May 2006-May 2010 with the help of an adaptive data analysis technique known as Hilbert Huang Transform（HHT）.Further,temperature anomalies computed using COSMIC retrieved temperatures are critically evaluated during different phases of ENSO,which has revealed interesting results and are discussed in light of available literature.     

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.     

Geochemistry and potential use of groundwater in the Rocca Busambra area (Sicily, Italy)

In the Rocca Busambra area (mid-west Sicily, Italy), from November 1999 to July 2002, 23 water points including wells and springs were sampled and studied for their chemical and isotopic compositions. Two rain gauges were also installed at different altitudes, and rainwater was collected monthly to determine the isotopic composition. The obtained results revealed the Rocca Busambra carbonate complex as being the main recharge area on account of its high permeability value. From a chemical view point, two main groups of water can be distinguished: calcium–magnesium–bicarbonate-type and calcium–magnesium–chloride–sulphate-type waters. The first group reflects the dissolution of the carbonate rocks; the second group probably originates from circulation within flyschoid sediments. Three water wells differ from the other samples due to their relatively high Na and K content, which probably is to be referred to a marked interaction with the “Calcareniti di Corleone” formation, which is rich in glauconite [(K, Na)(Fe³⁺, Al, Mg)₂(Si, Al)₄O₁₀(OH)₂]. In accordance with WHO guidelines for drinking water (2004), almost all the samples collected can be considered drinkable, with the exception of four of them, whose NO₃ ⁻, F⁻ and Na⁺ contents exceed the limits. On the contrary, the sampled groundwater studied is basically suitable for irrigation.