Verification of the RAMS-based operational weather forecast system in the Valencia Region: a seasonal comparison

Natural Hazards - The meteorological model Regional Atmospheric Modeling System (RAMS) in its version 4.4 has been applied operationally within the Valencia Region. The model output is being used...     

A 180 ka record of environmental change at Erdut (Croatia): a new chronology for the loess–palaeosol sequence and its implications for environmental interpretation

While there are numerous thick loess–palaeosol sequences preserved across the Carpathian Basin, well dated sites that provide terrestrial palaeoenvironmental records extending beyond last glacial–interglacial cycle are scarce. Robust chronologies are essential for correlations of loess with other long-term Quaternary records and to further understanding of the palaeoenvironment and climate of this important region beyond the last 125 ka. Here a new geochronology based on 13 post-infrared infrared stimulated luminescence ages focused on the lower part of the loess–palaeosol sequence at Erdut is presented. The results show that the lower part of the Erdut profile spans the penultimate glacial cycle (MIS 7 to MIS 5). The considerable sediments overlaying the investigated part of the profile suggest that this section spans two glacial cycles, rather than the previously suggested one. The most likely source of the discrepancy is the use of uncorrected infrared stimulated luminescence signal, which can cause age underestimation if not accounted for. This study demonstrates the need to revisit sites such as Erdut, re-date them using updated measurement protocols, and update existing palaeoenvironmental interpretations.     

Impacts of a bottom trawling exclusion zone on Snow Crab abundance and fish harvester behavior in the Labrador Sea, Canada

The Hawke Box trawling exclusion zone off southern Labrador is a 8610 km² closed area implemented in 2003 to protect soft-shelled pre-recruit Snow Crab and juvenile cod from mortality imposed by shrimp trawling and other bottom-impact fisheries. This study utilizes survey, logbook, and observer data from the Snow Crab and Northern Shrimp fisheries to assess the effectiveness of the Hawke Box in protecting and possibly enhancing the Snow Crab resource off southern Labrador. The results indicate that the exclusion zone has failed to protect pre-recruit crabs largely due to a redistribution and intensification of directed Snow Crab effort inside the Box in the years following closure. This unexpected outcome resulted in a high level of fishery-induced mortality to pre-recruit crabs and masked any potential positive outcomes from the cessation of trawling. The shortcomings that contributed to the failure of this exclusion area are discussed in relation to the current state of knowledge on the effectiveness of marine protected areas in general as management tools for conserving aquatic resources.     

Modeling of hydrodynamics and transport processes in the Dnieper–Bug Estuary

A numerical model of baroclinic circulation based on the use of a double sigma coordinate system is presented and its application to the simulation of flows and temperature and salinity fields in the Dnieper-Bug Estuary is described. The model reproduces the salinity and temperature fields surveyed in 1998. The results of simulations reveal the existence of a global influence of the relatively narrow and deep ship channel (through which Black-Sea waters can penetrate deep into the estuary) on the transport processes. Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 66–77, November–December, 2008.     

A Sensitivity Analysis of the Waterline Method of Constructing a Digital Elevation Model for Intertidal Areas in ERS SAR scene of Eastern England

A sensitivity analysis of the waterline method of constructing a Digital Elevation Model (DEM) of an intertidal zone using remote sensing and hydrodynamic modelling is described. Variation in vertical height accuracy as a function of beach slope is investigated using a set of nine ERS Synthetic Aperture Radar (SAR) images of the Humber/Wash area on the English east coast acquired between 1992 and 1994. Waterlines from these images are heighted using a hydrodynamic tide-surge model and interpolated using block kriging. On 1:500 slope beaches, an average block height estimation standard deviation of 18–22 cm is achieved. This rises to 27 cm on 1:100 slope beaches, and 32 cm on 1:30 slope beaches. The average heighting error at different slopes is decomposed into components due to waterline heighting error, inadequate sensor resolution and interpolation inaccuracy. It is shown that, at 1:500 slope, waterline heighting error and interpolation inaccuracy are the main error sources, whilst at 1:30 slope, errors due to inadequate sensor resolution become dominant. The ability of the technique to generate intertidal DEMs for almost the entire coastal zone in a complete ERS SAR scene covering 100×100 km is demonstrated.     

A model of Cs activity profile for soil erosion studies in uncultivated soils of Mediterranean environments

A model to simulate ¹³⁷Cs profiles in soils during the time in which they are being eroded is proposed. The model uses one parameter to characterize the cesium transference in the soil and another to express the erosion rate. To test the model, ¹³⁷Cs profiles of stable and eroded soils were collected at sampling sites located on semi-arid and temperate slopes in the Central Ebro basin, Spain. The ¹³⁷Cs profiles, corresponding to uncultivated soils with natural vegetation cover, were simulated using this model. The ¹³⁷Cs inventories and profiles calculated with the model are very similar to those measured experimentally, and thus it is possible to calculate soil erosion rates in physiographically diverse Mediterranean environments.     

Modeling of the swelling–shrinkage behavior of expansive clays during wetting–drying cycles

Acta Geotechnica - This paper presents a constitutive model for simulating the swelling–shrinkage volume change of expansive soils during wetting–drying cycles. Based on the concept of...     

Nanoparticles in natural systems II: The natural oxide fraction at interaction with natural organic matter and phosphate

Information on the particle size and reactive surface area of natural samples and its interaction with natural organic matter (NOM) is essential for the understanding bioavailability, toxicity, and transport of elements in the natural environment. In part I of this series (Hiemstra et al., 2010), a method is presented that allows the determination of the effective reactive surface area (A, m²/g soil) of the oxide particles of natural samples which uses a native probe ion (phosphate) and a model oxide (goethite) as proxy. In soils, the natural oxide particles are generally embedded in a matrix of natural organic matter (NOM) and this will affect the ion binding properties of the oxide fraction. A remarkably high variation in the natural phosphate loading of the oxide surfaces (Γ, μmol/m²) is observed in our soils and the present paper shows that it is due to surface complexation of NOM, acting as a competitor via site competition and electrostatic interaction. The competitive interaction of NOM can be described with the charge distribution (CD) model by defining a ≡NOM surface species. The interfacial charge distribution of this ≡NOM surface species can be rationalized based on calculations done with an evolved surface complexation model, known as the ligand and charge distribution (LCD) model. An adequate choice is the presence of a charge of −1 v.u. at the 1-plane and −0.5 v.u. at the 2-plane of the electrical double layer used (Extended Stern layer model).The effective interfacial NOM adsorption can be quantified by comparing the experimental phosphate concentration, measured under standardized field conditions (e.g. 0.01 M CaCl₂), with a prediction that uses the experimentally derived surface area (A) and the reversibly bound phosphate loading (Γ, μmol/m²) of the sample (part I) as input in the CD model. Ignoring the competitive action of adsorbed NOM leads to a severe under-prediction of the phosphate concentration by a factor ∼10 to 1000. The calculated effective loading of NOM is low at a high phosphate loading (Γ) and vice versa, showing the mutual competition of both constituents. Both constituents in combination usually dominate the surface loading of natural oxide fraction of samples and form the backbone in modeling the fate of other (minor) ions in the natural environment.Empirically, the effective NOM adsorption is found to correlate well to the organic carbon content (OC) of the samples. The effective NOM adsorption can also be linked to DOC. For this, a Non-Ideal Competitive adsorption (NICA) model is used. DOC is found to be a major explaining factor for the interfacial loading of NOM as well as phosphate. The empirical NOM-OC relation or the parameterized NICA model can be used as an alternative for estimating the effective NOM adsorption to be implemented in the CD model for calculation of the surface complexation of field samples. The biogeochemical impact of the NOM-PO₄ interaction is discussed.