Electrochemical strengthening of clayey sandy soils

Most previous studies and applications of electrochemical stabilization of soils through electroosmosis have been made on clayey soils. The object of this investigation was to find out if relatively small amounts of clay (1.5%–3.5%, by weight) present in a sandy soil would be enough for stabilization and strengthening to be possible. The results indicate increases of cohesion of the order of 100–200 lb./sq.ft. X-ray analyses of treated soils indicate that sheet structures of clays are reduced and silicates destroyed upon treatment by electroosmosis. Newly-formed minerals also cement the soil. These neoformations include gibbsite, limonite, calcite, hydrohematite, hydrogoethite (hydrolepidocrocite), hisingerite, allophane, allophanoid, gypsum, hematite, magnetite, nontronite, trona and natron (Na₂ CO₃, 10H₂O). The process seems to be irreversible.     

Climatic satellite monitoring of the external heat balance of the oceans and Black Sea

The long-wave outgoing radiation, effective cloudiness equal to the product of the total cloud amount by their optical density, and the sea-surface temperature determined from the satellites are used to determine the annual course of the components of external heat balance on the sea surface whose climatic anomalies, parallel with the meridional heat and water transfer in the ocean-atmosphere system, specify the intraannual and interannual large-scale variations of weather in different regions of the Earth. The development of these studies is connected with the progress of satellite hydrophysics because the data obtained from the space become sufficiently exact, regular, and global. The increase in the existing data array on the external heat balance of the oceans from ∼15–20 to 100 yr and more would promote the solution of the problem of oscillations of Earth's climate. We present examples of coordinated numerical analysis of the heat balance of the upper (0–100 m ) layer of the Black Sea performed on the basis of the shipborne and satellite data. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 59–75, November–December, 2007.     

Lagrangian diffusion equation and its application to oceanic dispersion

The Lagrangian diffusion equation appropriate for the dispersion of current followers (e. g., floats, drogues, drifters) is proposed. The analytical solution to the equation is obtained for a uniform deformation field, characterized by Lagrangian deformations and anisotropic eddy diffusivities both varying with time. Expressions are derived for the patch area and its elongation and rotation. For small values of elapsed time after the initial release the patch area can be accounted for by the exponential of the cumulative value of the horizontal divergence; the relative rate of change of the patch area can be accounted for by the horizontal divergence.     

Lethal and sublethal effects of short term acute doses of Kuwait Crude Oil and a dispersant Corexit 9527 on bay scallops, Argopecten irradians (Lamarck) and two predators at different temperatures

Investigations of short term acute exposure of bay scallops, Argopecten irradians and two scallop predators, the oyster drill Urosalpinx cinerea and the common starfish Asterias forbesi, to oil, dispersant, and oil-dispersant mixtures (Kuwait Crude Oil and Corexit 9527) suggested that predator and prey have different lethal susceptibilities. Scallops were most sensitive to dispersant and dispersant mixed with oil, starfish were only sensitive to dispersant while the oyster drill seemed unaffected even though all were exposed to dilutions of identically prepared stock solutions. Scallops were least susceptible during winter months and most susceptible at summer temperatures. Treatment had less effect on predators than on scallops at summer temperatures. Sublethal concentrations of dispersant and oil-dispersant mixtures diminished the behavioural ability of scallops to recognise drills and starfish. The degree of effect increased with temperature. Predator detection of prey at the same concentrations was more complex. The feeding response or posturing reflex of starfish was significantly slowed by all treatments. In contrast, drills were unaffected in their recognition of scallop effluent in a choice chamber after treatment.     

The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.     

Incorporation,distribution and fate of saturated petroleum hydrocarbons in sediments from a controlled marine ecosystem

A simulation of a chronic input of petroleum into an estuarine environment was investigated using the facilities at the Marine Ecosystems Research Laboratory at the University of Rhode Island. An oil-water dispersion of No. 2 fuel oil was added to the system (twice weekly for 24 weeks) and the saturated hydrocarbons from this oil were measured in suspended material and sediments. After the initial chronic oil addition, trace amounts of hydrocarbons were detected in the sediments within two weeks, but substantial accumulation was not detected for approximately 135 days. The oil appeared to enter the sediment via the suspended material, with most of the saturated hydrocarbons associated with smaller size sediment particles (< 45 μm to > 0·3 μm). With time, the fuel oil saturated hydrocarbons in the sediments were mixed to a depth of 3 to 4 cm. Although only 12% of the total saturated hydrocarbons added to the system were found in the sediments, these hydrocarbons appear to be relatively stable and were still detectable in these sediments for at least six months after the last oil addition.     

Geophysical evidence of mud diapirism on the Mediterranean Ridge accretionary complex

Mud volcanoes, mud cones, and mud ridges have been identified on the inner portion of the crestal area, and possibly on the inner escarpment, of the Mediterranean Ridge accretionary complex. Four areas containing one or more mud diapirs have been investigated through bathymetric profiling, single channel seismic reflection profiling, heat flow measurements, and coring. A sequence of events is identified in the evolution of the mud diapirs: initially the expulsion on the seafloor of gasrich mud produces a seafloor depression outlined in the seismic record by downward dip of the host sediment reflectors towards the mud conduit; subsequent eruptions of fluid mud may create a flat topped mud volcano with step-like profile; finally, the intrusion of viscous mud produces a mud cone.The origin of the diapirs is deep within the Mediterranean Ridge. Although a minimum depth of about 400 m below the seafloor has been computed from the hydrostatic balance between the diapiric sediments and the host sediments, a maximum depth, suggested by geometric considerations, ranges between 5.3 and 7 km. The presence of thermogenic gas in the diapiric sediments suggests a better constrained origin depth of at least 2.2 km.The heat flow measured within the Olimpi mud diapir field and along a transect orthogonal to the diapiric field is low, ranging between 16 ± 5 and 41 ± 6 mW m^–2. Due to the presence of gas, the thermal conductivity of the diapiric sediments is lower than that of the host hemipelagic oozes (0.6–0.9 and 1.0–1.15 W m^–1 K^–1 respectively).We consider the distribution of mud diapirs to be controlled by the presence of tectonic features such as reverse faults or thrusts (inner escarpment) that develop where the thickness of the Late Miocene evaporites appears to be minimum. An upward migration through time of the position of the décollement within the stratigraphic column from the Upper Oligocene (diapiric sediments) to the Upper Miocene (present position) is identified.     

Numerical modelling of the seasonal variability of hydrophysical fields in the Black Sea

The results of research into the seasonal variability of hydrothermodynamic characteristics of the Black Sea are presented. These have been obtained using field data on the fields of temperature, salinity, and wind, and by mathematical modelling. The seasonal variability of the current and heat content fields and of the cold intermediate layer and other hydrophysical characteristics is discussed.Translated by Mikhail M. Trufanov.     

Toward parameterization of the eddy field near the Gulf Stream

Analysis of measurements from two long-term moored arrays in and near the Gulf Stream suggests a simple parameterization of eddy spatial covariance statistics: a parameterization that can be referred to as “quasi-homogeneous and isotropic”. Taking the normalized covariance function (i.e. the correlation function) for streamfunction to be homogeneous and isotropic and assuming motions to be horizontally nondivergent and hydrostatic permit the velocity and temperature covariances to be derived from the streamfunction covariance. Statistical tests indicate that deviations from these assumptions are indistinguishable from Gaussian random noise. The spatial correlation function used in Gaussian with a decay scale of about 140 km, which is only weakly depth dependent. A simple form is also suggested for the vertical lag dependence. This parameterization permits calculation of derived quantities such as the eddy vorticity flux divergence which is discussed in the context of the mean potential vorticity balances for the depth integrated circulation and for the subthermocline layer. The divergence of the relative vorticity flux is found capable of driving two counter-rotating gyres of strength 30–40 Sv on either side of the Stream, as are observed. The “thickness flux” dominates the lower layer eddy potential vorticity flux and is of the correct sign to make the recirculation more barotropic. The lower layer eddy forcing is weak and the gyres exist in a region of nearly uniform mean potential vorticity.     

Validation of a finite difference method for the simulation of vortex-induced vibrations on a circular cylinder

The Karman Vortex Street generated by a circular cylinder is investigated by the numerical solution of the compressible Navier–Stokes equations in the incompressible Mach number range (Mach<0.3) using the Beam and Warming implicit scheme. The agreement with the fully incompressible projection method (Chorin, 1968) is fairly good while convergence time is very much better. The investigation suggests that the compressible Navier–Stokes equations may be used as an efficient alternative to study incompressible flows as well. Mach numbers just below 0.3 are enough to simulate incompressible flow behavior and at the same time do not cause numerical ill-conditioning in the solution. In addition, some relevant features of the vortices generated and carried by the wake of the cylinder could be fairly well captured.