Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.     

Mantle Pb paradoxes: the sulfide solution

There is growing evidence that the budget of Pb in mantle peridotites is largely contained in sulfide, and that Pb partitions strongly into sulfide relative to silicate melt. In addition, there is evidence to suggest that diffusion rates of Pb in sulfide (solid or melt) are very fast. Given the possibility that sulfide melt “wets” sub-solidus mantle silicates, and has very low viscosity, the implications for Pb behavior during mantle melting are profound. There is only sparse experimental data relating to Pb partitioning between sulfide and silicate, and no data on Pb diffusion rates in sulfides. A full understanding of Pb behavior in sulfide may hold the key to several long-standing and important Pb paradoxes and enigmas. The classical Pb isotope paradox arises from the fact that all known mantle reservoirs lie to the right of the Geochron, with no consensus as to the identity of the “balancing” reservoir. We propose that long-term segregation of sulfide (containing Pb) to the core may resolve this paradox. Another Pb paradox arises from the fact that the Ce/Pb ratio of both OIB and MORB is greater than bulk earth, and constant at a value of 25. The constancy of this “canonical ratio” implies similar partition coefficients for Ce and Pb during magmatic processes (Hofmann et al. in Earth Planet Sci Lett 79:33–45, 1986), whereas most experimental studies show that Pb is more incompatible in silicates than Ce. Retention of Pb in residual mantle sulfide during melting has the potential to bring the bulk partitioning of Ce into equality with Pb if the sulfide melt/silicate melt partition coefficient for Pb has a value of ∼ 14. Modeling shows that the Ce/Pb (or Nd/Pb) of such melts will still accurately reflect that of the source, thus enforcing the paradox that OIB and MORB mantles have markedly higher Ce/Pb (and Nd/Pb) than the bulk silicate earth. This implies large deficiencies of Pb in the mantle sources for these basalts. Sulfide may play other important roles during magmagenesis: (1) advective/diffusive sulfide networks may form potent metasomatic agents (in both introducing and obliterating Pb isotopic heterogeneities in the mantle); (2) silicate melt networks may easily exchange Pb with ambient mantle sulfides (by diffusion or assimilation), thus “sampling” Pb in isotopically heterogeneous mantle domains differently from the silicate-controlled isotope tracer systems (Sr, Nd, Hf), with an apparent “de-coupling” of these systems.     

The effect of single vegetation elements on wind speed and sediment transport in the Sahelian zone of Burkina Faso

Soil loss caused by wind erosion is a widespread phenomenon in the Sahelian zone of West Africa. According to Sahelian farmers, scattered vegetation standing in amongst the crop has the potential for a wind erosion control strategy. This study was conducted to study the effect of single vegetation elements on the pattern of average wind speed and sediment transport. This was done by two experiments that were carried out during the rainy seasons of 2002 and 2003 in north Burkina Faso, West Africa. Wind speeds were measured using three sonic anemometers, at a sampling frequency of 16 Hz. Sediment transport was determined by calculating the mass fluxes from 17 MWAC catchers. In this study, a shrub was defined as a vegetation element with branches until ground and a tree as a vegetation element with a distinctive trunk below a canopy. Behind shrubs wind speed near the soil surface was reduced up to approximately seven times the height of the shrub. The observed reduction in wind speed in the area where wind speed was reduced was 15 per cent on average. At the sides of the shrub, wind speed was increased, by on average 6 per cent. As the area of increase in wind speed is one‐third of the area of decrease in wind speed, the net effect of a shrub is a reduction in wind speed. A similar pattern was visible for the pattern of sediment transport around a shrub. Downwind of a shrub, sediment transport was diminished up to seven times the height of the shrub. Probably most of this material was trapped by the shrub. Trees showed a local increase of wind around the trunk, which is expected to relate to an increase in sediment transport around the trunk. Mass flux measurements of sediment transport were not made, but visual observations in the field substantiate this. Behind the canopy of a tree, a tree acts similarly to a shrub regarding its effects on average wind speed, but as a tree is generally a larger obstacle than a shrub the extent of this effect is larger than for shrubs. Thus, whereas shrubs are more effective than trees regarding their direct effect on soil loss by trapping sand particles near the soil surface, trees are more effective in affecting soil loss indirectly by reducing the wind speed downwind more effectively than shrubs. Therefore, to reduce soil loss in an area, the presence of both trees and shrubs is crucial. Copyright © 2007 John Wiley & Sons, Ltd.     

阿德朗达克-西魁北克地震带地壳三维速度结构成像

根据在阿德朗达克-西魁北克地震带及其邻近地区的59台短周期数字地震仪记录的直达P波走时观测值,用地震层析成像方法反演了该地区地壳三维速度结构.结果表明,地壳上层（0-5km）在阿德朗达克穹隆山的中南部地区出现正速度异常;第二层（5-10km）及第三层（10-15km）的速度横向变化较小,介质相对比较均匀;第四层（15-25km）出现显著的速度异常,一个是位于地震带中部的正速度异常（+4％）,它与布格重力正异常一致;另一个是位于阿德朗达克穹隆山下的负速度异常（-4％）.结合已有的地质及地球物理资料进行对比,可以认为阿德朗达克是一个正在发展的穹隆上升山,但其热源前锋尚未到达地面的大陆热点.     

Mean and extreme characteristics of Moscow climate at the end of the 20th century

Characteristics are presented of climate in Moscow, as obtained from instrumental observations since 1879 at the stations of the Timiryazev Agricultural Academy and of Moscow State University’s Meteorological Observatory. Changes in meteorological elements are estimated for the period 1961–1990 along with tendencies of their changes during the 20th century and the first half of the 21st century.     

Amino acid nitrogen in atmospheric aerosols: Occurrence,sources and photochemical modification

The presence of amino acids in atmospheric precipitation and aerosols has been noted for many years, yet relatively little is known about these or other nitrogen containing organic compounds in the atmosphere. Marine and continental rainwater analyses indicate that atmospheric aerosols, and subsequently atmospheric precipitation, may contain substantial levels of free and combined amino acids. The most likely source of amino N in the remote marine atmosphere appears to be the injection of proteinaceous material through the action of bursting bubbles at the sea-air interface or the long range transport from terrestrial sources. The capacity of these substrates to undergo photooxidation and photodegradation in the atmosphere to simpler species, such as ammonium ions, carboxylic acids, and for the S containing amino acids, oxidized forms of sulfur, has received little attention from atmospheric chemists. The photochemistry of covalently bound amino groups, particularly as found in peptides and amino acids, is discussed here with the purpose of summarizing what is known of their occurrence and their possible importance to atmospheric chemistry.     

Natural expansion and experimental manipulation of seagrass (Zostera spp.) abundance and the response of infaunal invertebrates

A study of an expanding seagrass bed on the south-west coast of British Columbia, Canada involved documentation and explanation of the pattern of expansion of the vegetation as well as documentation and experimental investigation of the accompanying changes in the distribution of infaunal invertebrates. Expansion followed a major environmental change, improved water clarity initiated in 1969 when a causeway blocked access to the site for silty Fraser River water. The original eelgrass (Zostera marina) bed expanded landward over 30 m year⁻¹, probably causing more and more water to be retained in the bed at low tide and thus improving its own habitat. More rapid expansion occurred from 1979–1983 after Z.japonica colonized at the landward edge of the eelgrass bed and in a separate intertidal area. Expansion ceased around 1983 coincident with, but probably independent of, further construction.Burrowing shrimp (Callianassa californiensis) decreased in abundance between 1977 and 1984 in areas where the two seagrasses colonized. Short-term experiment over one summer and fall showed that removal of all shoots allowed adult shrimp and tube worms to colonize the sediment while addition of shoots of Z. japonica by transplanting caused temporary decreases in shrimp abundance. After a few weeks an established shrimp population destroyed the transplants. Among reasonable alternate hypotheses for the decline in Callianassa, the effect of sediment texture can be eliminated, but either direct negative effects of seagrass, i.e. inhibition of the burrowing of adult shrimp or of settlement of juveniles, or indirect effects, i.e. the harboring of more predators of shrimp in seagrass beds, deserve further study.