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361.
S. Miko G. Koch S. Mesić M. Šparica-Miko M. Šparica R. Čepelak A. Bačani P. Vreča T. Dolenec S. Bergant 《Environmental Geology》2008,55(3):517-537
Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud.
An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution
of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and
storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially
channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic
(Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates
a moderate (EFs between 2–3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using
the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic
sources via dermal contact. 相似文献
362.
Regional distribution pattern of groundwater heavy metals resulting from agricultural activities 总被引:18,自引:0,他引:18
Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study
was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural
activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions
of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely
used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km2 between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions
A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004.
The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples
and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that
in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However,
the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were
more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural
activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the
environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and
groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of
the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants. 相似文献
363.
364.
365.
G. Caro V.C. Bennett B. Bourdon T.M. Harrison A. von Quadt S.J. Mojzsis J.W. Harris 《Chemical Geology》2008,247(1-2):253-265
146Sm–142Nd and 147Sm–143Nd systematics were investigated in garnet inclusions in diamonds from Finsch (S. Africa) and Hadean zircons from Jack Hills (W. Australia) to assess the potential of these systems as recorders of early Earth evolution. The study of Finsch inclusions was conducted on a composite sample of 50 peridotitic pyropes with a Nd model age of 3.3 Ga. Analysis of the Jack Hills zircons was performed on 790 grains with ion microprobe 207Pb/206Pb spot ages from 3.95 to 4.19 Ga. Finsch pyropes yield 100 × ?142Nd = ? 6 ± 12 ppm, ?143Nd = ? 32.5, and 147Sm/144Nd = 0.1150. These results do not confirm previous claims for a 30 ppm 142Nd excess in South African cratonic mantle. The lack of a 142Nd anomaly in these inclusions suggests that isotopic heterogeneities created by early mantle differentiation were remixed at a very fine scale prior to isolation of the South African lithosphere. Alternatively, this result may indicate that only a fraction of the mantle experienced depletion during the first 400 Myr of its history. Analysis of the Jack Hills zircon composite yielded 100 × ?142Nd = 8 ± 10 ppm, ?143Nd = 45 ± 1, and 147Sm/144Nd = 0.5891. Back-calculation of this present-day ?143Nd yields an unrealistic estimate for the initial ?143Nd of ? 160 ?-units, clearly indicating post-crystallization disturbance of the 147Sm–143Nd system. Examination of 146,147Sm–142,143Nd data reveals that the Nd budget of the Jack Hills sample is dominated by non-radiogenic Nd, possibly contained in recrystallized zircon rims or secondary subsurface minerals. This secondary material is characterized by highly discordant U–Pb ages. Although the mass fraction of altered zircon is unlikely to exceed 5–10% of total sample, its high LREE content precludes a reliable evaluation of 146Sm–142Nd systematics in Jack Hills zircons. 相似文献
366.
Deep dissolution affects great part of soluble rocks (e.g. gypsum and anhydrite) of the Western Italian Alps. The related superficial phenomena (sinkholes, gravity-induced processes and a local worsening of geomechanical rock properties) are not limited to typical karsts landscape and cause slope instability also affecting populated sites and infrastructures. The paper aims to describe general characteristic of dissolution phenomena, to interpret their conditioning factors and evolutionary stages and to assess possible hazards due to their superficial effects.The search for evidences of deep dissolution leads to the selection of representative sites in the central part of the Western Italian Alps (Piemonte and Valle d'Aosta Region). Detailed geological and geomorphological studies have been used to classify the selected sites by type, size and variable state of activity. Very different evolutionary stages of dissolution phenomena have been interpreted by comparison of case-studies: some are early “embryonic”; others are more evolved, up to typical sinkholes, or even remodelled by other phenomena. Some cases show an extreme complexity in the interactions between corrosion phenomena and other geomorphic processes: slope deformations, from one side, and karst, fluvial and glacial phenomena, to the other. A wide range of movement rates on slope instabilities induced by deep dissolution have been estimated by topographic and geomorphic data. Geochemical data on removed rocks by dissolution indicate 0.4 mm/year values for local subsidence. Historical and technical data indicate low frequency of major dissolution-induced collapses, but highlight widespread damages to tunnels, roads and buildings, especially along slopes. 相似文献
367.
A.N. Krot M. Chaussidon H. Yurimoto N. Sakamoto K. Nagashima I.D. Hutcheon G.J. MacPherson 《Geochimica et cosmochimica acta》2008,72(10):2534-2555
In situ oxygen isotopic measurements of primary and secondary minerals in Type C CAIs from the Allende CV3 chondrite reveal that the pattern of relative enrichments and depletions of 16O in the primary minerals within each individual CAI are similar to the patterns observed in Types A and B CAIs from the same meteorite. Spinel is consistently the most 16O-rich (Δ17O = −25‰ to −15‰), followed by Al,Ti-dioside (Δ17O = −20‰ to −5‰) and anorthite (Δ17O = −15‰ to 0‰). Melilite is the most 16O-depleted primary mineral (Δ17O = −5‰ to −3‰). We conclude that the original melting event that formed Type C CAIs occurred in a 16O-rich (Δ17O −20‰) nebular gas and they subsequently experienced oxygen isotopic exchange in a 16O-poor reservoir. At least three of these (ABC, TS26F1 and 93) experienced remelting at the time and place where chondrules were forming, trapping and partially assimilating 16O-poor chondrule fragments. The observation that the pyroxene is 16O-rich relative to the feldspar, even though the feldspar preceded it in the igneous crystallization sequence, disproves the class of CAI isotopic exchange models in which partial melting of a 16O-rich solid in a 16O-poor gas is followed by slow crystallization in that gas. For the typical (not associated with chondrule materials) Type C CAIs as well for as the Types A and B CAIs, the exchange that produced internal isotopic heterogeneity within each CAI must have occurred largely in the solid state. The secondary phases grossular, monticellite and forsterite commonly have similar oxygen isotopic compositions to the melilite and anorthite they replace, but in one case (CAI 160) grossular is 16O-enriched (Δ17O = −10‰ to −6‰) relative to melilite (Δ17O = −5‰ to −3‰), meaning that the melilite and anorthite must have exchanged its oxygen subsequent to secondary alteration. This isotopic exchange in melilite and anorthite likely occurred on the CV parent asteroid, possibly during fluid-assisted thermal metamorphism. 相似文献
368.
Daniel J. Schulze Howard G. Coopersmith Lori-Ann Pizzolato 《Geochimica et cosmochimica acta》2008,72(6):1685-1695
Thirty-four silicate and oxide inclusions large enough for in situ WDS electron microprobe analysis were exposed by grinding/polishing of 19 diamonds from the Kelsey Lake Mine in the Colorado-Wyoming State Line Kimberlite district. Eighteen olivines, seven Cr-pyropes, four Mg-chromites, and one orthopyroxene in 15 stones belong to the peridotite (P) suite and three garnets and one omphacite in three stones belong to the eclogite (E) suite. The fact that this suite is dominated by the peridotite population is in stark contrast to the other diamond suites studied in the State Line district (Sloan, George Creek), which are overwhelmingly eclogitic. Kelsey Lake olivine inclusions are magnesian (17 of 18 grains in 9 stones are in the range Fo 92.7-93.1), typical of harzburgitic P-suite stones worldwide, but unlike the more Fe-rich (lherzolitic) Sloan olivine suite. Mg-chromites (wt% MgO = 12.8-13.8; wt% Cr2O3 = 61.4-66.6) are in the lower MgO range of diamond inclusion chromites worldwide. Seven harzburgitic Cr-pyropes in five stones have moderately low calcium contents (wt% CaO = 3.3-4.3) but are very Cr-rich (wt% Cr2O3 = 9.7-16.7). A few stones have been analyzed by SIMS for carbon isotope composition and nitrogen abundance. One peridotitic stone is apparently homogeneous in carbon isotope composition (δ13CPDB = −6.2‰) but with variable nitrogen abundance (1296-2550 ppm). Carbon isotopes in eclogitic stones range from “normal” for the upper mantle (δ13CPDB = −5.5‰) to somewhat low (δ13CPDB = −10.2‰), with little internal variation in individual stones (maximum difference is 3.6‰). Nitrogen contents (2-779 ppm) are lower than in the peridotitic stone, and are lower in cores than in rims. As, worldwide, harzburgite-suite diamonds have been shown to have formed in Archean time, we suggest that the Kelsey Lake diamond population was derived from a block of Archean lithosphere that, at the time of kimberlite eruption, existed beneath the Proterozoic Yavapai province. The mixed diamond inclusion populations from the State Line kimberlites appear to support models in which volumes of Wyoming Craton Archean mantle survive buried beneath Proterozoic continental crust. Such material may be mixed with eclogitic/lherzolitic regimes emplaced beneath or intermingled with the Archean rocks by Proterozoic subduction. 相似文献
369.
David M. Sherman Caroline L. Peacock Christopher G. Hubbard 《Geochimica et cosmochimica acta》2008,72(2):298-310
Sorption of U(VI) to goethite is a fundamental control on the mobility of uranium in soil and groundwater. Here, we investigated the sorption of U on goethite using EXAFS spectroscopy, batch sorption experiments and DFT calculations of the energetics and structures of possible surface complexes. Based on EXAFS spectra, it has previously been proposed that U(VI), as the uranyl cation , sorbs to Fe oxide hydroxide phases by forming a bidentate edge-sharing (E2) surface complex, >Fe(OH)2UO2(H2O)n. Here, we argue that this complex alone cannot account for the sorption capacity of goethite (α-FeOOH). Moreover, we show that all of the EXAFS signal attributed to the E2 complex can be accounted for by multiple scattering. We propose that the dominant surface complex in CO2-free systems is a bidentate corner-sharing (C2) complex, (>FeOH)2UO2(H2O)3 which can form on the dominant {101} surface. However, in the presence of CO2, we find an enhancement of UO2 sorption at low pH and attribute this to a (>FeO)CO2UO2 ternary complex. With increasing pH, U(VI) desorbs by the formation of aqueous carbonate and hydroxyl complexes. However, this desorption is preceded by the formation of a second ternary surface complex (>FeOH)2UO2CO3. The three proposed surface complexes, (>FeOH)2UO2(H2O)3, >FeOCO2UO2, and (>FeOH)2UO2CO3 are consistent with EXAFS spectra. Using these complexes, we developed a surface complexation model for U on goethite with a 1-pK model for surface protonation, an extended Stern model for surface electrostatics and inclusion of all known UO2-OH-CO3 aqueous complexes in the current thermodynamic database. The model gives an excellent fit to our sorption experiments done in both ambient and reduced CO2 environments at surface loadings of 0.02-2.0 wt% U. 相似文献
370.
Kathryn A. Matthews Andréa G. Grottoli James E. Palardy 《Geochimica et cosmochimica acta》2008,72(18):4537-4550
Skeletal cadmium-to-calcium (Cd/Ca) ratios in hermatypic stony corals have been used to reconstruct changes in upwelling over time, yet there has not been a systematic evaluation of this tracer’s natural variability within and among coral species, between depths and across environmental conditions. Here, coral skeletal Cd/Ca ratios were measured in multiple colonies of Pavona clavus, Pavona gigantea and Porites lobata reared at two depths (1 and 7 m) during both upwelling and nonupwelling intervals in the Gulf of Panama (Pacific). Overall, skeletal Cd/Ca ratios were significantly higher during upwelling than during nonupwelling, in shallow than in deep corals, and in both species of Pavona than in P. lobata. P. lobata skeletal Cd/Ca ratios were uniformly low compared to those in the other species, with no significant differences between upwelling and nonupwelling values. Among colonies of the same species, skeletal Cd/Ca ratios were always higher in all shallow P. gigantea colonies during upwelling compared to nonupwelling, though the magnitude of the increase varied among colonies. For P. lobata, P. clavus and deep P. gigantea, changes in skeletal Cd/Ca ratios were not consistent among all colonies, with some colonies having lower ratios during upwelling than during nonupwelling. No statistically significant relationships were found between skeletal Cd/Ca ratios and maximum linear skeletal extension, δ13C or δ18O, suggesting that at seasonal resolution the Cd/Ca signal was decoupled from growth rate, coral metabolism, and ocean temperature and salinity, respectively. These results led to the following conclusions, (1) coral skeletal Cd/Ca ratios are independent of skeletal extension, coral metabolism and ambient temperature/salinity, (2) shallow P. gigantea is the most reliable species for paleoupwelling reconstruction and (3) the average Cd/Ca record of several colonies, rather than of a single coral, is needed to reliably reconstruct paleoupwelling events. 相似文献