Lagrangian diffusion equation and its application to oceanic dispersion

The Lagrangian diffusion equation appropriate for the dispersion of current followers (e. g., floats, drogues, drifters) is proposed. The analytical solution to the equation is obtained for a uniform deformation field, characterized by Lagrangian deformations and anisotropic eddy diffusivities both varying with time. Expressions are derived for the patch area and its elongation and rotation. For small values of elapsed time after the initial release the patch area can be accounted for by the exponential of the cumulative value of the horizontal divergence; the relative rate of change of the patch area can be accounted for by the horizontal divergence.     

A sonic well log of the basement complex of the Walvis Ridge

A sonic well log was obtained within the basement complex of the Walvis Ridge during Deep Sea Drilling Project Leg 74. The top of the basement complex is characterized by smooth acoustic reflectors. The rocks recovered within the basement complex consist of basalts with intercalated sediments. According to the log ～-50% of the upper 75 m of basement are igneous rocks and the other 50% sedimentary. Sonobuoy results indicate that the ratio of sediments to basalt increases with depth for an additional 225 m until a typical oceanic velocity structure is observed. Paleontological results suggest that the processes forming this upper 300 m of the basement complex was accomplished within a short time interval.     

Interpolation and extrapolation of hydrodynamic coefficients

The solution to the problem of calculating the hydrodynamic forces on multiple floating bodies is summarised. The complex coefficients which characterise the forces at each frequency of oscillation are expensive to compute; interpolation of intermediate values and extrapolation to high frequencies appear difficult since the coefficients seem to vary arbitrarily with frequency. Interpolation and extrapolation schemes based on a novel representation of the coefficients are proposed and tested. The excellent numerical results indicate that the values of the coefficients at a few frequency points can characterise the hydrodynamics at all frequencies. These techniques can save economically significant amounts of computer time and permit investigations which would otherwise be prohibitively expensive.     

Response of the suspended sediment transport system to continental shelf dynamics

Surface currents influenced by a wind-driven upwelling event in San Pedro Bay moved total suspended matter (TSM) confined to the inner shelf on 19 April 1978 seaward, so that by 27 April surface TSM had increased over the outer shelf. Near-bottom concentrations of TSM also increased across the shelf during this time. This is explained by sediment resuspended by large surface waves being advected from the inner shelf seaward by the mean flow after this flow had turned from southeasterly to southerly when upwelling ceased on 26 April. These complex shelf dynamics contribute to the off-shelf transport of mud to the slope and deep basins.     

An ocean-bottom hydrophone recorder for seismic refraction experiments

A new and inexpensive pop-up ocean-bottom hydrophone recorder has been developed for use in seismic refraction experiments. It is capable of operating in water depths of up to 4000 m and in very rugged topography, and uses an acoustic command system built by the U.K. Institute of Oceanographic Sciences for recovery. The instrument is mounted in an inexpensive cylindrical pressure case based on commercially available extruded aluminium alloy tubing, and uses glass spheres and syntactic foam for buoyancy. Hydrophone and clock signals are frequency modulated and recorded on tape cassettes, with a recording duration of three hours allowing up to 18 programmed shot windows. The prototype has made seven free descents on the Mid-Atlantic ridge and in the Gulf of Oman, and successfully recorded shots under operational conditions for the first time in September 1979. The total component cost of the prototype was £2740 (1979 prices).(Department of Earth Sciences, University of Cambridge Contribution No. ES135).     

Lethal and sublethal effects of short term acute doses of Kuwait Crude Oil and a dispersant Corexit 9527 on bay scallops, Argopecten irradians (Lamarck) and two predators at different temperatures

Investigations of short term acute exposure of bay scallops, Argopecten irradians and two scallop predators, the oyster drill Urosalpinx cinerea and the common starfish Asterias forbesi, to oil, dispersant, and oil-dispersant mixtures (Kuwait Crude Oil and Corexit 9527) suggested that predator and prey have different lethal susceptibilities. Scallops were most sensitive to dispersant and dispersant mixed with oil, starfish were only sensitive to dispersant while the oyster drill seemed unaffected even though all were exposed to dilutions of identically prepared stock solutions. Scallops were least susceptible during winter months and most susceptible at summer temperatures. Treatment had less effect on predators than on scallops at summer temperatures. Sublethal concentrations of dispersant and oil-dispersant mixtures diminished the behavioural ability of scallops to recognise drills and starfish. The degree of effect increased with temperature. Predator detection of prey at the same concentrations was more complex. The feeding response or posturing reflex of starfish was significantly slowed by all treatments. In contrast, drills were unaffected in their recognition of scallop effluent in a choice chamber after treatment.     

The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.     

Incorporation,distribution and fate of saturated petroleum hydrocarbons in sediments from a controlled marine ecosystem

A simulation of a chronic input of petroleum into an estuarine environment was investigated using the facilities at the Marine Ecosystems Research Laboratory at the University of Rhode Island. An oil-water dispersion of No. 2 fuel oil was added to the system (twice weekly for 24 weeks) and the saturated hydrocarbons from this oil were measured in suspended material and sediments. After the initial chronic oil addition, trace amounts of hydrocarbons were detected in the sediments within two weeks, but substantial accumulation was not detected for approximately 135 days. The oil appeared to enter the sediment via the suspended material, with most of the saturated hydrocarbons associated with smaller size sediment particles (< 45 μm to > 0·3 μm). With time, the fuel oil saturated hydrocarbons in the sediments were mixed to a depth of 3 to 4 cm. Although only 12% of the total saturated hydrocarbons added to the system were found in the sediments, these hydrocarbons appear to be relatively stable and were still detectable in these sediments for at least six months after the last oil addition.