砂土应力-应变关系的加载速率效应分析

分析研究了两种砂土在排水平面应变压缩PSC试验和不排水三轴压缩TC试验条件下的加载速率效应,既实现了不同恒定应变率加载条件下的试验,也实现了不同的加载阶段采用不同的恒定应变率（即应变率分阶段变化）的试验。在加载速率为不同恒定应变率时,砂土的应力-应变响应是唯一的,与应变率无关。在加载速率分阶段变化时,依据应力-应变关系对应变率突变的响应程度,对砂土的加载速率效应进行了评价。分析结果表明,砂土应力-应变关系的加载速率效应表现为黏性消散特性,在应变率发生突变的瞬间,由于应变加速度的影响,应力-应变曲线也相应地突变并表现为刚度很大,近似弹性的特性,随着应变的进一步增加,这一近似弹性的行为逐渐消失。     

Stable hydrogen isotope measurement of archaeal ether-bound hydrocarbons

Compound-specific hydrogen isotope analysis of ether-bound isoprenoid hydrocarbons from archaeal membranes has been developed using chemical degradation and gas chromatography/pyrolysis/isotope ratio mass spectrometry. The ether-bound hydrocarbons are quantitatively converted to saturated hydrocarbons by cleavage of ether bonds with HI followed by H₂ reduction in the presence of PtO₂. The δD value of ether-bound hydrocarbon moieties are corrected by way of isotopic mass balance calculation for the hydrogen incorporated during the hydrogenation. The method was successfully applied to determination of the δD values of biphytane moieties in glycerol dialkyl glycerol tetraethers (GDGTs) from a Sulfolobus sp. culture and a marine sediment.     

Investigation of cutting methods for small samples of Hayabusa and future sample return missions

We report the investigation of cutting methods for Hayabusa samples. The purpose of our study is to explore the possibility of applying multiple analyses to a single particle effectively. We investigated the cutting performance of a blade dicing saw, laser, focused ion beam (FIB), and physical breaking by microindenter. Cutting performance was examined by estimating the aspect ratio of the cut slit, i.e., depth over width of the slit. We also investigated the possible contamination and sample damage by cutting. The result of the investigation shows that we can cut the samples from <50 μm to 500 μm using those methods with aspect ratios from 10 to 20, although they would introduce some contamination or damage to the samples. Our investigations also provide an important basis for the analysis of samples obtained by future sample return missions.     

Eclogite-facies fluid infiltration: constraints from δ18O zoning in garnet

In situ analysis reveals that eclogite-facies garnets are zoned in δ¹⁸O with lower values in the core and rims that are ~1.5 to 2.5 ‰ higher. This pattern is present in 9 out of 12 garnets analyzed by SIMS from four orogenic eclogite terranes, and correlates with an increase in the mole fraction of pyrope and Mg/Fe ratio from core to rim, indicating prograde garnet growth. At the maximum temperatures and the time-scales experienced by these garnets, calculated intragranular diffusion distances for oxygen are small (<5 μm), indicating that δ¹⁸O records primary growth zoning and not diffusive exchange. The oxygen isotope gradients are larger than could form due to temperature changes during closed-system mineral growth. Thus, gradients reflect the compositions of fluids infiltrating during prograde metamorphism. Values of δ¹⁸O in garnet cores range from ?1 to 15 ‰, likely preserving the composition of the eclogite protoliths. Two garnet cores from the Almenningen eclogite in the Western Gneiss Region, Norway, have δ¹⁸O ~?1 ‰ and are the first negative δ¹⁸O eclogites identified in the region. In contrast with orogenic eclogites, seven high δ¹⁸O garnets (>5 ‰) from two kimberlites are homogeneous in δ¹⁸O, possibly due to diffusive exchange, which is possible for prolonged periods at higher mantle temperatures. Homogeneity of δ¹⁸O in garnets outside the normal mantle range (5–6 ‰) may be common in kimberlitic samples.     

A rotary-shear low to high-velocity friction apparatus in Beijing to study rock friction at plate to seismic slip rates

This paper reviews 19 apparatuses having highvelocity capabilities,describes a rotary-shear low to highvelocity friction apparatus installed at Institute of Geology,China Earthquake Administration,and reports results from velocity-jump tests on Pingxi fault gouge to illustrate technical problems in conducting velocity-stepping tests at high velocities.The apparatus is capable of producing plate to seismic velocities（44 mm/a to 2.1 m/s for specimens of 40 mm in diameter）,using a 22 kW servomotor with a gear/belt system having three velocity ranges.A speed range can be changed by 103 or 106by using five electromagnetic clutches without stopping the motor.Two cam clutches allow fivefold velocity steps,and the motor speed can be increased from zero to 1,500 rpm in 0.1-0.2 s by changing the controlling voltage.A unique feature of the apparatus is a large specimen chamber where different specimen assemblies can be installed easily.In addition to a standard specimen assembly for friction experiments,two pressure vessels were made for pore pressures to 70 MPa;one at room temperature and the other at temperatures to 500 °C.Velocity step tests are needed to see if the framework of rate-and-state friction is applicable or not at high velocities.We report results from velocity jump tests from 1.4 mm/s to 1.4 m/s on yellowish gouge from a Pingxi fault zone,located at the northeastern part of the Longmenshan fault system that caused the 2008 Wenchuan earthquake.An instantaneous increase in friction followed by dramatic slip weakening was observed for the yellowish gouge with smooth sliding surfaces of host rock,but no instantaneous response was recognized for the same gouge with roughened sliding surfaces.Instantaneous and transient frictional properties upon velocity steps cannot be separated easily at high velocities,and technical improvements for velocity step tests are suggested.     

Silicification of pelitic schist in the Ryoke low-pressure/temperature metamorphic belt, Southwest Japan: Origin of competent layers in the middle crust

We propose that competent layers composed of silicified rocks in the Cretaceous Ryoke low-pressure/temperature (low- P/T ) metamorphic belt in the Iwakuni–Yanai area, Southwest Japan, may be an exhumed equivalent of a seismically-reflective bright-layer in the middle crust. Silicified rocks crop out as layers or long lenticular bodies several to fifteen meters in thickness, and they are restricted to the area of greenschist facies conditions within a structural thickness of about one kilometer. The silicified rock layers exhibit a sharp contact with subjacent biotite schist but a gradational contact with overlying pelitic schist. Silicified rock is mainly composed of fine-grained quartz and minor muscovite and biotite, and some colored minerals have been variably decolorized by alteration. This implies that silicification turned the color of pelitic schists to pale gray or milky white. Quartz veins cutting schistosity at high angles were preferentially developed in the silicified rocks, while schistosity-parallel quartz veins, which underwent viscous flow, were observed in the underlying biotite schists. En echelon quartz veins and fishnet-like quartz veins are characteristic of silicified rocks. The modes of occurrence of quartz veins indicate that silicified rocks were competent relative to underlying biotite schist. The combination of contact with high-competence contrast adjacent to low-permeability silicified rocks may be a good reflector of seismic waves. If the silicified rocks were distributed in the middle crust to a considerable extent, they may result in seismic bright-layer reflections.     

Oxygen isotope thermometry using quartz inclusions in garnet

Oxygen isotope ratios of quartz inclusions (QI) within garnet from granulite and amphibolite facies gneisses in the Adirondack Mountains, NY were analysed and used to determine metamorphic temperatures. Primary QI for eight of 12 samples have δ¹⁸O values significantly lower than matrix quartz (MQ). The primary QI retain δ¹⁸O values representative of thermal conditions during garnet crystallization, whereas the δ¹⁸O values of MQ were raised by diffusive exchange with other matrix minerals (e.g. mica and feldspar) during cooling. The δ¹⁸O differences between QI and MQ show that garnet (a mineral with slow diffusion of oxygen) can armour QI from isotopic exchange with surrounding matrix, even during slow cooling. These differences between δ¹⁸O in MQ and QI can further be used to test cooling rates by Fast Grain Boundary diffusion modelling. Criteria for identifying QI that preserve primary compositions and are suitable for thermometry were developed based on comparative tests. Relations between δ¹⁸O and inclusion size, distance of inclusion to host–garnet rim, core–rim zonation of individual inclusions, and presence or absence of petrological features (healed cracks in QI, inclusions in contact with garnet cracks lined by secondary minerals, and secondary minerals along the inclusion grain boundary) were investigated. In this study, 61% of QI preserve primary δ¹⁸O and 39% were associated with features that were linked to reset δ¹⁸O values. If δ¹⁸O in garnet is homogeneous and inclusions are removed, laser‐fluorination δ¹⁸O values of bulk garnet are more precise, more accurate, and best for thermometry. Intragrain δ¹⁸O(Grt) profiles measured in situ by ion microprobe show no δ¹⁸O zonation. Almandine–rich garnet (Alm_60–75) from each sample was measured by laser‐fluorination mass‐spectrometry (LF‐MS) for δ¹⁸O and compared with ion microprobe measurements of δ¹⁸O in QI for thermometry. The Δ¹⁸O(Qz–Grt) values for Adirondack samples range from 2.66 to 3.24‰, corresponding to temperatures of 640–740 °C (A[Qz–Alm] = 2.71). Out of 12 samples that were used for thermometry, nine are consistent with previous estimates of peak temperature (625–800 °C) based on petrological and carbon–isotope thermometry for regional granulite and upper amphibolite facies metamorphism. The three samples that disagree with independent thermometry for peak metamorphism are from the anorthosite–mangerite–charnockite–granite suite in the central Adirondacks and yield temperatures of 640–665 °C, ~100 °C lower than previous estimates. These low temperatures could be interpreted as thermal conditions during late (post‐peak) crystallization of garnet on the retrograde path.     

Temporal and spatial variations in the spawning activity of the micronektonic shrimp,Sergia lucens (hansen) in Suruga Bay,Japan

Temporal and spatial variations in the spawning activity ofSergia lucens were investigated in relation to some environmental conditions of Suruga Bay. The daily egg abundance varied considerably with the coefficient of variation from 81% to 269% in July. The spawning activity was most clearly affected by temperature, but the relationship to lunar period and content of chlorophylla were not obvious. Timing of the July spawning is predictable with increase of the surface temperature to 24°C and strong vertical movements of the 18°C isotherm depth; it is also related to modal length of the shrimp in June. It is suggested that intrusion of cold water at 20–50 m affects reproduction of the shrimps and vertical distribution of eggs and larvae. The shrimp population seemed to relate principally to two spawning grounds,i.e. the head part and the western part of the bay. The timing of spawning is not always synchronous throughout the bay. The spawning is sporadic and the distribution of eggs is patchy. This may reflect a recent decrease in the population of the shrimp due to increased fishing pressure.A part of the present paper is based on the thesis submitted by G. H. B. in partial fulfilment of the requirements for her degree of Master of Science at the Tokyo University of Fisheries in 1986.     

Evolution of the composition of seawater through geologic time, and its influence on the evolution of life

The redox state of the surface environment of the early Earth is still controversial, and a detailed and quantitative estimate is still lacking. We carried out in-situ analyses of major, trace, and rare-earth elements of carbonate minerals in rocks with primary sedimentary structures in shallow and deep sea-deposits, in order to eliminate secondary carbonate and contamination of detrital materials, and to estimate the redox condition of seawater through time. Based on the Ce content and anomalies of the carbonate minerals at given parameters of atmospheric CO₂ content (pCO₂) and Ca content of seawater, we calculated the oxygen contents of shallow and deep seawater, respectively. The results show that the oxygen content of the deep sea was low and constant until at least 1.9 Ga. The oxygen content of shallow seawater increased after 2.7 Ga, but fluctuated. It became quite high at 2.5 and 2.3 Ga, but eventually increased after the Phanerozoic. In addition, the calculation of a high pCO₂ condition shows that seawater was more oxic even in the Archean than at present, suggesting a relatively low pCO₂ through geologic time.Our detailed calculations from compositions of carbonate minerals in Three Gorge area, south China show a low oxygen content of seawater after the Snowball Earth until the late Ediacaran, an increase in the late Ediacaran, and a significant decrease around the Precambrian–Cambrian and Nemakit/Daldynian–Tommotian boundaries. These variations were possibly caused by global regression and dissolution of methane hydrates.     

高岭土一维增湿的湿陷-流变分析方法研究

塑性单元体与黏性单元体并联之后再与弹性单元体串联即构成三要素模型,其各单元体都具有非线性本构关系。通过考虑增湿过程中饱和度对三要素模型中的黏性单元体和塑性单元体的影响,建立了弹-塑-黏性与湿陷性耦合的湿陷流变本构模型。湿陷对塑性单元体的影响表现为应变不变条件下屈服应力的降低;而对黏性单元体的影响表现为速率敏感系数的升高。两种影响可以通过试验确定。以此模型为基础,分析了高岭土的单轴压缩固结试验中的湿陷-流变变形,提出了一种湿陷-流变分析方法。试验中,在干燥条件下观测了蠕变;在增湿过程中观测了湿陷。试验中对含水量的测量精度高。理论所得含水率-应变-时间关系与实测结果接近,并区分了增湿过程中的湿陷和干燥条件下的蠕变,证明了本方法的有效性。