Evaluating the thermal metamorphism of CM chondrites by using the pyrolytic behavior of carbonaceous macromolecular matter

The degrees of thermal metamorphism of 10 CM chondrites and of the Allende CV3 chondrite were evaluated from the viewpoint of “graphitization” of the carbonaceous macromolecular matter by means of flash pyrolysis-gas chromatography (GC). The unheated chondrites, Yamato- (Y-) 791198, Murray and Cold Bokkeveld, yielded larger amounts and wider varieties of pyrolyzates than the chondrites strongly heated in the parent asteroids, Y-82054, Y-86695, and Belgica- (B-) 7904, and Asuka- (A-) 881334 (more strongly heated than Y-793321, which has been weakly heated, but lesser than the other strongly heated meteorites). The weakly heated chondrites, Y-793321 and A-881458, showed intermediate features. The data indicate that graphitization of the carbonaceous matter is most extreme in the strongly heated chondrites and that during graphitization, the matter has lost its labile portion, which can generate pyrolyzates such as naphthalene. In order to establish a new method for the evaluation of the degree of graphitization of chondritic carbonaceous matter, a diagram was developed to show the relationship between the total amounts of pyrolyzates with retention times later than 5 min (=S_RT>5) and the ratio of the amount of naphthalene, a pyrolysis product, to S_RT>5 (=S_N/S_RT>5). The diagram indicates a possible evolutionary pathway of graphitization of the carbonaceous matter in carbonaceous chondrites.     

Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.     

Modelling the Shimokita deep coalbed biosphere over deep geological time: Starvation,stimulation, material balance and population models

Basin models can simulate geological, geochemical and geophysical processes and potentially also the deep biosphere, starting from a burial curve, assuming a thermal history and utilizing other experimentally obtained data. Here, we apply basin modelling techniques to model cell abundances within the deep coalbed biosphere off Shimokita Peninsula, Japan, drilled during Integrated Ocean Drilling Program Expedition 337. Two approaches were used to simulate the deep coalbed biosphere: (a) In the first approach, the deep biosphere was modelled using a material balance approach that treats the deep biosphere as a carbon reservoir, in which fluxes are governed by temperature-controlled metabolic processes that retain carbon via cell-growth and cell-repair and pass it back via cell-damaging reactions. (b) In the second approach, the deep biosphere was modelled as a microbial community with a temperature-controlled growth ratio and carrying capacity (a limit on the size of the deep biosphere) modulated by diagenetic-processes. In all cases, the biosphere in the coalbeds and adjacent habitat are best modelled as a carbon-limited community undergoing starvation because labile sedimentary organic matter is no longer present and petroleum generation is yet to occur. This state of starvation was represented by the conversion of organic carbon to authigenic carbonate and the formation of kerogen. The potential for the biosphere to be stimulated by the generation of carbon-dioxide from the coal during its transition from brown to sub-bituminous coal was evaluated and a net thickness of 20 m of lignite was found sufficient to support an order of magnitude greater number of cells within a low-total organic carbon (TOC) horizon. By comparison, the stimulation of microbial populations in a coalbed or high-TOC horizon would be harder to detect because the increase in population size would be proportionally very small.     

Wide-Field Camera for Gravitational Microlensing Survey: MOA-cam2

We have constructed a large, mosaic CCD camera called MOA-cam2 which has 4096 × 6144-pixelsto search for gravitational microlensing events. MOA-cam2 has three4096 × 2048-pixel SITe CCD chips, which have a very high quantum efficiency (nearly 80% in the wave region 500 to 800 nm),and three buttable sides. We have placed the threechips side by side with 100 m dead space. MOA-cam2 has been installed on the 61 cm Boller and Chivens telescope of the MOA collaboration at the Mt. John University Observatory (MJUO) in NewZealand since July 1998. The field coverage is 0.92° × 1.38° per exposure. The technical details of MOA-cam2 and the first images obtained with the Boller and Chivens telescope are presented. MOA-cam2 introduces a second phase of research on gravitational microlensing by the MOA collaboration.     

Soil-structure interaction analysis of the Hualien containment model

This paper presents results from forced vibration tests, microtremor observations and earthquake response analysis of a nuclear reactor containment model constructed on stiff soil in Hualien, Taiwan. The dynamic behavior of the soil-structure system is simulated successfully with two numerical models: a sway-rocking model, whose soil parameters are evaluated on the basis of the continuum formulation method, and a finite element model, using the program SASSI with the flexible volume substructuring approach. The dependences of the soil parameters of both models on the amplitudes of the different dynamic excitations are investigated in detail. An original numerical simulation of microtremor is performed. Comparison with results of a previous study involving a rigid tower on a soft soil site in Chiba, Japan is offered.     

Response of rigid body assemblies to dynamic excitation

Shaking table tests were conducted to investigate the response of rectangular wooden blocks and block assemblies of various sizes and slenderness to harmonic and earthquake base excitation. The shaking tests were followed by an analytical and a numerical study of response of single blocks and block assemblies. The analytical study was aimed at establishing criteria for the initiation of rocking and of overturning in response to harmonic base motion and consisted of solving numerically the differential equations of motion of a rigid block on a rigid foundation. The numerical study, in the course of which the response of both single blocks and block assemblies was examined, was implemented by means of the Distinct Element Method (DEM). Prior to the DE simulation of actual shaking tests, preliminary analyses were conducted to confirm numerical stability and to evaluate material and damping parameters. Comparing the recorded time histories with those given by the analytical study and the DE simulation, good agreement was found. The distinct element model in use appeared to follow the highly non-linear motion of rigid body assemblies faithfully to reality. On the basis of the results, provided that the necessary parameters are carefully estimated, the employed DE model can be regarded as an appropriate tool to simulate response of rigid body assemblies to dynamic base excitation.     

Response analysis of the Higashi–Kobe Bridge and surrounding soil in the 1995 Hyogoken–Nanbu Earthquake

This paper presents results of observation and analysis of the response of one of the longest cable-stayed bridges in the world to the Hyogoken–Nanbu (Kobe) Earthquake of 17 January 1995. It is determined that interaction of the foundations of the bridge towers with the supporting soil plays a decisive role in the overall structural behaviour. The key factor governing the changes of the soil properties at this site is pore-water pressure buildup, which results in liquefaction of the saturated surface soil layers under large dynamic loads. Models of the soil and structure are created and initially validated by accurately simulating the system response to a small earthquake. Soil parameters reflecting the pore-water pressure buildup in the strong earthquake are determined by an advanced non-linear effective stress analysis, combining the Ramberg–Osgood model of stress–strain dependence with a pore pressure model based on shear work concept. They are utilized to investigate and simulate the interaction of the foundation and the supporting soil using the program SASSI with the flexible volume substructuring approach. The results show a good agreement with the observations and have useful implications to the scientific and engineering practice. © 1998 John Wiley & Sons, Ltd.     

Strength and deformation behavior of the Shimanto accretionary complex across the Nobeoka thrust

A rapid reduction in sediment porosity from 60 to 70 % at seafloor to less than 10 % at several kilometers depth can play an important role in deformation and seismicity in the shallow portion of subduction zones. We conducted deformation experiments on rocks from an ancient accretionary complex, the Shimanto Belt, across the Nobeoka Thrust to understand the deformation behaviors of rocks along plate boundary faults at seismogenic depth. Our experimental results for phyllites in the hanging wall and shale‐tuff mélanges in the footwall of the Nobeoka Thrust indicate that the Shimanto Belt rocks fail brittlely accompanied by a stress drop at effective pressures < 80 MPa, whereas they exhibit strain hardening at higher effective pressures. The transition from brittle to ductile behavior in the shale–tuff mélanges lies on the same trend in effective stress–porosity space as that for clay‐rich and tuffaceous sediments subducting into the modern Nankai subduction zone. Both the absolute yield strength and the effective pressure at the brittle–ductile transition for the phyllosilicate‐rich materials are much lower than for sandstones. These results suggest that as the clay‐rich or tuffaceous sediments subduct and their porosities are reduced, their deformation behavior gradually transitions from ductile to brittle and their yield strength increases. Our results also suggest that samples of the ancient Shimanto accretionary prism can serve as an analog for underthrust rocks at seismogenic depth in the modern Nankai Trough.     

Statistical analysis of peaks and directivity of earthquake ground motion

Conversion factors are useful for attenuation and damage estimation relationships. These factors among different definitions of peaks (i.e. larger, average and resultant) for peak ground motion indices and acceleration response spectrum were investigated. A large number of horizontal acceleration records recorded at 76 free-field sites of the Japan Meteorological Agency were used in this study. Two orthogonal horizontal components were combined in the time domain to get the maximum resultant peak ground motion indices and acceleration response spectrum in the horizontal plane. From the analysis, the means of the larger/resultant ratio were found to be 0·934 for acceleration, 0·926 for velocity, and 0·913 for displacement. A similar decreasing trend was observed for the means of the average/resultant ratio of the ground motion indices and acceleration response spectrum. The directivity of peak ground motion indices was also examined. It was found that the peak ground motion is more likely to occur in the transverse direction than in other directions. This trend is more prominent in the long-period contents of ground motion.     

Non-destructive monitoring of trace element levels in short-tailed albatrosses (Phoebastria albatrus) and black-footed albatrosses (Phoebastria nigripes) from Torishima Island, Japan using eggs and blood

Concentrations of 18 trace elements (V, Cr, Mn, Co, Cu, Zn, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, Hg, Tl and Pb) were determined in abandoned eggs of short-tailed albatrosses and abandoned eggs and blood of black-footed albatrosses from Torishima Island, Japan in 2002. Mercury concentration was highest among the toxic elements in egg content of both the two species. In some egg contents of black-footed albatrosses, Hg concentrations were higher than the threshold level that may cause decreased hatchability and aberrant nesting behavior in some avian species. Concentrations of Cd in egg content and Ba in egg content and shell increased with an increase in egg breadth/length ratio, whereas Hg in egg content showed an opposite trend in black-footed albatrosses. Since egg breadth/length ratio is known to increase with the age of mother bird, this result may imply that concentrations of these elements in eggs vary with age of mother bird. In blood of black-footed albatross chicks, concentration of Hg was highest among the toxic elements and the Hg concentration showed an increase in the later growth stages. In contrast, concentration of Sr in blood decreased with growth stage. Since the behaviour of Sr is similar to that of Ca in animals, it is conceivable that Sr was used along with Ca for the formation of bone.