Modeling diagnosis of suspended sediment transport in tidal estuarine system

A three-dimensional, time-dependent hydrodynamic and suspended sediment transport model was performed and applied to the Danshuei River estuarine system and adjacent coastal sea in northern Taiwan. The model was validated with observed time-series salinity in 2001, and with salinity and suspended sediment distributions in 2002. The predicted results quantitatively agreed with the measured data. A local turbidity maximum was found in the bottom water of the Kuan-Du station. The validated model then was conducted with no salinity gradient, no sediment supply from the sediment bed, wind stress, and different freshwater discharges from upstream boundaries to comprehend the influences on suspended sediment dynamics in the Danshuei River estuarine system. The results reveal that concentrations of the turbidity maximum simulated without salinity gradient are higher than those of the turbidity maximum simulated with salinity gradient at the Kuan-Du station. Without bottom resuspension process, the estuarine turbidity maximum zone at the Kuan-Du station vanishes. This suggests that bottom sediment resuspension is a very important sediment source to the formation of estuarine turbidity maximum. The wind stress with northeast and southwest directions may contribute to decrease the suspended sediment concentration. When the freshwater discharges increase at the upstream boundaries, the limits of salt intrusion pushes downriver toward river mouth. Suspended sediment concentrations increase at the upriver reaches in the Danshuei River to Tahan Stream, while decrease at Kuan-Du station.     

Distribution of mixotrophic nanoflagellates along the latitudinal transect of the central North Pacific

To elucidate the ecological importance of mixotrophic nanoflagellates in the open ocean and the environmental factors that regulate their abundance, we surveyed latitudinal distributions of autotrophic, mixotrophic and heterotrophic nanoflagellates in the central North Pacific Ocean along a transect at 170°W. Mixotrophic nanoflagellates significantly contributed (26–64 %) to total bacterivory, as measured by the fluorescently-labeled bacteria method, from the equatorial through the subarctic regions, which reinforces the importance of mixotrophic nanoflagellates as a trophic link in the open ocean. The proportion of mixotrophic to total plastidic nanoflagellates was significantly higher in the nutrient-depleted subtropical gyre than in other regions, sometimes exceeding 10 %. Additionally, the proportion was negatively correlated with soluble reactive phosphorus concentration within the tropical and subtropical waters, suggesting that low nutrient availability could facilitate phagotrophy of plastidic nanoflagellates, which may explain the survival of nano-sized eukaryotic phytoplankton in the ultraoligotrophic water. In the subarctic regions, the proportion exhibited no obvious relationship with any environmental parameter. Conversely, the numerical proportion of mixotrophic nanoflagellates in total phagotrophic nanoflagellates (sum of mixotrophic and heterotrophic nanoflagellates) was positively correlated with nutrient concentrations. In contrast to macronutrient availability, the physical stability of the water column did not appear to affect the contribution of mixotrophic nanoflagellates.     

Formation of tonalite from basaltic magma at the Komahashi-Daini Seamount,northern Kyushu-Palau Ridge in the Philippine Sea,and growth of Izu-Ogasawara (Bonin)-Mariana arc crust

Tonalitic rocks dredged from the Komahashi-Daini Seamount, northern Kyushu-Palau Ridge are classified as biotite-hornblende tonalites and hornblende tonalites. These rocks have radiometric ages of 37-38 Ma, indicating that felsic plutonic activity occurred during the early stages of Izu-Ogasawara (Bonin)-Mariana (IBM) arc volcanism. Therefore, this tonalite complex has great importance for understanding the initial processes of island arc and continental crust formation. These tonalitic rocks exhibit the following petrological and geochemical characteristics: (1) common lamellar twins and oscillatory zoning patterns in plagioclase phenocrysts throughout the compositional range; (2) hornblende tonalite shows parallel REE patterns and increasing total REE content with increasing SiO₂, except for an increasingly strong negative Eu anomaly at higher SiO₂ levels; and (3) isotopic composition remains constant over a wide silica variation. We compare this tonalite with younger tonalities of the same arc from the Tanzawa Complex (10-5 Ma), central Japan, considered to represent the lower-middle crust of the IBM arc, and find the following differences: (1) cumulate textures found in Tanzawa tonalites are not observed in samples from the Komahashi-Daini Seamount; and (2) Komahashi-Daini Seamount tonalites, unlike those from Tanzawa, exhibit linear variations of Zr and REEs vs. SiO₂ plots. These data and other observations support the interpretation that tonalite in the Komahashi-Daini Seamount was produced by crystal fractionation from basaltic magma. We suggest that fractional crystallization operated during the early stage of oceanic island arc formation to produce tonalite, whereas tonalities in later stages formed largely by partial melting of basaltic lower crust, as represented by the tonalites in the Tanzawa Complex.     

Mechanisms of uranium mineralization by the yeast Saccharomyces cerevisiae

We determined the association of uranium in yeast cells S. cerevisiae grown in medium containing high (1 g · L^-1) or low (0.2 g · L^-1) concentrations of phosphate after exposure for 96 h to a 4 × 10^-4 mol · L^-1 U(VI) solution at pH 3.2 or 4.7. The analysis was made using a field emission scanning electron microscope equipped with energy dispersive spectroscopy (FESEM-EDS), transmission electron microscopy (TEM), and visible diffuse reflectance spectrometry. Cells grown in the high-phosphate medium rapidly accumulated U(VI) from solution at pH 3.2 over the first 24 h, followed by a slow uptake until 96 h, whereas in cells grown in low-phosphate medium, U(VI) accumulation reached a steady state within 24 h. FESEM-EDS analyses revealed the formation of a U(VI)-bearing precipitate on the yeast cells grown in high-phosphate medium after only 48 h exposure; no precipitate was detected on cells grown in low-phosphate medium up to 96 h. These results suggest that sorption onto the cell surfaces was the dominant process initially. Analysis of the U(VI)-bearing precipitates by all three methods demonstrated the presence of H-autunite, HUO₂PO₄ · 4H₂O. Thermodynamic calculations suggest that the chemical compositions of the solutions containing yeast grown in high-phosphate medium were undersaturated with respect to H-autunite, but were supersaturated with ten times more U(VI) and P than were actually observed. Apparently, the sorbed U(VI) on the cell surfaces reacts with P released from the yeast to form H-autunite by local saturation. The U(VI) uptake by yeast cells grown in high phosphate medium at pH 4.7, along with the thermodynamic calculation, indicated that more H-autunite is precipitated in neutral pH solution than in acid solution. Thus, U(VI)-phosphate mineralization on the cells of microorganisms should be taken into account for predicting U(VI) mobility in the environment.     

Variations of magnetic susceptibility and fine quartz accumulation rate in Daisen loam over the past 200 000 years: Interaction between winter and summer monsoons in south-west Japan

Abstract A loam section near Daisen volcano, South-west Japan, has been examined for low-field magnetic susceptibility (MS) and fine quartz accumulation rate. Fission track dating of tephra layers interbedded in the deposit shows that the loam age ranges from about 200 ka to the Present. The MS was measured for both bulk sample and the < 63 μm fine fraction. Fine quartz contents in the < 63 μm fraction were also determined using acid-alkali digestions and recalculated to derive fine quartz accumulation rate (Rqz). Grain size analysis was then carried out on the separated fine quartz. Low-field MS varies from low frequency magnetic suspectibility (χ(LF)) 5 to 100 (× 10⁻⁶ m³/kg) for bulk samples and from 1 to 30 for fine fractions. The fine fraction χ(LF) variation correlated with Chinese loess MS stratigraphy, which indicated changes in pedogenic enhancement of the MS and is reflected by summer monsoon intensity. The Rqz are high in cool climate stages, with volumes between 0.2 and 0.4 (× 10⁻² kg/m² per yr), whereas in warm stages the rate falls to about 0.1. These values compare well with those reported from the Hokkaido and Kanto areas, suggesting the fine quartz originates from tropospheric dust. The strong winter monsoons during glacial stages alternated with weak summer monsoons as a result of a southward shift of the jet stream. In interglacials, summer monsoons were stronger. Seasonal alternating monsoons appear to have operated in South-west Japan through the past 200 000 years.     

Elastic stress and strain in jointed rock masses by means of crack tensor analysis

Summary An elastic stress-strain relation is formulated in terms of crack tensors which makes it possible to take into account explicitly the effect of joints on elastic behavior of rock masses. The present study is to discuss some related topics which may be encountered in its practical application. Two problems are solved by incorporating the elastic stress-strain relation into a program for three-dimensional finite element analyses; i. e., stress concentration by surface loading and displacement by excavation of an intersecting tunnel. Validity of the results is checked by comparing them with a laboratory model test and a field test, with the following conclusions: The overall distribution of stress definitely depends on a joint stiffness ratio (i. e., normal stiffness to shear stiffness). If the ratio is chosen as unity, the stress concentration occurs mainly in the direction parallel to major joints. If the ratio is high, say 10, then the stress concentrates along the perpendicular as well as the parallel directions to major joints. It can be said, on the basis of the fairly good agreement of the calculations using the high stiffness ratio with the field and laboratory measurements, that the elastic solution by crack tensors provides a practical tool for estimating the stress and strain in strongly jointed rock masses.     

Elemental Concentrations in Nine New GSJ Rock Reference Samples "Sedimentary Rock Series"

Nine new rock reference samples of the "Sedimentary rock series", Chert JCh-1, Dolomite JDo-1, Lake sediment JLk-1, Limestone JLs-1, Stream sediments JSd-1 to JSd-3, and Slates JS1-1 and JSl-2 have been prepared by the Geological Survey of Japan(GSJ). Thirty major, minor and trace elements were determined using atomic absorption spectrometry, flame emission spectrometry, infrared absorption spectrometry and wet chemical techniques. The results of homogeneity tests showed that almost all elements, with a few exceptions, are considered to be distributed homogeneously in each reference sample.     

Early tholeiitic and calc-alkaline arc magmatism of middle to Late Eocene Age in the southern Ogasawara (Bonin) forearc

Analysis of middle and upper Eocene rocks from the IBM forearc, including the Ogasawara and Mariana Islands, help illuminate early arc volcanism of the proto-IBM arc. Dredged volcanic rocks from the forearc are two-pyroxene basalt to andesite, and may be divided into two groups, tholeiite and calc-alkaline, on the basis of mineralogy, petrography, and bulk chemistry. Tholeiites are characterized by high HFSE contents, high crystallization temperatures, and low water contents. In contrast, the calc-alkaline rocks are characterized by low HFSE contents, low crystallization temperatures, and higher water contents. These characteristics indicate that magma genesis for the two series differed. The tholeiites resulted from high degrees of partial melting of slightly depleted mantle under anhydrous conditions, whereas the calc-alkaline rocks were generated by low degrees of melting of depleted mantle under hydrous conditions. We believe that differences in mantle depletion arose from compositional layering and fluid zonations caused by MORB volcanism and slab dehydration, respectively. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Study of the structure of silica film by infrared spectroscopy and electron diffraction analyses

Amorphous silicon oxide films have been studied on the basis of electron diffraction (ED) analyses and infrared (IR) spectroscopy in order to elucidate the relationship between the structures. After the heat treatment of the film in air at 300 and 500°C, the ED pattern showed halo rings, and the IR spectra clearly changed. Intensity analysis of the ED pattern provided evidence for the structural change of the amorphous film. It was concluded that the spectral changes in the ranges of 9.2–10.2, 12.5–13.5 and 19.5–22.5 μm were the result of phase transitions of the microcrystallites of α-cristobalite to β-cristobalite, and α- or β-quartz. Astrophysical implications have been discussed.