Enrichment of adsorbed methane in authigenic carbonate concretions of the Japan Trench

Substantial amounts of adsorbed methane were detected in authigenic carbonate concretions recovered from sedimentary layers from depths between 245 and 1,108 m below seafloor during Ocean Drilling Program Leg 186 to ODP sites 1150 and 1151 on the deep-sea terrace of the Japan Trench. Methane contents were almost two orders of magnitude higher in the concretions (291–4,528 nmol/g wet wt) than in the surrounding bulk sediments (5–93 nmol/g wet wt), whereas methane/ethane ratios and stable carbon isotopic compositions were very similar. Carbonate content of surrounding bulk sediments (0.02–3.2 wet wt%) and methane content of the surrounding bulk sediments correlated positively. Extrapolation of the carbonate contents of bulk sediments suggests that 100 wt% carbonate would correspond to 1,886±732 nmol methane per g bulk sediment, which is similar to the average value observed in the carbonate concretions (1,321±1,067 nmol/g wet wt, n = 13). These data support the hypothesis that, in sediments, adsorbed hydrocarbon gases are strongly associated with authigenic carbonates.     

Dissolved and labile particulate Zr,Hf, Nb,Ta, Mo and W in the western North Pacific Ocean

Dissolved and labile particulate Zr, Hf, Nb, Ta, Mo and W were determined at stations K1 (51°N, 165°E), K2 (47°N, 160°E), KNOT (44°N, 155°E) and 35N (35°N, 160°E) in the western North Pacific Ocean. A portion of seawater for dissolved species (D) was passed through a 0.2 μm Nuclepore filter and acidified to pH 2.2 with HCl and HF. A portion of seawater for acid-dissolvable species (AD) was acidified without filtration. Labile particulate (LP) species is defined as AD minus D, which represents a chemically labile fraction of particulate species. D-Zr, Hf and Ta increase with depth, Nb shows a slight depletion in surface water, whereas Mo and W have a conservative vertical profile. The concentration range of D-Zr, Hf, Nb, Ta and W is 31–275, 0.14–0.95, 4.0–7.2, 0.08–0.29 and 40–51 pmol kg⁻¹, respectively, whereas that of Mo is 97–105 nmol kg⁻¹. LP-species of Zr, Hf and Ta account for 10–14% of AD in average and increase up to 25% below 4000 m, whereas those for Mo and W are negligible. In contrast, LP-Nb shows maxima (up to 27%) in surface water. We also found that D-Zr/Hf, Nb/Ta and Mo/W mole ratios generally increase in the order continental crust < river water < coastal sea < open ocean.     

Basalts and serpentinite from the Puerto Rico Trench, 1. Petrology

Typical abyssal tholeiites occur on both north and south walls of the Puerto Rico Trench. Probably they were erupted in the Mid-Atlantic Ridge in Cretaceous time and afterwards were moved to the present position. In addition, doleritic basalts containing phenocrysts of pigeonite rimmed by augite were found from the north wall, and these rocks presumably represent a new type of abyssal tholeiites characterized by $\text{CaO}\text{Na}{}_2\text{O}$ ratios lower than those of ordinary abyssal tholeiites.A new analysis of serpentinite from the north wall is also recorded here.     

Effects of Recharge Wells and Flow Barriers on Seawater Intrusion

The installation of recharge wells and subsurface flow barriers are among several strategies proposed to control seawater intrusion on coastal groundwater systems. In this study, we performed laboratory‐scale experiments and numerical simulations to determine the effects of the location and application of recharge wells, and of the location and penetration depth of flow barriers, on controlling seawater intrusion in unconfined coastal aquifers. We also compared the experimental results with existing analytical solutions. Our results showed that more effective saltwater repulsion is achieved when the recharge water is injected at the toe of the saltwater wedge. Point injection yields about the same repulsion compared with line injection from a screened well for the same recharge rate. Results for flow barriers showed that more effective saltwater repulsion is achieved with deeper barrier penetration and with barriers located closer to the coast. When the flow barrier is installed inland from the original toe position however, saltwater intrusion increases with deeper barrier penetration. Saltwater repulsion due to flow barrier installation was found to be linearly related to horizontal barrier location and a polynomial function of the barrier penetration depth.     

Glacial hazards in the Rolwaling valley of Nepal and numerical approach to predict potential outburst flood from glacial lake

In recent years, climate change and retreating glaciers constitute a major hazard in the Himalaya of South Asia. Glacial lakes are rapidly developing or increasing due to climate change. The rapid development of the lake may cause outburst of the lake. The outburst discharge from the glacial lake can cause catastrophic flooding and disaster in downstream area. Therefore, it is necessary to investigate the impact of climate change on glacial lakes and to understand the characteristics of the glacial lake outburst. In this study, the field assessment of Tsho Rolpa Glacial Lake in the Himalaya of Nepal has been presented and the impact of climate change on this glacial lake has been discussed. The Tsho Rolpa Glacial Lake is the largest and most potentially dangerous glacial lake in Nepal. In addition, a numerical model has been also developed for computing the characteristics of glacial lake outburst due to moraine dam failure by seepage and water overtopping. The numerical model is tested for the flume experimental cases. The simulated results of the outburst discharge, the dam surface erosion, and the temporal variation of the moisture movement in the dam are compared with those obtained from the hydraulic model experiments. The moisture profile calculated by numerical model was agreeable with the experimental moisture profile. The simulated failure surface of the dam due to seepage by considering the suction in slope stability analysis gave more agreeable results than the Janbu's simplified method. The results of the outburst discharge and dam surface erosion also agreed with the experimental results.     

Far-infrared detection limits – II. Probing confusion including source confusion

We present a comprehensive analysis for the determination of the confusion levels for the current and the next generation of far-infrared surveys assuming three different cosmological evolutionary scenarios. We include an extensive model for diffuse emission from infrared cirrus in order to derive absolute sensitivity levels taking into account the source confusion noise due to point sources, the sky confusion noise due to the diffuse emission, and instrumental noise. We use our derived sensitivities to suggest best survey strategies for the current and the future far-infrared space missions Spitzer , AKARI ( ASTRO-F ), Herschel and SPICA . We discuss whether the theoretical estimates are realistic and the competing necessities of reliability and completeness. We find the best estimator for the representation of the source confusion and produce predictions for the source confusion using far-infrared source count models. From these confusion limits considering both source and sky confusions, we obtain the optimal, confusion limited redshift distribution for each mission. Finally, we predict the cosmic far-infrared background (CFIRB), which includes information about the number and distribution of the contributing sources.     

Far-infrared detection limits – I. Sky confusion due to Galactic cirrus

Fluctuations in the brightness of the background radiation can lead to confusion with real point sources. This type of confusion with background emission is relevant when making infrared (IR) observations with relatively large beam sizes, since the amount of fluctuation tends to increase with the angular scale. To quantitively assess the effect of the background emission on the detection of point sources for current and future far-IR observations by space-borne missions such as Spitzer , ASTRO-F , Herschel and Space Infrared Telescope for Cosmology and Astrophysics ( SPICA ), we have extended the Galactic emission map to a higher level of angular resolution than that of the currently available data. Using this high-resolution map, we estimate the sky confusion noise owing to the emission from interstellar dust clouds or cirrus, based on fluctuation analysis and detailed photometry over realistically simulated images. We find that the confusion noise derived by simple fluctuation analysis agrees well with the results from realistic simulations. Although sky confusion noise becomes dominant in long wavelength bands  (>100 μm)  with 60–90 cm aperture missions, it is expected to be two orders of magnitude lower for the next generation of space missions (with larger aperture sizes) such as Herschel and SPICA .