A role for a superficial sediment layer in upward nutrient fluxes across the overlying water–sediment interface

A superficial sediment layer (SL) is the top 2–3 mm layer of surface sediment that may contribute to high upward nutrient flux. To study the characteristics and the biogeochemical processes in the superficial layer, the seasonal variation in the total phytopigments (chlorophyll a and pheo-pigments), total organic carbon (TOC), and total nitrogen (TN) of the surface sediments in a shallow coastal area, Shido Bay, were measured, and the influence of the superficial sediment layer on nutrient flux at the sediment–water interface was investigated. TOC and TN content were relatively constant for the SL and subsurface layers (0–1 and 1–2 cm) during the study period. In contrast, total phytopigments content was higher in the SL layer than in the subsurface layers. The results of upward nutrient flux experiments showed higher nutrient release within the whole sediment core (SL remaining) than the SL-less (SL removed) core. Moreover, high nutrient fluxes were observed during the high temperature season, indicating that seasonal variation in nutrient flux was regulated by temperature. Moreover, in the low temperature season, the SL seemed to absorb nutrients, probably because of microphytobenthos photosynthesis that took up the nutrients under the sufficient light penetration to the sea floor.     

Effect of solid to solution ratio on biogenic silica determination in coastal sediments

The method of DeMaster (1981) for measuring biogenic silica (BSi) in marine sediments was modified. We found a considerable effect of the solid to solution (S/S) ratio on BSi determination in coastal sediments. The BSi contents determined by DeMaster’s method were overestimated due to the contribution of clay mineral-derived extractable Si at a low S/S ratio (<1 g l⁻¹), and incomplete recovery of BSi was observed due to incomplete extraction when using a high S/S ratio (>2 g l⁻¹). For BSi analysis of coastal sediment samples, the BSi content of representative samples must be measured using various S/S ratios to determine the appropriate S/S ratio in order to minimize the contribution of extractable Si derived from clay minerals and to obtain sufficiently efficient extraction with 1% Na₂CO₃ before actual sample measurement. One way to determine the appropriate S/S ratio is to use artificial sediment which has a theoretical Si and clay mineral content similar to the sediment sample composition. Using artificial sediment, the S/S ratio of 2 g l⁻¹ seems appropriate for measuring the BSi content of the coastal sediments investigated in this study, because 99.6% recovery can be achieved.     

Petrographic and Geochemical Constraints on the Provenance of Sanidine‐Bearing Temper in Ceramic Potsherds,Four Corners Region,Southwest USA

Previous researchers proposed that trachybasalt temper with “poikilitic” sanidine, found in pottery from the Mesa Verde region of the American Southwest, was procured along the eastern Chuska Mountains. This served as one line of evidence that Chaco Canyon was a regional trade center linked to the Chuska Mountains in the ninth to thirteenth centuries. Recent geologic studies, however, revealed other potential sources for the trachybasalt temper. A comparison of petrographic features and geochemical signatures of poikilitic sanidine in rock samples and potsherds shows no definitive correlation of temper materials and a specific geologic source. Several outcrops of trachybasalt are identified as less viable prospects, but the results do not support the idea that the sanidine‐rich temper was exclusively gathered in the Chuska Mountains. This conclusion opens up the possibility that raw materials were gathered from local sources that were more accessible, reducing the dependence on a regional trade center.     

推断勒夫波相速度的圆形台阵微震新技术

介绍了简单而又新颖的公式,使用微震的二分量,即圆形台阵记录的水平运动直接推断勒夫波相速度(cL)时,这些公式具有帮助作用。我们的公式与一般用于推断瑞雷波相速度(cR)的微震探测技术的空间自相关(SPAC)方法的公式类似。虽然SPAC方法现有的理论确实提供了估计cL的可能性,但这只能通过求解非线性的方程组才能实现,而其中待求解的未知数也包括cR以及瑞雷波?勒夫波的幂分配比。相反,在我们公式中cL是出现的唯一未知数。基于我们推荐公式——我们称为SPAC+L、SPAC-L和CCA-L(其中CCA表示无中心圆形台阵)法——的cL估算法的现场适用范围通过2个测试点的分析结果说明。在所提出的3种技术中,SPAC+L法由于表现最佳而出名。3种方法的有效波长范围下限是台阵半径r的2～5倍区域,上限是10～25r的区域。近年来,提出了类似的仅涉及cL的圆形台阵微震技术,但与它们相比,我们在此给出的方法,不是在数理计算上繁冗更少,就是在数学上更为简单。     

Variation of dissolved organic matter and fluorescence characteristics before,during and after phytoplankton bloom

The variation of dissolved organic matter (DOM) and fluorescence characteristics during the phytoplankton bloom were investigated in Yashima Bay, at the eastern part of the Seto Inland Sea, Japan. We found significant accumulations of dissolved organic carbon (DOC), dissolved organic nitrogen (DON), chromophoric dissolved organic matter (CDOM) fluorescence, and UV₂₆₀ during the phytoplankton bloom period in 2005, although lower accumulations of DOC and DON and only increases of CDOM fluorescence were observed during the bloom period in 2006. Little or no correlation between DOM and phytoplankton abundance might be due to the composition of DOM, which is a complex mixture of organic materials. The 3D-EEM results revealed that the DOM produced around the phytoplankton bloom period contained tyrosine, tryptophan, and humic-like substances. Our results showed that the occurrence of phytoplankton bloom contributed to the production of DOM in coastal water but the DOM accumulation depended on the type of phytoplankton bloom, the phytoplankton species in particular. From our results, we concluded that phytoplankton have a great role in the dynamics of DOM as a producer in a coastal environment.     

Determination of the freshwater origin of Coastal Oyashio Water using humic-like fluorescence in dissolved organic matter

Coastal Oyashio Water (COW), defined as a water mass with a temperature lower than 2 °C and a salinity lower than 33.0, is distributed in the North Pacific Ocean off southeastern Hokkaido, Japan, from winter to spring. COW is rich in macronutrients and dissolved iron and is thus considered to affect the spring phytoplankton blooms in the Oyashio region. Although river water and sea-ice melt water have been considered freshwater end-members of COW, the contributions of these freshwater sources to COW have not been well described. In this study, the humic-like components in dissolved organic matter were first applied as a parameter to evaluate the freshwater end-members of COW in March 2015. Linear regressions with negative slopes were determined between the humic-like components and the salinity of COW. The intercepts of the regressions against the humic-like components were within the ranges of those observed for the local rivers of Hokkaido but were very different from those of sea ice. These findings suggest that river water contributed to the COW observed here as a freshwater end-member, although the contribution of sea-ice melt water to COW could not be evaluated. This novel approach also highlighted two different less-saline water masses in COW. The first was characterized by a lower temperature and relatively high levels of humic-like components, while the second was higher in temperature and had higher levels of humic-like components. It is suggested that these different characteristics are due to the contributions of water from different rivers and/or different effects of sea-ice melt water.     

Mercury dynamic simulation of Minamata Bay by using a three-dimensional numerical model

Ocean Dynamics - Residual mercury dynamic has been the research emphasis since mercury contamination was publicly recognized in Minamata Bay. Simulation of mercury distribution and transport...     

Standing stock and production rate of phytoplankton and a red tide outbreak in a heavily eutrophic embayment, Dokai Bay, Japan.

The seasonal variation of phytoplankton biomass and primary productivity in a heavily eutrophic embayment, Dokai Bay, Japan, was determined. Dokai Bay was characterized by high phytoplankton biomass and productivity during summer and low phytoplankton biomass and productivity during other seasons. The results suggested that phytoplankton growth was limited by only irradiance and water temperature under the high nutrient concentrations available for phytoplankton growth in the entire year. Moreover, in spite of sufficient nutrient for phytoplankton growth in the entire year, a red tide occurred only in the summer period in this bay. Our results suggested that a red tide occurred by the high phytoplankton growth rate in the summer season, but in other periods surface phytoplankton was flushed out of the bay before forming the red tide, because phytoplankton growth rate was low and could not form the red tide due to low irradiance and low water temperature.     

Large-Eddy Simulation of Turbulent Organized Structures within and above Explicitly Resolved Cube Arrays

Large-eddy simulations have been performed for fully developed turbulent flow within and above explicitly resolved simple cube arrays. The results from our model, hereafter LES-CITY, are shown to agree with laboratory experiments. We investigated the systematic influence of cube density on turbulent flow characteristics by performing numerical experiments for cube areal densities from 0 to 44%. The following results were obtained: (1) The dispersive momentum flux was quite large within the canopy layer due to a mean stream re-circulation, whereas it was smaller above the canopy. The spatial variation of temporally averaged momentum in the roughness sub-layer was 20% or less of the total kinematic surface drag. (2) The temporally and spatially-averaged flow structure confirmed the existence of conventionally described canyon flow regimes; isolated, interfacial, and wake. However, the intermittency of the canyon flow for all cube densities was quite large and the stream patterns were never persistent. (3) Turbulent organized structures (TOS) similar to those observed in turbulent surface-layer flows were simulated, which are characterized by longitudinally-elongated low speed streaks and the corresponding shorter streamwise vortices. The streaks in sparse and dense canopy flows were likely to be aligned to the street line and to the roof lines, respectively. Such heterogeneity of TOS partially accounts for the large spatial variation of momentum flux. (4) In contrast to the mixing layer analogy of vegetation flows, the TOS and the resulting turbulent statistics of urban flow above the canopy resembled those in surface layers. The recirculation within the canopy significantly influenced the turbulent statistical properties.