滇西南团梁子岩组绿片岩、基性脉岩及构造分异石英脉岩锆石U-Pb年龄及其地质意义

滇西南团梁子岩组是南澜沧江构造带内重要的构造岩石单元之一,与兰坪-思茅盆地演化有密切联系。由于层序恢复困难和缺乏标志生物化石,该套岩石地层的时代归属缺乏有效约束。江桥团梁子岩组中基性脉岩和构造分异石英脉岩较为发育,在岩石学观察基础上,以绿片岩、辉长(绿)岩及与区域面理(S2)同期的构造分异石英脉岩为研究对象,借助激光剥蚀等离子体质谱(LA-ICP-MS)技术,对其中分选出的锆石开展了精确的U-Pb年龄测定。2件绿片岩样品31个锆石测点中存在4组206Pb/238U年龄,分别为1816~1542 Ma(加权平均为1630±210 Ma,N=6)、850~832 Ma(加权平均为844±95 Ma,N=2)、517~422 Ma(加权平均为438±26 Ma,N=4)和292~188Ma(加权平均为219.7±8.5 Ma,N=19)。2件辉长(绿)岩样品31个锆石测点中也存在4组206Pb/238U年龄,分别为2256~1357 Ma(加权平均为1646±160 Ma,N=16)、861~750 Ma(加权平均为773±92 Ma,N=2)、484~388 Ma(加权平均为433±38 Ma,N=6)和320~233 Ma(加权平均为253±16 Ma,N=7)。1件构造分异石英脉岩样品20个锆石测点中有3组206Pb/238U年龄,分别为1244±19 Ma(N=1)、430±5 Ma(N=1)和312~212 Ma(加权平均为229.6±6.7 Ma,N=18)。不同类型岩石中的各组锆石206Pb/238U加权平均年龄极为接近,代表了不同的地质意义,其中1646~1630 Ma可能代表了团梁子岩组原岩的形成年龄,而253~219 Ma可能代表了团梁子岩组在此时期受到构造热事件影响,该事件可能与古特提斯洋盆由西向东的俯冲消减作用有关。本次获得的绿片岩、基性脉岩及构造分异石英脉岩锆石U-Pb年龄将团梁子岩组时代约束为老于1630 Ma,即中元古代,可能属澜沧岩群的一部分。     

U-Pb zircon geochronology, geochemistry and kinetics of the Huaniushan A-type granite in Northwest China

The Huaniushan granite is located at the Beishan orogenic belt, northwestern China. At the contact zone between the granite and marble, a hydrothermal Pb-Zn and skarn Au deposit is formed. LA-ICP-MS zircon U-Pb dating yielded a weighted mean 206Pb/238U age of 229.5±2.6 Ma (MSDW=0.93) for the Huaniushan granite, imply-ing its Late Triassic intrusion. Geochemistry analyses show that the Huaniushan granite is enriched in Si, K, Na, and REE, and depleted in Mg and Ca, with contents of SiO2 (70.8% to 74.4%), Na2O+K2O (8.8% to 10.2%), CaO (0.93% to 1.44%), and MgO (0.14% to 0.48%). REE is characterized by obvious negative Eu anomaly. Rb, Th, U, K, Pb, Nb, Zr and Hf elements are rich in the granite while Ba, Sr, P, Ti and Eu are deplete. The granite has a high (Zr+Nb+Ce+Y) abundance and 104 Ga/Al ratios. Petrology, major and trace elements data all indicate that the Hua-niushan granite is A-type granite which intruded in a post-collisional extensional tectonic setting. The magma was dominantly sourced from partial melting of crustal intermediate-felsic igneous rocks. Intensive magmatic activities and Au-Cu-Mo mineralization occurred throughout the Beishan orogenic belt during the period from ca. 240 to 220 Ma.     

水射流破碎南海含水合物沉积物数值模拟研究

为研究高压水射流切割、破碎南海天然气水合物储层的过程,采用著名的LS—DYNA显示动力分析有限元程序,对淹没状态下,水射流破碎海底含水合物沉积物过程进行数值模拟研究,研究了不同射流速度对高压水射流作用下含水合物沉积物破碎效果的影响规律。随着射流速度的增大,冲蚀深度逐渐增大,两者呈线性递增关系。含水合物沉积物冲蚀体积是轴向冲蚀与径向冲蚀共同作用的结果,射流速度越大,对含水合物沉积物的轴向与径向冲蚀作用增强,加大了含水合物沉积物冲蚀体积递增速率。     

吉林珲春东北部中生代侵入岩——一个中性—酸性双峰式岩系的演化和形成环境

地质调查和年代学资料表明,研究区内早燕山期侵入岩为一套中性—酸性双峰式岩系。通过岩石学、矿物学和地球化学方面的研究,对该岩系的成分演化特征、形成的构造环境进行了较细致的论述,得出该岩系是一个具不连续演化特点的钙碱性岩系,形成于破坏性板块边缘的张性环境,相当于Ⅰ型花岗岩系,属于环太平洋岩浆作用的内容。     

腾冲地热水化学特征及腐蚀机理探讨

本文从腾冲地热成因的角度,分析其地热水化学的总体特征和赋存规律。在此基础上对地热水ｐＨ值、流速、溶解氧、ＣＯ２及Ｃｌ＾－、ＳＯ４＾２－、ＳｉＯ３＾２－、Ｃａ＾２等对金属材料的腐蚀机理进行讨论。     

Magmatic‐Hydrothermal Mineralization Sequence in Xinlu Ore Field,Guangxi, South China: Constraints from Zircon U‐Pb,Molybdenite Re‐Os,and Muscovite Ar‐Ar Dating

The Xinlu Sn‐polymetallic ore field is located in the western Nanling Polymetallic Belt in northeastern Guangxi, South China, where a number of typical skarn‐, hydrothermal vein‐type tin deposits have developed. There are two types of Sn deposits: skarn‐type and sulfide‐quartz vein‐type. The tin mineralizations mainly occur on the south side of the Guposhan granitic complex pluton and within its outer contact zone. To constrain the Sn mineralization age and further understand its genetic links to the Guposhan granitic complex, a series of geochronological works has been conducted at the Liuheao deposit of the ore field using high‐precision zircon SHRIMP U‐Pb, molybdenite Re‐Os, and muscovite Ar‐Ar dating methods. The results show that the biotite‐monzogranite, which is part of the Xinlu intrusive unit of the Guposhan complex pluton, has a SHRIMP U‐Pb zircon age of 161.0 ± 1.5 Ma. The skarn‐type ore has a ⁴⁰Ar‐³⁹Ar muscovite plateau age of 160 ± 2 Ma (same as its isochron age), and the sulfide‐quartz vein‐type ore yields an Re‐Os molybdenite isochron age of 154.4 ± 3.5 Ma. The magmatic‐hydrothermal geochronological sequence demonstrated that the hydrothermal mineralization took place immediately following the emplacement of the monzogranite, with the skarn metasomatic mineralization stage predating the sulfide mineralization stage. Geochronologically, we have compared this ore field with 26 typical Sn deposits distributed along the Nanling Polymetallic Belt, leading to the suggestion of the magmatic‐metallogenic processes in the Xinlu ore field (ca. 161–154 Ma) as a component of the Early Yanshanian large‐scale Sn‐polymetallic mineralization event (peaked at 160–150 Ma) in the Nanling Range of South China. Petrogenesis of Sn‐producing granite and Sn‐polymetallic mineralization were probably caused by crust–mantle interaction as a result of significant lithospheric extension and thinning in South China in the Late Jurassic.     

反向断裂下盘较顺向断裂上盘更易富集油气机理的定量解释

为了研究含油气盆地中断裂对油气成藏与分布的控制作用,在断层侧向封闭机理及影响因素研究的基础上,对反向断裂下盘较顺向断裂上盘更易富集油气的机理进行了定量解释。结果表明,无论是反向断裂还是顺向断裂,均源于断层岩封闭油气,断层岩油气运移方向排替压力是影响其侧向封闭油气能力的主要因素。在断裂埋深、断裂倾角和地层岩性、地层倾角相同的条件下,理论上反向断裂断层岩泥质体积分数大于顺向断裂断层岩泥质体积分数,即反向断裂断层岩油气运移方向排替压力大于顺向断裂断层岩油气运移方向排替压力,反向断裂侧向封闭能力强于顺向断裂侧向封闭能力,造成反向断裂下盘较顺向断裂上盘更易富集油气。歧口凹陷板桥断裂下盘沙一段下部断层岩在反向条件和顺向条件下油气运移方向排替压力的实例研究结果表明,反向条件下较顺向条件下在油气运移方向有更高的排替压力,侧向封闭能力更强,更有利于油气在板桥断裂下盘沙一段储层中富集。     

内蒙武川后石花金矿床辉钼矿Re-Os同位素年龄及其地质意义

后石花金矿是华北克拉通北缘一小型石英脉型金矿床。对矿体5件辉钼矿样品的ReOs同位素分析,获得了介于280.3±3.8~283.0±3.9Ma,加权平均为282.0±1.8Ma(MSWD=0.28)的同位素模式年龄,以及一个相关性很好的等时线年龄281.9±1.8Ma(MSWD=0.57),表明矿床形成于早二叠世,推测是海西晚期古亚洲洋俯冲体制下陆缘弧背景中构造-热液成矿事件产物。综合区域资料认为,华北北缘中段在海西晚期曾发生过重要成矿作用,但多在后期被剥蚀破坏。华北北缘中段大陆弧范围内,叠加在前寒武纪结晶基底韧性剪切带之上的脆性断裂构造带,以及华北北缘早古生代增生带内部,是形成海西晚期金、钼矿床的有利部位。     

从黄铁矿特征论380地区金鸡岭岩体外带铀矿床成矿机理

本文以铀矿区广泛发育的黄铁矿为研究对象，通过成因矿物学方法探讨金鸡岭岩体外带铀矿床的成矿机理；论证了矿质来源于岩体的围岩，与花岗岩关系不密切；岩体侵位所引起的围岩热变质作用，以及由此而产生的变质热液，是导致成矿物质重新活化、迁移和富集成矿的根本原因。     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.