Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.     

Modelling fractionation of stable isotopes in stalagmites

High resolution δ¹³C and δ¹⁸O profiles recorded in precisely dated speleothems are widely used proxies for the climate of the past. Both δ¹³C and δ¹⁸O depend on several climate related effects including meteorological processes, processes occurring in the soil zone above the cave and isotope fractionation processes occurring in the solution layer on the stalagmite surface. Here we model the latter using a stalagmite isotope and growth model and determine the relationship between the stable isotope values in speleothem calcite and cave parameters, such as temperature, drip interval, water p_CO2 and a mixing coefficient describing mixing processes between the solution layer and the impinging drop.The evolution of δ¹³C values is modelled as a Rayleigh distillation process and shows a pronounced dependence on the residence time of the solution on the stalagmite surface and the drip interval, respectively. The evolution of δ¹⁸O values, in contrast, is also influenced by buffering reactions between the bicarbonate in the solution and the drip water driving the δ¹⁸O value of the bicarbonate towards the value expected for equilibrium isotope fractionation between drip water and calcite. This attenuates the dependence of the δ¹⁸O values on drip interval. The temperature dependence of δ¹⁸O, however, is more pronounced than for δ¹³C and in a similar range as expected for fractionation under equilibrium conditions.We also investigate the isotopic enrichment of the δ¹³C and δ¹⁸O values along individual growth layers and, thus, the slopes expected for Hendy tests. The results show that a positive Hendy test is only possible if isotope fractionation occurred under disequilibrium conditions. However, a negative Hendy test does not exclude that isotope fractionation occurred under disequilibrium conditions. A more reliable indicator for disequilibrium fractionation is the enrichment of the δ¹³C values along an individual growth layer.     

Erosion-driven uplift of the modern Central Alps

We present a compilation of data of modern tectono-geomorphic processes in the Central European Alps which suggest that observed rock uplift is a response to climate-driven denudation. This interpretation is predominantly based on the recent quantification of basin-averaged Late Holocene denudation rates that are so similar to the pattern and rates of rock uplift rates as determined by geodetic leveling. Furthermore, a GPS data-based synthesis of Adriatic microplate kinematics suggests that the Central Alps are currently not in a state of active convergence. Finally, we illustrate that the Central Alps have acted as a closed system for Holocene redistribution of sediment in which the peri-Alpine lakes have operated as a sink for the erosional products of the inner Central Alps.While various hypotheses have been put forward to explain Central Alpine rock uplift (e.g. lithospheric forcing by convergence, mantle processes, or ice melting) we show with an elastic model of lithospheric deformation, that the correlation between erosion and rock uplift rates reflects a positive feedback between denudation and the associated isostatic response to unloading. Thus, erosion does not passively respond to advection of crustal material as might be the case in actively converging orogens. Rather, we suggest that the geomorphic response of the Alpine topography to glacial and fluvial erosion and the resulting disequilibrium for modern channelized and associated hillslope processes explains much of the pattern of modern denudation and hence rock uplift. Therefore, in a non-convergent orogen such as the Central European Alps, the observed vertical rock uplift is primarily a consequence of passive unloading due to erosion.     

Biological and Physical Clogging in Infiltration Wells: Effects of Well Diameter and Gravel Pack

Gravity-driven infiltration into the shallow subsurface via small-diameter wells (SDWs), i.e., wells with an inner diameter smaller than 7.5 cm (3 inches) and no gravel pack) has proven to be a cost-efficient and flexible tool for managed aquifer recharge (MAR), as it provides relatively high recharge rates with minimal construction effort. SDWs have a significantly smaller open filter area than larger diameter wells with gravel pack, making the infiltration of low-quality waters through these wells more at risk clogging. To investigate their susceptibility for biological and physical clogging, 24 physical models with different well setups were evaluated by infiltrating either nutrient-poor but turbid water or nutrient-rich but clear water. The experiments showed that smaller diameters and the lack of a gravel pack increase the well's susceptibility to both kinds of clogging. However, this effect was observed to be much more pronounced for physical than for biological clogging. Our conclusion is that SDWs show severe disadvantages with respect to the infiltration of highly turbid waters in comparison to large diameter wells with a gravel pack. Nevertheless, this disadvantage is much less severe when it comes to the infiltration of clear but nutrient-rich waters (e.g., treated wastewater). Depending on the economic and geological circumstances of a MAR-project, this disadvantage could be outweighed by the significantly lower construction costs of SDWs.     

Properties of dusty tori in active galactic nuclei – I. The case of SWIRE/SDSS quasars

We derive the properties of dusty tori in active galactic nuclei from the comparison of observed spectral energy distributions (SEDs) of SDSS quasars and a precomputed grid of torus models. The observed SEDs comprise SDSS photometry, Two-Micron All-Sky Survey J , H and K data, whenever available, and mid-infrared (mid-IR) data from the Spitzer Wide-area InfraRed Extragalactic Survey. The adopted model is that of Fritz, Franceschini & Hatziminaoglou. The fit is performed by standard  χ²  -minimization; the model, however, can be a multicomponent comprising a stellar and a starburst component, whenever necessary. Models with low equatorial optical depth, τ_9.7, were allowed as well as 'traditional' models with  τ_9.7≥ 1.0  , corresponding to   A _V≥ 22  and the results were compared. Fits using high optical depth tori models only produced dust more compactly distributed than in the configuration where all τ_9.7 models were permitted. Tori with decreasing dust density with the distance from the centre were favoured while there was no clear preference for models with or without angular variation of the dust density. The computed outer radii of the tori are of some tens of parsecs large but can reach, in a few cases, a few hundreds of parsecs. The mass of dust, M _Dust, and IR luminosity, L _IR, integrated in the wavelength range between 1 and 1000 μm, do not show significant variations with redshift, once the observational biases are taken into account. Objects with 70-μm detections, representing 25 per cent of the sample, are studied separately and the starburst contribution (whenever present) to the IR luminosity can reach, in the most extreme but very few cases, 80 per cent.     

Evolution of the Kivu Rift,East Africa: interplay among tectonics,sedimentation and magmatism

The seismically and volcanically active Kivu Rift, in the western branch of the East African Rift System, is a type locale for studies of high‐elevation, humid‐climate rift basins, as well as magmatic basin development. Interpretations of offshore multi‐channel seismic (MCS) reflection data, terrestrial radar topography, lake bathymetry and seismicity data recorded on a temporary array provide new insights into the structure, stratigraphy and evolution of the Kivu rift. The Kivu rift is an asymmetric graben controlled on its west side by a ca. 110 km‐long, N‐S striking border fault. The southern basins of the lake and the upper Rusizi river basin are an accommodation zone effectively linking 1470 m‐high Lake Kivu to 770 m‐high Lake Tanganyika. MCS data in the eastern Kivu lake basin reveal a west‐dipping half graben with at least 1.5 km of sedimentary section; most of the ca. 2 km of extension in this sub‐basin is accommodated by the east‐dipping Iwawa normal fault, which bounds an intrabasinal horst. Lake Kivu experienced at least three periods of near desiccation. The two most recent of these approximately correlate to the African Megadrought and Last Glacial Maximum. There was a rapid lake level transgression of at least 400 m in the early Holocene. The line load of the Virunga volcanic chain enhances the fault‐controlled basin subsidence; simple elastic plate models suggest that the line load of the Virunga volcanic chain depresses the basin by more than 1 km, reduces flank uplift locally and broadens the depocentre. Not only do the voluminous magmatism and degassing to the lake pose a hazard to the riparian population, but our studies demonstrate that magmatism has important implications for short‐term processes such as lake levels, inflow and outlets, as well as long term modification of classic half‐graben basin morphology.     

Der Chlorophyllgehalt im See und seine photosynthetische Valenz als geophysikalisches Problem

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